Iron oxides in comet 81P/Wild 2     

John C. BRIDGES  Mark J. BURCHELL  Hitesh C. CHANGELA  Nick J. FOSTER  J. Alan CREIGHTON  James D. CARPENTER  Steve J. GURMAN  Ian A. FRANCHI  Henner BUSEMANN 《Meteoritics & planetary science》2010,45(1):55-72

Abstract– We have used synchrotron Fe‐XANES, XRS, microRaman, and SEM‐TEM analyses of Stardust track 41 slice and track 121 terminal area slices to identify Fe oxide (magnetite‐hematite and amorphous oxide), Fe‐Ti oxide, and V‐rich chromite (Fe‐Cr‐V‐Ti‐Mn oxide) grains ranging in size from 200 nm to ～10 μm. They co‐exist with relict FeNi metal. Both Fe‐XANES and microRaman analyses suggest that the FeNi metal and magnetite (Fe₂O₃FeO) also contain some hematite (Fe₂O₃). The FeNi has been partially oxidized (probably during capture), but on the basis of our experimental work with a light‐gas gun and microRaman analyses, we believe that some of the magnetite‐hematite mixtures may have originated on Wild 2. The terminal samples from track 121 also contain traces of sulfide and Mg‐rich silicate minerals. Our results show an unequilibrated mixture of reduced and oxidized Fe‐bearing minerals in the Wild 2 samples in an analogous way to mineral assemblages seen in carbonaceous chondrites and interplanetary dust particles. The samples contain some evidence for terrestrial contamination, for example, occasional Zn‐bearing grains and amorphous Fe oxide in track 121 for which evidence of a cometary origin is lacking.  相似文献   

Non-destructive xrf characterization of basaltic artifacts from Truckee,California     

Thomas S. Latham  Paula A. Sutton  Kenneth L. Verosub 《Geoarchaeology》1992,7(2):81-101

We have developed a new approach to the problem of the chemical fingerprinting of artifacts manufactured from volcanic rocks of basaltic and andesitic composition. The method is an adaptation of standard energy-dispersive X-ray fluorescence spectrometry and is based on the observation that for irregularly-shaped rock fragments, the ratios of the intensities of the characteristic X-rays of certain trace elements are proportional to the ratios of the concentrations of those elements. This observation has allowed us to obtain geochemical data about the artifacts in a way that is rapid, inexpensive, and nondestructive, making it particularly suited to archaeological applications. We have used our approach to compare a suite of artifacts from an archaeological site in Martis Valley, near Truckee, California, with a group of lava flows from the surrounding area. Using a numerical measure of the geochemical difference between samples, we have been able to group the artifacts on the basis of their geochemistry, to determine which artifacts were manufactured from material found in Martis Valley and, in at least one case, to identify the lava flow that was the actual source of the lithic material for several of the artifacts.  相似文献