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31.
This paper examines historical and spatial trends in hazardous materials transportation spills from 1971 to 1991. While the number of spills Inc.reased steadily during the 1970s, peaking in 1978–1979, there has been a decline in frequency sInc.e then largely due to modifications in reporting. Monetary damages have the opposite temporal pattern, with major Inc.reases recorded from 1982 onward. Death and injury statistics are more variable. Spatially, accidents are more prevalent in the Rust Belt extending from the Northeast corridor westward to the Great Lakes states, as well as in the Southeast. The greatest potential risk to the public is found in smaller, more densely populated industrial states such as New Jersey, Delaware, and Maryland. The spatial distribution, however, has not changed. Potential risk sources (e.g., chemical industry, number of hazardous waste facilities, number of railroad miles) are the best predictors of hazmat Inc.ident frequency. Mitigation efforts (statewide regulatory and/or management policies) also help explain the variability in hazmat Inc.idents.  相似文献   
32.
The shelf-break acts as a separator between the coastal ocean and the open ocean. Circulation (particularly deep near-bottom flow) is restricted from crossing the bathymetry. Eddies become elongated in the region of the shelf-break restricting exchange. An estimate of the horizontal eddy diffusivity over the shelf-break of less than 10m2s-1 is found from a numerical model. Various mechanisms are responsible for the weak cross-isobath flow that does occur. One is the increase of the Rossby number over small-scale topography such as submarine canyons. Along-shore flow (in the direction opposite to Kelvin wave propagation) generates upwelling through submarine canyons. A review of upwelling through submarine canyons is given. The deep cross-shelf flow generated by the canyons is shown to be as significant as the wind-driven upwelling in some regions. Examples for the reduction of flow across the shelf-break and for upwelling through canyons are taken from the West Coast of Vancouver Island.  相似文献   
33.
To compare relative reaction rates of mineral dissolution in a mineralogically simple groundwater aquifer, we studied the controls on solute concentrations, Sr isotopes, and rare earth element and yttrium (REY) systematics in the Cape Cod aquifer. This aquifer comprises mostly carbonate-free Pleistocene sediments that are about 90% quartz with minor K-feldspar, plagioclase, glauconite, and Fe-oxides. Silica concentrations and pH in the groundwater increase systematically with increasing depth, while Sr isotopic ratios decrease. No clear relationship between 87Sr/86Sr and Sr concentration is observed. At all depths, the 87Sr/86Sr ratio of the groundwater is considerably lower than the Sr isotopic ratio of the bulk sediment or its K-feldspar component, but similar to that of a plagioclase-rich accessory separate obtained from the sediment. The Si-87Sr/86Sr-depth relationships are consistent with dissolution of accessory plagioclase. In addition, solutes such as Sr, Ca, and particularly K show concentration spikes superimposed on their respective general trends. The K-Sr-87Sr/86Sr systematics suggests that accessory glauconite is another major solute source to Cape Cod groundwater. Although the authigenic glauconite in the Cape Cod sediment is rich in Rb, it is low in in-grown radiogenic 87Sr because of its young Pleistocene age. The low 87Sr/86Sr ratios are consistent with equilibration of glauconite with seawater. The impact of glauconite is inferred to vary due to its variable abundance in the sediments. In the Cape Cod groundwater, the variation of REY concentrations with sampling depth resembles that of K and Rb, but differs from that of Ca and Sr. Shale-normalized REY patterns are light REY depleted, show negative Ce anomalies and super-chondritic Y/Ho ratios, but no Eu anomalies. REY input from feldspar, therefore, is insignificant compared to input from a K-Rb-bearing phase, inferred to be glauconite. These results emphasize that interpretation of groundwater chemistry, even in relatively simple aquifers, may be complicated by solute contributions from “exotic” accessory minerals such as glauconite. To detect such peculiarities, groundwater studies should combine the study of elemental concentration and isotopic composition of several solutes that show different geochemical behavior.  相似文献   
34.
Estimating severity of liquefaction-induced damage near foundation   总被引:1,自引:2,他引:1  
An empirical procedure for estimating the severity of liquefaction-induced ground damage at or near foundations of existing buildings is established. The procedure is based on an examination of 30 case histories from recent earthquakes. The data for these case histories consist of observations of the damage that resulted from liquefaction, and the subsurface soil conditions as revealed by cone penetration tests. These field observations are used to classify these cases into one of three damaging effect categories, ‘no damage’, ‘minor to moderate damage’, and ‘major damage’. The potential for liquefaction-induced ground failure at each site is calculated and expressed as the probability of ground failure. The relationship between the probability of ground failure and the damage class is established, which allows for the evaluation of the severity of liquefaction-induced ground damage at or near foundations. The procedure presented herein represents a significant attempt to address the issue of liquefaction effect. Caution must be exercised, however, when using the proposed model and procedure for estimating liquefaction damage severity, because they are developed based on limited number of case histories.  相似文献   
35.
Vegetation changes in the Jornada Basin from 1858 to 1998   总被引:1,自引:1,他引:1  
Notes made by land surveyors in 1858 were utilized to estimate cover of grasses and shrubs on the Jornada Experimental Range (JER) and the Chihuahuan Desert Range Research Center (CDRRC) in the northern Chihuahuan Desert in southern New Mexico, USA. Portions of these areas have been previously assessed for historical vegetation dynamics but the entire 84,271 ha assessed in the 19th century has not been examined in total. In 1858, fair to very good grass cover occurred on 98% and 67% of the JER and CDRRC, respectively. Shrubs were present throughout both properties but 45% of the JER and 18% of the CDRRC were shrub free. Reconnaissance surveys, made to determine carrying capacity for livestock were made in 1915–1916 and 1928–1929 on the JER and in 1938 on the CDRRC, show that shrubs had made large increases in area occupied at the time of the surveys. Vegetation type maps were made of both properties in 1998. Mesquite (Prosopis glandulosa) was the primary dominant on 59% of the JER in 1998 and creosotebush (Larrea tridentata) was the primary dominant on 27% of the area. On the CDRRC mesquite and creosotebush were primary dominants on 37% and 46% of the area, respectively. Grass cover has decreased greatly with the increase in shrubs and only shrub control efforts have maintained the once abundant black grama (Bouteloua eriopoda) as a primary dominant on 1% or less of the area on both properties.  相似文献   
36.
Although many bioessential metals are scarce in natural water and rock systems, microbial secretion of high-affinity ligands for metal extraction from solid phases has only been documented for Fe. However, we have discovered that Mo is extracted from a silicate by a high-affinity ligand (a possible “molybdophore”) secreted by an N2-fixing soil bacterium. The putative molybdophore, aminochelin, is secreted as a siderophore under Fe-depleted conditions, but is also secreted under Fe-sufficient, Mo-depleted conditions. Presumably, molybdophore production facilitates uptake of Mo for use in Mo enzymes. In contrast, an Fe-requiring soil bacterium without a special Mo requirement only enhances the release of Fe from the silicate. Fractionation of Mo stable isotopes during uptake to cells may provide a “fingerprint” for the importance of chelating ligands in such systems. Many such metal-specific ligands secreted by prokaryotes for extraction of bioessential metals, their effects on Earth materials, and their possible utility in the recovery of economic metals remain to be discovered.  相似文献   
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39.
The sky brightness is a critical parameter for estimating the coronal observation conditions for a solar observatory. As part of a site-survey project in Western China, we measured the sky brightness continuously at the Lijiang Observatory in Yunnan province in 2011. A sky brightness monitor (SBM) was adopted to measure the sky brightness in a region extending from 4.5 to 7.0 apparent solar radii based on the experience of the Daniel K. Inouye Solar Telescope (DKIST) site survey. Every month, the data were collected manually for at least one week. We collected statistics of the sky brightness at four bandpasses located at 450, 530, 890, and 940 nm. The results indicate that aerosol scattering is of great importance for the diurnal variation of the sky brightness. For most of the year, the sky brightness remains under 20 millionths per airmass before local Noon. On average, the sky brightness is less than 20 millionths, which accounts for 40.41% of the total observing time on a clear day. The best observation time is from 9:00 to 13:00 (Beijing time). The Lijiang Observatory is therefore suitable for coronagraphs investigating the structures and dynamics of the corona.  相似文献   
40.
The hydrologic response of engineered media plays an important role in determining a stormwater control measure's ability to reduce runoff volume, flow rate, timing, and pollutant loads. Five engineered media, typical of living roof and bioretention stormwater control measures, were investigated in laboratory column experiments for their hydrologic responses to steady, large inflow rates. The inflow, medium water content response, and outflow were all measured. The water flow mechanism (uniform flow vs. preferential flow) was investigated by analyzing medium water content response in terms of timing, magnitude, and sequence with depth. Modeling the hydrologic process was conducted in the HYDRUS‐1D software, applying the Richards equation for uniform flow modeling, and a mobile–immobile model for preferential flow modeling. Uniform flow existed in most cases, including all initially dry living roof media with bimodal pore size distributions and one bioretention medium with unimodal pore size distribution. The Richards equation can predict the outflow hydrograph reasonably well for uniform flow conditions when medium hydraulic properties are adequately represented by appropriate functions. Preferential flow was found in two media with bimodal pore size distributions. The occurrence of preferential flow is more likely due to the interaction between the bimodal pore structure and the initial water content rather than the large inflow rate.  相似文献   
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