The distribution of sulfur and organic matter in various fractions of peat: origins of sulfur in coal     

Daniel J. Casagrande  Kathy Gronli  Nell Sutton 《Geochimica et cosmochimica acta》1980,44(1):25-32

The peat-forming systems of the Okefenokee Swamp are viewed as modern progenitors of coal. Taxodium and Nymphaea-derived peat-forming systems were characterized in terms of (1) organic fractions and (2) the distribution of organic/inorganic sulfur in each organic fraction (water soluble, benzene/methanol soluble, humin, humic acid, fulvic acid). The humin fraction is the largest organic fraction in both environments, approaching 70% of the total organic matter in the Nymphaea-derived environment. Humin origins are discussed in terms of a humic acid precursor, and undecomposed plant material. It is suggested that each depth of peat represents a diagenetic history of events which the authors believe occurred primarily when the currently buried peat was at the surface. The sulfur content of both peat-forming areas is low (0.23–0.27%); organic sulfur is the dominant sulfur form. Humin contains 50–80% of the total sulfur and of this, 80% is organic sulfur. Ester-sulfate appears to be especially prevalent in the fulvic acid fraction. The sulfur content of freshwater-derived peats is similar in quantity and distribution to that found in low sulfur coals.  相似文献   

A Nitrogen Powered Continuous Delivery, All-Glass-Teflon Pumping System for Ground-Water Sampling from Below 10 Meters     

M. B. Tomson  Steve Hutchinsa  Joe M. Kingb  C. H. Warda 《Ground water》1980,18(5):444-446

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Paleomagnetic evidence of northward movement of the Pacific plate in deep-sea cores from the Central Pacific Basin     

S.R. Hammond  F. Theyer  G.H. Sutton 《Earth and Planetary Science Letters》1974,22(1):22-28

Seven deep-sea sediment cores recovered in the central equatorial Pacific collectively span a magneto- and biostratigraphically determined age interval ranging from about 0.1 to 21 m.y. B.P. Measured values of paleomagnetic inclination and their systematic variation with depth in these cores denote relative motion between the central Pacific lithosphere and the magnetic field of the earth. Assuming that the position of the earth's dipole field remained essentially parallel to the present spin axis during the interval, the data provide evidence of a marked decrease in the northward rate of plate motion from about 11 cm/yr to about 6 cm/yr at approximately 12 m.y. B.P. This date of change of motion as well as the northward direction and overall average rate of about 8 cm/yr throughout the last 21 m.y., agree reasonably well with results of other studies of the tectonic history of the Pacific plate and ridge system. More significantly, however, these preliminary results demonstrate the usefulness of the paleomagnetic record in deep-sea sediment cores spanning sufficiently long intervals of time as an aid in reconstructing plate motions.  相似文献   

Sensitivity of the global atmospheric cycle of mercury to emissions     

Kristen Lohman  Christian Seigneur  Mae Gustin  Steve Lindberg 《Applied Geochemistry》2008

A systematic investigation of the impact of current uncertainties in Hg emissions from specific source categories on global air Hg concentrations is presented. First, the uncertainties in different emission source categories are discussed and then the results of a base simulation and three sensitivity simulations conducted with a global chemical transport model for mercury (CTM-Hg) are presented. The total Hg emissions in the four scenarios range from 6600 to 9400 Mg/a. The sensitivity studies investigate the impact of the range in uncertainty in natural emissions, emissions of previously deposited Hg, and anthropogenic emissions both in China and worldwide, while taking into account constraints imposed by available data (current/pre-industrial emission ratio of 2–4). In one case, natural emissions and emissions of previously deposited Hg were changed to represent a mid point of the range of values found in the literature. This lead to a 16% increase in background emissions, i.e., natural emissions and emissions of previously deposited Hg combined. Increasing natural emissions by 16% or Chinese anthropogenic emissions by 100% yielded atmospheric Hg concentrations comparable with those measured across the globe without any changes to the atmospheric chemistry. Increasing natural emissions and emissions of previously deposited Hg by 16% and all anthropogenic emissions by 100% as compared to the base scenario yielded atmospheric Hg concentrations that were not compatible with measurements and changes in the chemical behavior of Hg in the atmosphere would be required to yield results that are consistent with observed Hg concentrations. The current uncertainty in total Hg emissions at the global scale is placed at about a factor of two.  相似文献   

Geotechnical and mineralogical characteristics of marl deposits in Jordan   总被引：1，自引：0，他引：1  

Fathi M. Shaqour  Ghaleb Jarrar  Steve Hencher  Mostafa Kuisi 《Environmental Geology》2008,55(8):1777-1783

Marls and marly limestone deposits cover most of Northern Jordan, where Amman City and its suburbs are located. These deposits serve as foundations for most buildings and roads as well as fill material for structural back filling, especially road bases and sub-bases. The present study aims at investigating the geotechnical characteristics and mineral composition of the marl units of these deposits through field investigations and laboratory testing. Using X-ray diffraction technique along with chemical analysis, representative samples of marl horizons were tested for mineral composition, and for a set of index and geotechnical properties including: specific gravity, grain size, Atterberg limits, Proctor compaction and shear strength properties. The test results show a positive linear relationship as expected between the clay content and both liquid and plastic limits. The tests results also show an inverse linear relationship between the clay content and the maximum dry density in both standard and modified compaction. This is attributed to the adsorption of water by the clay minerals. The relationship is more prominent in the case of modified compaction test. The results also indicate a similar relationship for the angle of internal friction. No clear correlation between cohesion and clay content was apparent.  相似文献   

Lithological controls on biological activity and groundwater chemistry in Quaternary sediments     

Rebecca Bartlett  Simon H. Bottrell  Karen Sinclair  Steve Thornton  Ian D. Fielding  Dave Hatfield 《水文研究》2010,24(6):726-735

Depth profiles of solute chemistry and sulfate isotopic compositions are presented for groundwater and pore water in a sequence of Quaternary glacial outwash sediments. Sand units show evidence for hydraulic connection to the surface and thus modern sources of solutes. Finer‐grained sediments show a general pattern of increasing solute concentrations with depth, with sulfate derived from ancient rainwater and pyrite oxidation in the soil/drift. In these sediments sulfate has undergone bacterial sulfate reduction (BSR) to produce biogenic sulfide. In clay sediments, with d₁₀ ≤ 1·6 µm, high concentrations of sulfate and acetate now co‐exist, implying that BSR is inhibited. The correlation with smaller sediment grain size indicates that this is due to pore size exclusion of the sulfate reducing bacteria. Mechanical restriction of microbial function thus provides a fundamental limitation on microbial respiration in buried clay‐rich sediments, which acts as a control on the chemical evolution of their pore waters. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Holocene climate and glacial history of the northeastern Antarctic Peninsula: the marine sedimentary record from a long SHALDRIL core     

Bradley R. Michalchuk  John B. Anderson  Julia S. Wellner  Patricia L. Manley  Wojciech Majewski  Steve Bohaty 《Quaternary Science Reviews》2009,28(27-28):3049-3065

A high-resolution record of Holocene deglacial and climate history was obtained from a 77 m sediment core from the Firth of Tay, Antarctic Peninsula, as part of the SHALDRIL initiative. This study provides a detailed sedimentological record of Holocene paleoclimate and glacial advance and retreat from the eastern side of the peninsula. A robust chronostratigraphy was derived from thirty-three radiocarbon dates on carbonate material. This chronostratigraphic framework was used to establish the timing of glacial and climate events derived from multiple proxies including: magnetic susceptibility, electric resistivity, porosity, ice-rafted debris content, organic carbon content, nitrogen content, biogenic silica content, and diatom and foraminiferal assemblages. The core bottomed-out in a stiff diamicton interpreted as till. Gravelly and sandy mud above the till is interpreted as proximal glaciomarine sediment that represents decoupling of the glacier from the seafloor circa 9400 cal. yr BP and its subsequent landward retreat. This was approximately 5000 yr later than in the Bransfield Basin and South Shetland Islands, on the western side of the peninsula. The Firth of Tay core site remained in a proximal glaciomarine setting until 8300 cal. yr BP, at which time significant glacial retreat took place. Deposition of diatomaceous glaciomarine sediments after 8300 cal. yr BP indicates that an ice shelf has not existed in the area since this time.The onset of seasonally open marine conditions between 7800 and 6000 cal. yr BP followed the deglacial period and is interpreted as the mid-Holocene Climatic Optimum. Open marine conditions lasted until present, with a minor cooling having occurred between 6000 and 4500 cal. yr BP and a period of minor glacial retreat and/or decreased sea ice coverage between 4500 and 3500 cal. yr BP. Finally, climatic cooling and variable sea ice cover occurred from 3500 cal. yr BP to near present and it is interpreted as being part of the Neoglacial. The onset of the Neoglacial appears to have occurred earlier in the Firth of Tay than on the western side of the Antarctic Peninsula. The Medieval Warm Period and Little Ice Age were not pronounced in the Firth of Tay. The breadth and synchroneity of the rapid regional warming and glacial retreat observed in the Antarctic Peninsula during the last century appear to be unprecedented during the Holocene epoch.  相似文献   

Interpreting characteristic drainage timescale variability across Kilombero Valley,Tanzania   总被引：1，自引：0，他引：1       下载免费PDF全文

Steve W. Lyon  Alexander Koutsouris  Friedemann Scheibler  Jerker Jarsjö  Rene Mbanguka  Madaka Tumbo  Keven K. Robert  Asha N. Sharma  Ype van der Velde 《水文研究》2015,29(8):1912-1924

We explore seasonal variability and spatiotemporal patterns in characteristic drainage timescale (K) estimated from river discharge records across the Kilombero Valley in central Tanzania. K values were determined using streamflow recession analysis with a Brutsaert–Nieber solution to the linearized Boussinesq equation. Estimated K values were variable, comparing between wet and dry seasons for the relatively small catchments draining upland positions. For the larger catchments draining through valley bottoms, K values were typically longer and more consistent across seasons. Variations in K were compared with long‐term averaged, Moderate‐resolution Imaging Spectroradiometer‐derived monthly evapotranspiration. Although the variations in K were potentially related to evapotranspiration, the influence of data quality and analysis procedure could not be discounted. As such, even though recession analysis offers a potential approach to explore aquifer release timescales and thereby gain insight to a region's hydrology to inform water resources management, care must be taken when interpreting spatiotemporal shifts in K in connection with process representation in regions like the Kilombero Valley. © 2014 The Authors. Hydrological Processes published by John Wiley & Sons Ltd.  相似文献   

Geographically weighted methods and their use in network re-designs for environmental monitoring   总被引：3，自引：3，他引：0  

Paul Harris  Annemarie Clarke  Steve Juggins  Chris Brunsdon  Martin Charlton 《Stochastic Environmental Research and Risk Assessment (SERRA)》2014,28(7):1869-1887

Given an initial spatial sampling campaign, it is often of importance to conduct a second, more targeted campaign based on the properties of the first. Here a network re-design modifies the first one by adding and/or removing sites so that maximum information is preserved. Commonly, this optimisation is constrained by limited sampling funds and a reduced sample network is sought. To this extent, we demonstrate the use of geographically weighted methods combined with a location-allocation algorithm, as a means to design a second-phase sampling campaign in univariate, bivariate and multivariate contexts. As a case study, we use a freshwater chemistry data set covering much of Great Britain. Applying the two-stage procedure enables the optimal identification of a pre-specified number of sites, providing maximum spatial and univariate/bivariate/multivariate water chemistry information for the second campaign. Network re-designs that account for the buffering capacity of a freshwater site to acidification are also conducted. To complement the use of basic methods, robust alternatives are used to reduce the effect of anomalous observations on the re-designs. Our non-stationary re-design framework is general and provides a relatively simple and a viable alternative to geostatistical re-design procedures that are commonly adopted. Particularly in the multivariate case, it represents an important methodological advance.  相似文献   

中国-巴基斯坦喀喇昆仑公路Ghulkin冰川百年进退变化     

廖丽萍  朱颖彦  杨志全  Muhammad Waseem  Steve Zou  陈济丁  王云  叶成银  张学进 《冰川冻土》2013,35(6):1391-1399

巴基斯坦喀喇昆仑山的Ghulkin冰川是距离中国-巴基斯坦喀喇昆仑公路最近的典型冰川之一,其冰川的进退变化影响着喀喇昆仑公路改建工程的线路设计与工程施工.为了追溯Ghulkin冰川的活动历史和查明近期进退变化,对过去200 a的相关文献和记录进行统计分析,并开展了2008-2011年野外定点观测,总结与分析了Ghulkin冰川冰舌的活动历史与近期变化.研究表明：Ghulkin冰川在1885-1980年近百年间经历了3次前进和3次后退,在此期间冰川波动了625 m;1913-1925年冰川处于显著的前进状态,1966-1978年冰川有小段距离的前进;2008-2011年K676+660处泥石流沟道逐年抬升,2011年南坡冰川融水由K676+660改道至K676+450;2010年的南坡冰舌较1994年后退了300余米,2011年的南坡冰舌较2010年后退了15.066 m,可见在2010-2011年期间冰川处于局部短期后退状态. 中巴公路冰川泥石流等灾害不但受区域气候的影响,而且还受冰川变化的影响.未来气候变暖将会导致冰川的强烈消融和后退,冰川融水携带大量冰碛体,形成大型的冰川泥石流,对公路的安全运营造成严重威胁.  相似文献