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41.
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Mössbauer measurements at 300 K, 77 K and 4.2 K and X-ray data are presented for synthetic aluminous goethites (α Fe1?x Al x OOH) in two series containing up to 15 mole percent aluminium (hydrothermal preparation) and 19 mole percent aluminium (low-temperature preparation). The Mössbauer spectra for specimens at 300 K and 77 K display broadened and relaxed line-shapes with the relaxation rate increasing with aluminium substitution, whereas all the 4.2 K spectra can be described by a single magnetically split spectrum. At 4.2 K the magnitude of this splitting is 505 kOe for pure goethite and it decreases by 0.52 kOe per mole percent aluminium substitution. The absolute value of the recoil-free fraction f at 4.2 K has been measured for pure goethite and for aluminous goethites containing 7, 15 and 19 mole percent aluminium; it increases from f=0.69±0.02 to f=0.89±0.02 in this range. The increase is attributed to a stiffening of the goethite lattice as it contracts to accommodate the smaller aluminium ion. At 300 K f is found to decrease from f=0.65±0.05 for pure goethite to f=0.50±0.03 for goethite with 19 mole percent aluminium.  相似文献   
43.
A static renewal toxicity test was conducted to evaluate the response of the copepod Acartia tonsa to bis(tributyltin) oxide (TBTO), the active compound of recently developed antifouling paints. Copepods were individually placed in test tubes containing 4 ml of 0.3, 0.5, 1.0, 1.7 or 3.0 μg l?1 TBTO with acetone and seawater. Thirty copepods were used for each treatment and control condition and all solutions were renewed daily. The 96-h LC50 was 1.0 μg l?1 with a 95% confidence interval between 0.8 and 1.2 μg l?1 TBTO. The 144-h EC50 was 0.4 μg l?1 TBTO which approaches concentrations recently measured in San Diego Bay. Some copepods exposed to 0.3 μg l?1 TBTO became moribund after six days.  相似文献   
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This paper is concerned with the application of fractal analysis to understand the structure of water-worked gravel-bed river surfaces. High resolution digital elevation models, acquired using digital photogrammetric methods, allowed the application of two-dimensional fractal methods. Previous gravel-bed river studies have been based upon sampled profiles and hence one-dimensional fractal characterisation. After basic testing that bed elevation increments are Gaussian, the paper uses two-dimensional variogram surfaces to derive directionally dependent estimates of fractal dimension. The results identify mixed fractal behavior with two characteristic fractal bands, one associated with the subgrain scale and one associated with the grain scale. The subgrain scale characteristics were isotropic and sensitive to decisions made during the data collection process. Thus, it was difficult to differentiate whether these characteristics were real facets of the surfaces studied. The second band was anisotropic and not sensitive to data collection issues. Fractal dimensions were greater in the downstream direction than in other directions suggesting that the effects of water working are to alter the level of surface organisation, by increasing surface irregularity and hence roughness. This is an important observation as it means that water-worked surfaces may have a distinct anisotropic signal, revealed when using a fractal type analysis.  相似文献   
46.
This study presents the results of numerical simulations of a model for lithospheremantle coupling in a terrestrial type planet. To first order, a geologically active terrestrial type planet may consist of a metallic core, silicate mantle and lithosphere, with the lithosphere being rheologically different from the mantle. Therefore we have developed a numerical model consisting of a thin non-Newtonian fluid hoop that is dynamically coupled to a thick Newtonian fluid cylindrical annulus. Thus the rheological dichotomy between mantle and lithosphere is built into the model. Time-dependent calculations show the existence of at least two regimes of behaviors. In one regime, the behavior of the hoop switches between periods characterized by low or high speeds, in response to changes in convective vigor and planform. This regime may apply to the planet Venus where the available evidence indicates that prior to 500 myr ago, the planet was resurfaced on a time scale of <100 myr. Since that time, large-scale tectonic activity on Venus has been sharply curtailed. In the other regime, which is more like plate tectonics on Earth, the hoop speeds rise and fall on short time scales.  相似文献   
47.
In HEXOS, a programme of coordinated laboratory, field and model studies, an international group of participants has extended the range of measurements of evaporation from the sea and has investigated the role of droplets in the transfer of water to the atmosphere. Predictions of a rapid rise in the evaporation coefficient at wind speeds above 15 m s-1 have not been substantiated. Wind stress measurements showed a relationship with wave age. New methods were developed for coping with flow distortion.  相似文献   
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The mid Hudson River is a heterotrophic system where allochthonous inputs apparently fuel the largest proportion of secondary production and ecosystem metabolism. We have analyzed a 6-yr dataset collected quarterly at six stations spanning a 150-km reach to assess variability at inter- and intra-annual time scales and regional spatial scales. The major components of the lower food web: bacterial biomass, detrital particulate organic carbon (POC), and dissolved organic carbon (DOC), show surprisingly discordant patterns in temporal and spatial variability. Bacterial abundance shows significant variability at all three scales, but the interannual variability is by far the greatest. DOC concentrations showed greatest variability among years, with intra-annual and spatial variability roughly equal. Freshwater flow is commonly considered a major driving force in river-estuarine variability but simple discharge was not a strong predictor of any component of suspended matter or DOC. For organisms in the Hudson River food web, these multiple scales of variability indicate highly unpredictable food resources in time and space, and these fluctuations may contribute to the variability in higher trophic levels.  相似文献   
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