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P. Beck E. Quirico L. Bonal F.-R. Orthous-Daunay B. Schmitt F. Deschamps S. Guillot 《Geochimica et cosmochimica acta》2010,74(16):4881-494
IR spectroscopy is one of the few techniques that can directly probe water molecules in rocks. This method has been used to characterize the mineralogy of hydrated/hydrous carbonaceous chondrites, and to link known meteorite families with spectroscopic observations of low albedo asteroids. In this paper, we present measurements of the infrared transmission spectra of matrix chunks from 3 CI and 9 CM chondrites. Spectra were measured at ambient conditions and then at different temperatures along a dehydration path toward high-T (∼300 °C) under primary vacuum. At ambient conditions, the 3-μm spectral range is always dominated by adsorbed atmospheric water molecules. Upon moderate (∼100 °C) and high (∼300 °C) heating under low pressure (P < 10−4 mbar), adsorbed water and then phyllosilicates interlayer water are removed, revealing a residual absorption band around 3 μm. This band is a characteristic IR feature of the phyllosilicate phases which dominate the mineralogical assemblage of hydrated carbonaceous chondrites. Among the CM chondrites, the high-T spectra reveal a strong variability that appears correlated with the alteration classification scheme of Rubin et al. (2007) and Howard et al. (2009a). The 3-μm band continuously evolves from a broad feature peaking at 3550-3600 cm−1 for the weakly altered CMs (Murchison-type) to a sharp asymmetric peak at ∼3675 cm−1 for the more extensively altered samples (Cold Bokkeveld-type). We attribute this spectral evolution to variations in the chemistry of the phyllosilicate phases from Fe-rich to Mg-rich. On the other hand, the 10-μm spectral region shows a single broad peak which does not compare with known terrestrial serpentine spectra, probably due to high structural disorder of the chondrite phyllosilicate phases. The present work clearly shows that previously published reflectance spectra of chondrites are biased by the presence of adsorbed terrestrial water molecules. Laboratory data collected under dry conditions are needed to reinterpret the chondrite-asteroid connection from the comparison of their 3-μm absorption features. 相似文献
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François Guillot Urs Schaltegger Jean-Michel Bertrand Étienne Deloule Thierry Baudin 《International Journal of Earth Sciences》2002,91(6):964-978
Among the Middle Penninic basements of the Internal NW-Alps, the Ruitor massif shows the best preserved remnants of pre-Permian metamorphic rocks. Their Barrovian-type mineral associations are somewhat masked by the greenschist to blueschist Alpine metamorphism of Tertiary age. Four Ruitor gneisses have been analysed, showing geochemical characters of granitoids from orogenic zones. Zircon morphology also suggests magmatic protoliths and a crustal source; some of the morphological zircon types suggest anatectic granites. The first U-Pb ages on zircon for this massif have been obtained concurrently through conventional multigrain and ion microprobe dating. Two metavolcanic rocks at 471LJ and 468ᆪ Ma could be slightly older than the porphyritic augen gneisses at 465ᆟ and 460lj Ma. Regional data from the other Internal basement massifs suggest that the Variscan event is poorly recorded, except in Ruitor-type units. Ruitor and Sapey gneisses belonged to the same unit (Nappe des Pontis), which was affected by a 480-450-Ma event including volcanism and anatexis and ended with a late calc-alkaline granite emplacement at 460-450 Ma. The distribution of Variscan basement units roughly parallels Alpine zonation. 相似文献
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New fission‐track ages on zircon and apatite (ZFT and AFT) from the south‐western internal Alps document a diachronous cooling history from east to west, with cooling rates of 15–19 °C Ma−1. In the Monviso unit, the ZFT ages are 19.6 Ma and the AFT ages are 8.6 Ma. In the eastern Queyras, ZFT ages range from 27.0 to 21.7 Ma and AFT ages from 14.2 to 9.4 Ma. In the western Queyras, ZFT ages are between 94.7 and 63.1 Ma and AFT ages are between 22.2 and 22.6 Ma. The Chenaillet ophiolite yields ages of 118.1 Ma on ZFT and 67.9 Ma on AFT. The combination of these new FT data with the available petrological and geochronological data emphasize an earlier exhumation in subduction context before 30 Ma, then in collision associated with westward tilting of the Piedmont zone. 相似文献
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A crustal‐scale cross‐section of the south‐western Alps combining geophysical and geological imagery
J.M. Lardeaux S. Schwartz P. Tricart A. Paul S. Guillot N. Bthoux F. Masson 《地学学报》2006,18(6):412-422
A geotransect across the south‐western Alps from the Pelvoux Massif (external French Alps) to the Dora‐Maira massif (internal Italian Alps), through the Monviso ophiolitic complex, was investigated in the framework of the ‘Géo‐France 3D Alpes’ programme. A new interpretative crustal‐scale section across the south‐western Alps is proposed, combining geological and geophysical 2D/3D data. The Apulian mantle (i.e. the Ivrea body) might be divided into two rigid pieces separated by the downward prolongation of the Penninic frontal thrust. These mantle indenters drive the decoupling of the European crust. Beneath the high to ultra‐high pressure metamorphic nappes, the deep structure results from the stacking of crustal slices extracted from the European lithosphere. The proposed structural model provides a basis for discussing the evidence of the crustal‐scale partitioning of the current strain pattern as well as the location of the seismicity. 相似文献
46.
R-P. Mnot A. Pêcher Y. Rolland J-J. Peucat A. Pelletier G. Duclaux S. Guillot 《Gondwana Research》2005,8(1):1-9
Geological maps of East Commonwealth Bay Unit (ECB), (Terre Adélie and Georges V Land, Antarctica) are presented with a summary of the main structural and metamorphic data for the region. The ECB unit was developed during Neoarchean_Paleoproterozoic event (at 2.5-2.42 Ga), with (i) granulite metamorphism at 9±1.5 kbar and 800±50°C in the lower crust section and amphibolite metamorphism (P=5 kbar, T=750°C) at the upper crustal levels; (ii) the lower crustal granulites were uplifted, and suffered local partial melting and retrogression to the amphibolite facies at 550±50°C_5 kbar. Granulites were extruded in the core of a crustal-scale anticlinal fold, but retrogressed only on the rims of the anticline. Crustal-scale folding, along with other structural features resulted from intense NE-SW shortening that prevailed during the Neoarchean orogenic cycle. Strike-slip and extensional motions were only minor components in that process; (iii) top-to-the-East thrusting and nappe piling had (at least locally) occurred under lower amphibolite to greenschist facies conditions. Finally, it seems that (iv) the Paleoproterozoic 1.7 Ga structural imprint may have only affected the rims of the Archean units. The tectonic context observed in the 1.7 Ga Cape Hunter phyllites features mainly an E-W shortening component and vertical extrusion. The eastern (Mertz) and western (Port Martin) parts of the Archean block were reactivated by localized dextral shearing. 相似文献