The Geochemical Effects of Microbial Humic Substances Reduction     

John D. Coates  Romy Chakraborty  Susan M. O&#x;Connor  Claudia Schmidt  Jürgen Thieme 《洁净——土壤、空气、水》2001,28(7):420-427

As part of a study on microbial redox alteration of humic substances we investigated the potential effect of this metabolism on the fate of heavy metals and hydrocarbons as a result of conformational alteration of the humic molecular structure due to microbial reduction. Our studies indicate that the microbial reduction of humic acids (HA) results in significant morphological and geochemical alterations. X‐ray microscopy analysis indicate that the conformational structure of the humic colloids is altered as a result of the redox change. In the reduced state, the HA appeared as small dense particles, on reoxidation, large loose aggregates were formed. In addition, spectrofluorometric studies indicated that the binding capacity of the HA for naphthalene was decreased by 10% when the HA was reduced. Similarly, the reduced HA yielded higher surface tension values at all concentrations tested which is indicative of a more hydrophilic and less hydrophobic solute. On reoxidation, the surface tension values reverted back to values similar to those obtained for the untreated oxidized HA. These data indicate that the hydrophobicity of the HA is altered on biological reduction of the HA and that this alteration is reversible. In contrast the reduced HA demonstrated a 15% higher affinity for heavy metals such as divalent cobalt than the oxidized HA. In addition to increasing the binding capacity of HA for heavy metals, the reduction of the HA also decreased the bioavailability and toxicity of bound heavy metals such as chromium. When incubated in the presence of Cr(III) and HA, cells of Escherichia coli grew much more rapidly in the presence of the reduced HA suggesting that the higher metal binding capacity of the reduced humic substances resulted in a removal of the Cr(III) from solution and hence reduced its bioavailability and toxicity. These studies demonstrate that HA redox state and reduction of humic acids by microorganisms can have a significant effect on the molecular morphology and binding constants of HA for heavy metals and hydrocarbons and also directly affects the bioavailability of these compounds in the environment.  相似文献   

Analyses of iron oxide assemblages within Namib dune sediments using high field remanence measurements (9 T) and Mössbauer analysis     

John Walden  Kevin H. White  Susan H. Kilcoyne  Phillip M. Bentley 《第四纪科学杂志》2000,15(2):185-195

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FOREWORD     

Mary R. Albert  Susan Taylor 《水文研究》1996,10(12):1551-1551

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Compositional and Isotopic Analytical Methods in Archaeological Micromorphology     

Susan M. Mentzer  Jay Quade 《Geoarchaeology》2013,28(1):87-97

Resin‐impregnated sediment blocks are a by‐product of micromorphological sample processing. These blocks can be further studied using a variety of destructive, nondestructive, and minimally destructive geochemical techniques. X‐ray fluorescence microanalyses conducted on sediment blocks yield semiquantitative major and trace elemental abundances that can be used to generate compositional maps, and to illustrate compositional change within or between archaeological strata and features. Sediment blocks can also be drilled to obtain small sediment samples for stable oxygen and carbon isotopic analyses. Both elemental and isotopic analyses can be conducted in conjunction with micromorphological analyses to yield a holistic picture of archaeological sediment composition, source, and depositional processes. The integration of micromorphological, compositional, and isotopic analyses is used here to aid in the differentiation of calcareous ash and lime plasters from the Neolithic site of Asıklı Höyük, Turkey.  相似文献