Polycyclic aromatic hydrocarbons and their molecular diagnostic ratios in urban atmospheric respirable particulate matter   总被引：2，自引：5，他引：2  

María del Rosario Sienra  Nelson G. Rosazza  Margarita Prndez 《Atmospheric Research》2005,75(4):267-281

Atmospheric concentrations of polycyclic aromatic hydrocarbons (PAHs) in Santiago de Chile city were evaluated to study particulate PAHs profiles during cold and spring weather periods. Urban atmospheric particulate matter PM10 was collected using High Volume PM10 samplers. Fifteen samples of 24 h during austral winter and 20 samples of 24 h during spring, 2000 were collected at two sampling sites (North–East and Central areas of the city) whose characteristics were representative of the prevailing conditions. Seventeen PAHs were quantified and total PAHs concentration ranged from 1.39 to 59.98 ng m⁻³, with a seasonal variation (winter vs. spring ratio) from 0.5 to 12.6 ng m⁻³. Molecular diagnostic ratios were used to characterize and identify PAHs emission sources such as combustion and biogenic emissions. Results showed that the major sources of respirable organic aerosol PM10 in Santiago are mobile and stationary ones.  相似文献   

Spatially discontinuous modern sedimentation in Georgian Bay, Huron Basin, Great Lakes     

Francine M. G. McCarthy  John H. McAndrews  Steve M. Blasco  Sarah H. Tiffin 《Journal of Paleolimnology》2007,37(3):453-470

High-resolution seismic reflection profile data show that the modern sediment cover (over the last 150 years) in Georgian Bay is thin and spatially discontinuous. Sediments rich in ragweed pollen, largely derived from siltation linked to land clearing and European settlement, form a thin, discontinuous veneer on the lakebed. Much of the lakebed consists of exposed sediments deposited during the late glacial or early postglacial. Accumulation rates of modern sediments range from < 0 mm/year (net erosion) to ∼3.2 mm/year, often within a few hundred metres spatially. These rates are much lower than those reported for the main basin of Lake Huron and the other Great Lakes, and are attributed to the low sediment supply. Only a few small rivers flow into Georgian Bay, and most of the basin is surrounded by bedrock of Precambrian gneiss and granite to the east, and Silurian dolostone, limestone and shale to the west. Thick deposits of Pleistocene drift, found on the Georgian Bay shoreline only between Meaford and Port Severn, are the main sediment source for the entire basin at present. Holocene to modern sediments are even absent from some deep basins of Georgian Bay. These findings have implications for the ultimate fate of anthropogenic contaminants in Georgian Bay. While microfossil assemblages in the ragweed-rich sediments record increased eutrophication over the last 150 years, most pollutants generated in the Georgian Bay catchment are not accumulating on the lakebed and are probably exported from the Bay.  相似文献   

The numerical solution of the Advection-Dispersion Equation: A review of some basic principles     

Steve Wallis 《Acta Geophysica》2007,55(1):85-94

The simulation of solute transport in rivers is frequently based on numerical models of the Advection-Dispersion Equation. The construction of reliable computational schemes, however, is not necessarily easy. The paper reviews some of the most important issues in this regard, taking the finite volume method as the basis of the simulation, and compares the performance of several types of scheme for a simple case of the transport of a patch of solute along a uniform river. The results illustrate some typical (and well known) deficiencies of explicit schemes and compare the contrasting performance of implicit and semi-Lagrangian versions of the same schemes. It is concluded that the latter have several benefits over the other types of scheme.  相似文献   

Evolution of the variability of surface temperature and vegetation density in the great plains     

Michael H. Cosh  Jery R. Stedinger  Steve C. Ou  Kuo-Nan Liou  Wilfried Brutsaert 《Advances in water resources》2007

This study focuses on how the variability of land surface temperature and vegetation density at the SGP ARM-CART site changes over episodic (day to day) and seasonal time scales using AVHRR satellite data. Four drying periods throughout the year are analyzed. Land surface temperature had an erratic relationship with time exhibiting no deterministic pattern from day-to-day or season-to-season. Furthermore, it did not exhibit spatial pattern persistence. On the other hand, vegetation density had a consistent spatial pattern and temporal decay during average length drying periods (less than 7 days) as well as within a season. However, there were distinct differences in the seasonal pattern of variation between winter and growing seasons. In addition, the paper highlights a methodology to quantify the relationships that exist at the land surface between the primary parameter of interest and the controlling variables.  相似文献   

Use of high spectral resolution remote sensing to determine leaf palatability of eucalypt trees for folivorous marsupials     

Steve Dury  Brian Turner  Bill Foley  Ian Wallis 《International Journal of Applied Earth Observation and Geoinformation》2001,3(4):328

In this study we assess the feasibility of remotely measuring canopy biochemistry, and thus the potential for conducting large-scale mapping of habitat quality. A number of studies have found nutrient composition of eucalypt foliage to be a major determinant of the distribution of folivorous marsupials. More recently it has been demonstrated that a specific group of secondary plant chemicals, the diformylphloroglucinols (DFPs), are the most important feeding deterrents, and are thus vital determinants of habitat quality. We report on the use of laboratory spectroscopy to attempt to identify one such DFP, sideroxylonal-A, in the foliage of Eucalyptus melliodora, one of the few eucalypt species browsed by folivorous marsupials. Reflectance spectra were obtained for freeze-dried, ground leaves using near infrared spectroscopy (NIRS) and for both oven-dried and fresh whole leaves using a laboratory-based (FieldSpec) spectroradiometer. Modified partial least squares (MPLS) regression was used to develop calibration equations for sideroxylonal-A concentration based on the reflectance spectra transformed as both the first and second difference of absorbance (Log 1/R). The predictive ability of the calibration equations was assessed using the standard error of calibration statistic (SECV). Coefficients of determination (r²) were highest for the ground leaf spectra (0.98), followed by the fresh leaf and dry leaf spectra (0.94 and 0.87, respectively). When applied to independent validation sub-sets, sideroxylonal-A was most accurately predicted from the ground leaf spectra (r² = 0.94), followed by the dry leaf and fresh leaf spectra (0.72 and 0.53, respectively). Two spectral regions, centred on 674 nm and 1394 nm, were found to be highly correlated with sideroxylonal-A concentration for each of the three spectral data sets studied. Results from this study suggest that calibration equations derived from modified partial least squares regression may be used to predict sideroxylonal-A concentration, and hence leaf palatability, of Eucalyptus melliodora trees, thereby indicating that the remote estimation of habitat quality of eucalypt forests for marsupial folivores is feasible.  相似文献   

Post-earthquake investigation on several geosynthetic-reinforced soil retaining walls and slopes during the Ji-Ji earthquake of Taiwan   总被引：1，自引：0，他引：1  

Hoe I. Ling  Dov Leshchinsky  Nelson N. S. Chou 《Soil Dynamics and Earthquake Engineering》2001,21(4):3087

This paper gives an overview on the application of geosynthetic-reinforced soil structures in Taiwan. Taiwan has an unique topography and geotechnical conditions that rendered a less conservative and more challenging design compared to that of North America, Europe and Japan. The Ji-Ji (Chi-Chi) earthquake of 1999 gave an opportunity to examine the behavior of reinforced soil structures. The performance of several modular-block reinforced soil retaining walls and reinforced slopes at the vicinity of the fault was evaluated. Reinforced structures performed better than unreinforced soil retaining walls. The failure cases were highlighted and the cause of failure was identified. The lack of seismic design consideration could be a major cause of failure. The compound failure mode, the inertia force of the blocks, and the connection stiffness and strength relative to the large dynamic earth pressure, were among major items that would warrant further design consideration.  相似文献   

Petroleum Hydrocarbon Bioventing Kinetics Determined in Soil Core, Microcosm, and Tubing Cluster Studies   总被引：2，自引：0，他引：2  

Ellen E. Moyer  David W. Ostendorf  Robin J. Richards  Steve Goodwin 《Ground Water Monitoring & Remediation》1996,16(1):141-153

Aerobic biodegradation of vapor-phase petroleum hydrocarbons was evaluated in an intact soil core from the site of an aviation gasoline release. An unsaturated zone soil core was subjected to a flow of nitrogen gas, oxygen, water vapor, and vapor-phase hydrocarbons in a configuration analogous to a biofilter or an in situ bioventing or sparging situation. The vertical profiles of vapor-phase hydrocarbon concentration in the soil core were determined by gas chromatography of vapor samples. Biodegradation reduced low influent hydrocarbon concentrations by 45 to 92 percent over a 0.6-m interval of an intact soil core. The estimated total hydrocarbon concentration was reduced by 75 percent from 26 to 7 parts per million. Steady-state concentrations were input to a simple analytical model balancing advection and first-order biodegradation of hydrocarbons. First-order rate constants for the major hydrocarbon compounds were used to calibrate the model to the concentration profiles. Rate constants for the seven individual hydrocarbon compounds varied by a factor of 4. Compounds with lower molecular weights, fewer methyl groups, and no quaternary carbons tended to have higher rate constants. The first-order rate constants were consistent with kinetic parameters determined from both microcosm and tubing cluster studies at the field site.  相似文献   

Social network interactions among mentally ill persons in community housing: research issues and agenda     

Dr. G. B. Hall  Dr. G. B. Nelson  Dr. D. Squire  Prof. Dr. R. Walsh 《GeoJournal》1992,26(1):81-86

This paper discusses social network interactions among individuals who have been hospitalized with mental illness and who currently reside in different types of community housing programmes. First, a conceptualisation of social networks that focuses on network interactions, both supportive and non-supportive, between network interactions may be more important influences on successful or unsuccessful adaptation of current and former psychiatric patients to community life than the structural dimensions of social networks more commonly analysed in the literature. The design of a current longitudinal study of social network interactions is presented. The results of two pilot studies that examine social network interactions is presented. The results of two pilot studies that examine social network interactions with data from several community housing programmes in southern Ontario, Canada are reviewed and an agenda is stated for further data collection and analysis.  相似文献   

A skeletal assemblage classification system for non-tropical carbonate deposits based on New Zealand Cenozoic limestones     

Shaun Hayton  Campbell S. Nelson  Steven D. Hood 《Sedimentary Geology》1995,100(1-4)

Cenozoic limestones in New Zealand are mainly skeletal grainstones and packstones formed under non-tropical climatic conditions in open marine shelf or ramp environments. Following petrographic analysis of the nature and abundance of the skeletal components in nearly 500 samples of these limestones, a complete linkage cluster analysis identified seven major skeletal assemblages that may be regarded as subdivisions of the single foramol skeletal association defined by Lees and Buller (1972) for temperate-region carbonate deposits. The seven assemblages are given contracted names, as follows: (a) BARNAMOL = barnacle/bivalve-dominated; (b) BIMOL = bivalve-dominated; (c) BRYOMOL = bryozoan/bivalve-dominated; (d) ECHINOFOR = echinoderm/benthic foraminiferal-dominated; (e) NANNOFOR = nannofossil/planktonic foraminiferal-dominated; (f) RHODALGAL = calcareous red algal-dominated; and (g) RHODECHFOR = calcareous red algal/echinoderm/benthic foraminiferal-dominated. A composite triangular classification diagram has been devised for naming the skeletal assemblage of an unknown sample on the basis of its three main skeletal components. The diagram successfully characterises more than 85% of the New Zealand Cenozoic limestone samples and also appears to be applicable for the skeletal assemblage designation of many overseas examples of non-tropical carbonate deposits. Limitations relate mainly to locally common skeletal types (e.g. serpulids, brachiopods) that are presently not incorporated into the New Zealand-based scheme. The general ecological preferences of the main skeletal contributors in each of the seven skeletal assemblages form a basis for relating the assemblages to broad shelf habitats. Consequently, as well as the benefits of providing a more consistent skeletal assemblage terminology for comparative studies between different workers, the scheme can assist with the paleoenvironmental interpretation of non-tropical skeletal carbonate facies.  相似文献   

Elucidation of the Alum Shale kerogen structure using a multi-disciplinary approach     

Sunil Bharati  Richard L. Patience  Steve R. Larter  Guy Standen  Iain J. F. Poplett 《Organic Geochemistry》1995,23(11-12)

The significance and validity of integrating data obtained from a variety of analytical techniques to understand, elucidate and model kerogen's complex chemical structure is reported here using degradative (open and closed system pyrolysis, chemical oxidation), non-degradative (¹³C CP/MAS NMR) and optical (incident white light and blue light) methods. Seven Cambrian Alum Shale samples, ranging in maturity from immature to post-mature with respect to petroleum generation, were studied and were chosen for their simple geological history, uniform organic matter type and high organic carbon content. The Alum Shale kerogens, which primarily consist of algal organic matter, liberate low molecular weight gaseous and aromatic compounds on pyrolysis and give mostly branched dicarboxylic acids on chemical oxidation. ¹³C NMR spectroscopy shows that the Alum Shale kerogens are anomalously rich in oxygen-bearing functional groups (such as C = O, ArCO, CHO, CH_xO), most of which apparently remain intact within the kerogen macro-molecule (KMM) through the diagenetic and catagenetic stages. Fragments released by different degradative techniques are quantified and the aromaticity (f_a), O/C and relative proportions of various carbon types estimated by ¹³C NMR. A synthesis of these data has allowed us to better understand the chemistry of the Alum Shale kerogen.  相似文献