The origin and isotopic composition of dissolved sulfide in groundwater from carbonate aquifers in Florida and Texas     

R.O. Rye  William Back  B.B. Hanshaw  C.T. Rightmire  F.J. Pearson 《Geochimica et cosmochimica acta》1981,45(10):1941-1950

The δ³⁴S values of dissolved sulfide and the sulfur isotope fractionations between dissolved sulfide and sulfate species in Floridan ground water generally correlate with dissolved sulfate concentrations which are related to flow patterns and residence time within the aquifer. The dissolved sulfide derives from the slow in situ biogenic reduction of sulfate dissolved from sedimentary gypsum in the aquifer. In areas where the water is oldest, the dissolved sulfide has apparently attained isotopic equilibrium with the dissolved sulfate (Δ³⁴S = 65 per mil) at the temperature (28°C) of the system. This approach to equilibrium reflects an extremely slow reduction rate of the dissolved sulfate by bacteria; this slow rate probably results from very low concentrations of organic matter in the aquifer.In the reducing part of the Edwards aquifer, Texas, there is a general down-gradient increase in both dissolved sulfide and sulfate concentrations, but neither the δ³⁴S values of sulfide nor the sulfide-sulfate isotope fractionation correlates with the ground-water flow pattern. The dissolved sulfide species appear to be derived primarily from biogenic reduction of sulfate ions whose source is gypsum dissolution although upgradient diffusion of H₂S gas from deeper oil field brines may be important in places. The sulfur isotope fractionation for sulfide-sulfate (about 38 per mil) is similar to that observed for modern oceanic sediments and probably reflects moderate sulfate reduction in the reducing part of the aquifer owing to the higher temperature and significant amount of organic matter present; contributions of isotopically heavy H₂S from oil field brines are also possible.  相似文献   

Dating of post-glacial landforms in the central howgills     

A. M. Harvey  F. Oldfield  A. F. Baron  G. W. Pearson 《地球表面变化过程与地形》1981,6(5):401-412

Little is known of Holocene landform development in Upland Britain. This paper describes a site at Middle Langdale in the Howgill Fells of Cumbria where large, but now stabilized and inactive gullies cut through periglacial material. At the base of the gullies large debris cones have buried earlier alluvial sediments on the valley floor. On these sediments and buried by the debris cones is a well-developed organic soil from which two ¹⁴C dates have been obtained in an attempt to estimate the age range of the soil. These dates range from 2580±55 years BP for the fine particulate fraction from the base of the organic horizon to 940±95 years BP for fossil rootlets from the uppermost organic layer, immediately below the overlying debris cones. The pollen evidence suggests that the valley floor site was initially dominated by alder carr and later by a Juncus marsh with birch, alder and hazel nearby. The pollen, from the surrounding upland area suggests woodland on the valley sides, dominated by oak and elm that was later replaced by a more open environment rich in heath species and in which disturbed ground species were present. The magnetic evidence indicates a stable local environment during soil formation but shows a sudden inwash of unweathered debris at the top of the buried soil. The evidence suggests that the valley floor was geomorphologically stable throughout the period of soil formation, although there was a local change in valley floor vegetation and a reduction of woodland cover on the valley sides at sometime during the period. The evidence then points to major geomorphological changes; a wave of soil erosion, gully development and debris cone deposition, perhaps following the Scandinavian introduction of sheep farming in the tenth century A.D.  相似文献   

Spectral Analysis in Geophysics: M. Båth. Developments in Solid Earth Geophysics no. 7. Elsevier,Amsterdam, 1974, 570 pp., 101 fig., Dfl. 120.00     

Stuart Crampin 《Tectonophysics》1975,27(1):83-84

  相似文献   

A discussion on models of thermals     

Robert A. Pearson 《Pure and Applied Geophysics》1980,118(2):913-934

For a thermal starting from rest, the scales of motion consistent with the initial conditions are given. An alternative time scale based on the motion of the thermal is derived. The anticipated similarity solutions for thermals are summarised and possible qualitative differences between solutions are given. Within this consistent framework previously published laboratory and numerical models of thermals are discussed. Reasons why numerical models have not rigorously demonstrated the existence of a self-similarity solution are considered. Comparisons of all available results show that a single similarity solution valid for all thermals does not exist.  相似文献   

Polycyclic aromatic hydrocarbons in Recent lake sediments—I. Compounds having anthropogenic origins     

Stuart G. Wakeham  Christian Schaffner  Walter Giger 《Geochimica et cosmochimica acta》1980,44(3):403-413

Polycyclic aromatic hydrocarbons (PAH) in sediment cores from Lake Lucerne, Lake Zürich, and Greifensee, Switzerland, and Lake Washington, northwest U.S.A., have been isolated, identified and quantified by glass capillary gas chromatography and gas chromatography/mass spectrometry. Surface sediment layers are greatly enriched in PAH—up to 40 times—compared to deeper layers. In addition, concentration increases in upper sediments generally correspond to increasing industrialization and urbanization in the catchment basins of the lakes. Few PAH could be detected in pre-industrial revolution sediments, indicating that background levels for most PAH in aquatic sediments are extremely low.These results are consistent with an anthropogenic source for most of the aromatic hydrocarbons present in the modern sediments. A comparison of PAH distributions in the sediments and in possible source materials shows that urban runoff of street dust may be the most important PAH input to these lacustrine sediments. There is evidence that a significant contribution to the PAH content of street dust comes from material associated with asphalt.  相似文献   

Poly cyclic aromatic hydrocarbons in Recent lake sediments—II. Compounds derived from biogenic precursors during early diagenesis     

Stuart G. Wakeham  Christian Schaffner  Walter Giger 《Geochimica et cosmochimica acta》1980,44(3):415-429

  相似文献   

PCBs in the Hudson River     

Stuart G Wakeham 《Marine pollution bulletin》1976,7(11):206-211

Hydrocarbon distribution in sediments from three lakes are related to the level of human activity in the respective drainage basins. Petroleum hydrocarbon contamination is found in surface sediments of a lake surrounded by a major city, compared to no detectable contamination in a lake located in a National Park.  相似文献   

Completing the loop: from data to decisions and back to data     

Stuart Hamilton 《水文研究》2007,21(22):3105-3106

  相似文献   

The correlation between the distribution of galaxies and 21-cm emission at high redshifts     

J. Stuart B. Wyithe  Abraham Loeb 《Monthly notices of the Royal Astronomical Society》2007,375(3):1034-1042

  相似文献   

Erratum to: “A robust surface matching technique for coastal geohazard assessment and management” [ISPRS J. Photogramm. Remote Sens. 63 (2008) 529–542]     

Pauline Miller  Jon Mills  Stuart Edwards  Paul Bryan  Stuart Marsh  Harvey Mitchell  Peter Hobbs 《ISPRS Journal of Photogrammetry and Remote Sensing》2009,64(2):243-245

  相似文献