Sources and biogeochemical cycling of particulate selenium in the San Francisco Bay estuary     

Martina A. Doblin  Stephen B. Baines  Lynda S. Cutter  Gregory A. Cutter 《Estuarine, Coastal and Shelf Science》2006,67(4):681-694

As part of a study of estuarine selenium cycling, we measured the concentration, chemical form (speciation), and distribution of particulate selenium under various river flow conditions in the North San Francisco Bay (from the Golden Gate to the Sacramento and San Joaquin Rivers). We also conducted laboratory studies on the accumulation of selenium by phytoplankton, the critical first step in the transformation of dissolved to particulate selenium. Total particulate selenium concentration in the North SF Bay was relatively constant between high and low flow periods, ranging spatially from 0.05 to 0.35 nmol l⁻¹ and comprising between 5 and 12% of the total water column selenium inventory. Mean concentrations were generally highest in the Carquinez Strait–Suisun Bay region (salinity 0–17) and lowest in Central Bay. However, selenium content of suspended particles varied with river flow, with higher content during low flow (9.76 ± 4.17 nmol g⁻¹; mean ± sd; n = 67) compared to high flow (7.10 ± 4.24 nmol g⁻¹; n = 39). Speciation analyses showed that most particulate selenium is organic selenide (45 ± 27%), with a smaller proportion (typically <30%) of adsorbed selenite + selenate and a varying proportion (35 ± 28%) of elemental selenium. Based on the amount of elemental selenium in the seston (total suspended material), we calculate that resuspension of estuarine sediments could contribute 29–100% of particulate selenium in the water column. While selenium content of SF Bay seston (>0.4 μm) is relatively unenriched compared to phytoplankton (13.6–155 nmol g⁻¹ dry weight) on a mass basis, when normalized to carbon or nitrogen, seston contains a similar selenium concentration to SF Bay sediments or phytoplankton cultures. SF Bay seston is thus comprised of selenium-rich phytoplankton and phyto-detritus, but also inorganic clay mineral particles that effectively “dilute” total particulate selenium. Selenium concentrations in algal cultures (11 species) exposed to 90 nmol l⁻¹ selenite show relatively large differences in selenium accumulation, with the diatoms, chlorophytes and cryptophytes generally having lower selenium cell content (3.8 ± 2.7 × 10⁻⁹ nmol selenium cell⁻¹) compared to the dinoflagellates (193 ± 73 × 10⁻⁹ nmol selenium cell⁻¹). Because phytoplankton are such a rich (but variable) source of selenium, their dynamics could have a profound effect on the particulate selenium inventory in the North SF Bay.  相似文献   

Effects of salinity downshock on dimethylsulfide production     

Takushi Niki  Miwa Shimizu  Ayako Fujishiro  Junji Kinoshita 《Journal of Oceanography》2007,63(5):873-877

During time-series observations in Sagami Bay, Japan, the concentration of dissolved dimethylsulfoniopropionate (DMSP_d), a precursor of dimethylsulfide (DMS), was negatively correlated with salinity. In the laboratory, low-salinity shock reduced DMS production rates of the natural bacterial community and induced rapid DMSP release from a dinophyte, Heterocapsa triquetra, suggesting that low-salinity shock reduced DMSP_d consumption but enhanced DMSP_d production, which agrees with the negative correlation between DMSP_d and salinity observed in Sagami bay. In addition, low-salinity shock did not affect DMSP lyase activity of H. triquetra. Low-salinity shock would increase the contribution from algae in DMS production, leading to an increase in potential DMS productivity in the environment.  相似文献   

Algorithm for HF radar vector current measurements   总被引：1，自引：0，他引：1  

Lei Liu  Xiongbin Wu  Feng Cheng  Shaolin Yang  Hengyu Ke 《Journal of Oceanography》2007,63(1):47-66

A new algorithm is proposed, called the stream function method (SFM) for producing vector current maps from radial data measured by dual-site high frequency surface wave radar (HFSWR). In SFM, a scalar stream function is constructed under some oceanographic assumptions. The function describes the two-dimensional (2-D) ocean surface water motion and is used to obtain the distribution of vector currents. The performance of SFM is evaluated using simulated radial data, which demonstrates that SFM has advantages over typical vectorial combination methods (VCM) both in error acceptance and robustness, and excels another method based on least-squares fitting (LSF) in recovering the complicated current models. Furthermore, SFM is capable of providing the total currents based on radials from single-site radar. We also test the assumptions of horizontal non-divergence in the simulation. The new algorithm is applied to the field experiment data of Wuhan University’s ocean state measuring and analyzing radar (OSMAR), collected in the coastal East China Sea during April 11–17, 2004. Quantitative comparisons are given between radar results by three current algorithms and in-situ current meter measurements. Preliminary analysis of the vertical current shear is given based on the current meter measurements.  相似文献   

Tectonic core of a sedimentary drift: a potential ridge propagation feature beneath the Blake Outer Ridge     

Dayton Dove  Steven C. Jaume  Erin Beutel 《Marine Geophysical Researches》2007,28(1):1-11

The Blake Outer Ridge is a 480–kilometer long linear sedimentary drift ridge striking perpendicular to the North American coastline. By modeling free-air gravity anomalies we tested for the presence of a crustal feature that may control the location and orientation of the Blake Outer Ridge. Most of our crustal density models that match observed gravity anomalies require an increase in oceanic crustal thickness of 1–3 km on the southwest side of the Blake Outer Ridge relative to the northeast side. Most of these models also require 1–4 km of crustal thinning in zone 20–30 km southwest of the crest of the Blake Outer Ridge. Although these features are consistent with the structure of oceanic fracture zones, the Blake Outer Ridge is not parallel to adjacent known fracture zones. Magnetic anomalies suggest that the ocean crust beneath this feature formed during a period of mid-ocean ridge reorganization, and that the Blake Outer Ridge may be built upon the bathymetric expression of an oblique extensional feature associated with ridge propagation. It is likely that the orientation of this trough acted as a catalyst for sediment deposition with the start of the Western Boundary Undercurrent in the mid-Oligocene.  相似文献   

Jellyfish patch formation investigated by aerial photography and drifter experiment     

Shinya Magome  Tomohiro Yamashita  Takeshi Kohama  Atsushi Kaneda  Yuichi Hayami  Satoru Takahashi  Hidetaka Takeoka 《Journal of Oceanography》2007,63(5):761-773

Jellyfish patch formation is investigated by conducting a drifter experiment combined with aerial photography of a sustained patch of the moon jellyfish in Hokezu Bay, Japan. Jellyfish patches are aggregations of individuals that are caused by a combination of swimming (active influence) and advection by currents (passive influence). The drifter experiment involved the injection of 49 drifters around a distinct surface patch of jellyfish within an area of approximately 300 m × 300 m. The drifters’ motion, caused only by the passive influence, was recorded in a series of 38 aerial photographs taken over approximately 1 h. The ambient uniform current field larger than the patch scale was estimated from the movement of the centroid position of drifters, while the distribution of horizontal divergence and relative vorticity around the patch was estimated from the time-derivative in areas of triangles formed by the drifters. The centroid positions of both drifters and patches moved stably toward the bay head at different speeds. The difference vector between the patch and drifter centroids was directed to the sun, and was opposite to the ambient current. The distributions of vorticity and divergence around patches exhibited inhomogeneity within the patch scale, and the drifters in this nonuniform current field aggregated near the convergence area within 1 h. The results suggest that horizontal patch formation is predominantly influenced by passive factors at the surface of Hokezu Bay. Furthermore, the upward swimming against downwelling may make sustained patch in surface layer.  相似文献   

Biodiversity of meiofauna in the intertidal khe nhan mudflat,can gio mangrove forest,vietnam with special emphasis on free living nematodes     

Quang Ngo Xuan  Ann Vanreusel  Nguyen Vu Thanh  Nic Smol 《Ocean Science Journal》2007,42(3):135-152

The ecological aspect of meiofaunal communities in Can Gio mangrove forest, Ho Chi Minh city, Vietnam has not been investigated before. The composition, distribution, density and biodiversity of meiofaunal communities were studied along an intertidal transect at the Khe Nhan mudflat. Each time, three replicate samples were collected in four stations along a transect following the water line from low tide level up to the mangrove forest edge. In total, 18 meiofaunal taxa were found with the dominant taxa belonging to Nematoda, Copepoda, Sarcomastigophora and Polychaeta. The densities of meiofauna ranged from 1156 inds/10 cm² to 2082 inds/10 cm². The increase in densities from the mangrove forest edge towards the low water line was significant. Along the mudflat transect, the biodiversity (expressed by different indices) was relatively high at different taxonomic levels but did not vary significantly along the mudflat except for taxa richness. Eighty nematode genera belonging to 24 families with Comesomatidae having the highest abundance 33.8 % were found.Theristus andNeochromadora decreased in densities from the lower water line towards the mangrove forest edge, whileParacomesoma andHopperia are typical and more abundant at the middle of the mudflat.Halalaimus increased from high on the mudflat to the low water line.  相似文献   

Further observations on the effects of preservation in 4% neutral formalin on the length and weight of 0-group flatfish     

Lockwood  Stephen J.; Daly  C. de B. 《ICES Journal of Marine Science》1975,36(2):170-175

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Dissolved titanium distributions in the Mid-Atlantic Bight   总被引：1，自引：0，他引：1  

Stephen A. Skrabal   《Marine Chemistry》2006,102(3-4):218-229

Although titanium is abundant in Earth's crust, its sources and distribution in the ocean are poorly understood. To elucidate its behavior, distributions of dissolved (< 0.2 μm) Ti were determined in surface waters and vertical profiles from the Mid-Atlantic Bight (MAB). Concentrations of Ti decreased from 390 pM at the Delaware Bay mouth to < 100 pM across the Delaware continental shelf. In vertical profiles, small increases in bottom waters suggest a possible flux of Ti from shelf sediments, consistent with previous reports of pore water enrichments of dissolved Ti in MAB sediments. Concentrations in surface waters of the outer shelf and slope ranged between 30 and 140 pM, with most values below 90 pM. Concentrations in a 1000 m vertical profile in the eastern Gulf Stream ranged between 110 and 280 pM, and showed a variable distribution attributed to the mixing of water masses in the outer MAB. A simple model of Ti sources to the MAB suggests that atmospheric deposition of dissolved Ti is comparable to net riverine contributions and therefore must be considered in applications of Ti as a tracer of oceanographic processes.  相似文献   

Multi-proxy evidence of long-term changes in ecosystem structure in a Danish marine estuary, linked to increased nutrient loading   总被引：3，自引：0，他引：3  

Marianne Ellegaard  Annemarie L. Clarke  Nina Reuss  Simon Drew  Kaarina Weckstrm  Stephen Juggins  N. John Anderson  Daniel J. Conley 《Estuarine, Coastal and Shelf Science》2006,68(3-4):567

This paper presents a study of changes in eutrophication over the past 100 years in a fertile estuary. The Danish estuary Mariager Fjord is a long, narrow sill-fjord with a permanently anoxic basin. In 1997 anoxia spread from the basin to the entire inner estuary, killing almost all eukaryotes and prompting debate on the causes. This paper reports a multi-proxy survey of ²¹⁰Pb-dated sediment cores from the anoxic basin. Analyses of diatoms, dinoflagellates, pigments and geochemical proxies were used to determine changes in ecosystem structure over the past 100 years. The aim was to establish ‘base-line conditions’, for management purposes, of the biological structure prior to 1900, and to examine possible causes of changes observed. Geochemical proxies total nitrogen (TN), total carbon (TC) and biogenic silica (BSi) were consistently high throughout the sediment record. Increased concentrations of pigments and natural isotopes (δ¹³C, δ¹⁵N) suggested increasing production and nutrient loading. The main changes in the biological proxies occurred between 1915 and the 1940s, and indicated that the estuary has been somewhat eutrophic since 1900, but that the eutrophication process increased over the past 100 years. A reconstruction of TN concentration by a diatom-based transfer function supports this interpretation, with inferred TN ca. 1900 around 60 μmol l⁻¹, and an increase in TN concentration over the past century to ca. 130 μmol l⁻¹ by 1995. Inferred TN decreased to ca. 100 μmol l⁻¹ by 2001, similar to present day monitoring data.  相似文献   

Baroclinic Buoyancy-Inertia Joint Stability Parameter     

Hideo Kawai 《Journal of Oceanography》2005,61(2):235-246

At present, the barotropic buoyant stability parameter has been derived from a vertical virtual displacement of a water parcel. The barotropic inertial stability parameter in the eccentrically cyclogeostrophic, basic current field was derived in 2003 from a horizontal cross-stream virtual displacement of a parcel. By expressing acceleration of a parcel due to a virtual displacement, which is arbitrarily sloping within a vertical section across the basic current, in terms of natural coordinates, we derived the vertical component of baroclinic buoyant stability parameter B ₂ ², the horizontal component of baroclinic inertial stability parameter I ₂ ², the baroclinic joint stability parameter J ², its buoyant component B ² and its inertial component I ². B ² is far greater than I ₂ ², and when neglecting relative vorticity except for vertical shear, a downward convex curve of J ² plotted against the slope of a virtual displacement follows a trend of B ² curve. If a parcel displaces along a horizontal surface or an isopycnal surface, however, B ² vanishes, and J ² becomes equal to I ². Actual parcel is apt to displace not only along the bottom slope, but also along the sea surface and an isopycnal interfacial surface, which is approximately equivalent to an isentropic surface, preferred by lateral mixing and exchange of momentum. Such actual displacement makes B ² vanishing, and grants I ² an important role. The present analysis of I ² examining effects due to curvature and horizontal and vertical shear vorticities are useful in deepening our understanding of baroclinic instability in actual oceanic streams.  相似文献