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61.
The phase relations of quaternary systems are generally represented by projections onto ternary compositional planes. Such
projections often obscure relationships that would only be evident in a three-dimensional tetrahedral plot. The tetrahedral
plot requires that compositions of the minerals and melts be transformed into Cartesian coordinates. It is shown here how
this transformation is carried out. The application is demonstrated by tetrahedral plots of experimental melt compositions
of partially molten lherzolite. Furthermore, the plot can be used to evaluate whether or not a particular basaltic composition
represents a primary melt. The methods are applicable to any four-component system. 相似文献
62.
We report the occurrence of micrometer-sized silver particles in the red (“impact” or “ejecta”) layer of the Fish Clay. These appear to be embedded into the biogenic/abiogenic calcite matrix. Energy dispersive X-ray analysis indicates that these microparticles are composed of pure silver (>99% of the total weight). Scanning electron microscopy images reveal irregular and predominantly rounded shapes with rugged surfaces. Numerous silver microparticles are spherical, and some exhibit dendritic textures. These microparticles were probably originated during the Chicxulub asteroid impact event, or immediately afterwards, and dispersed globally. 相似文献
63.
Norbert?A.?GajosEmail author Craig?C.?Lundstrom Alexander?H.?Taylor 《Contributions to Mineralogy and Petrology》2016,171(11):93
We present new Fe and Si isotope ratio data for the Torres del Paine igneous complex in southern Chile. The multi-composition pluton consists of an approximately 1 km vertical exposure of homogenous granite overlying a contemporaneous 250-m-thick mafic gabbro suite. This first-of-its-kind spatially dependent Fe and Si isotope investigation of a convergent margin-related pluton aims to understand the nature of granite and silicic igneous rock formation. Results collected by MC-ICP-MS show a trend of increasing δ56Fe and δ30Si with increasing silica content as well as a systematic increase in δ56Fe away from the mafic base of the pluton. The marginal Torres del Paine granites have heavier Fe isotope signatures (δ56Fe = +0.25 ± 0.02 2se) compared to granites found in the interior pluton (δ56Fe = +0.17 ± 0.02 2se). Cerro Toro country rock values are isotopically light in both Fe and Si isotopic systems (δ56Fe = +0.05 ± 0.02 ‰; δ30Si = ?0.38 ± 0.07 ‰). The variations in the Fe and Si isotopic data cannot be accounted for by local assimilation of the wall rocks, in situ fractional crystallization, late-stage fluid exsolution or some combination of these processes. Instead, we conclude that thermal diffusion or source magma variation is the most likely process producing Fe isotope ratio variations in the Torres del Paine pluton. 相似文献
65.
Emissions of biogenic volatile organic compounds (BVOC) were measured using a relaxed eddy accumulation (REA) technique on an above-canopy tower in a temperate forest (Changbai Mountain, Jilin province, China) during the 2010 and 2011 summer seasons. Solar global radiation and photosynthetically active radiation (PAR) were also measured. Based on PAR energy dynamic balance, an empirical BVOC emission and PAR transfer model was developed that includes the processes of BVOC emissions and PAR transfer above the canopy level, including PAR absorption and consumption, and scattering by gases, liquids, and particles (GLPs). Simulated emissions of isoprene and monoterpenes were in agreement with observations. The averages of the relative estimator biases for the flux were 39.3 % for isoprene, and 27.1 % for monoterpenes in the 2010 and 2011 growing seasons, with NMSE (normalized mean square error) values of 0.133 and 0.101, respectively. The observed and simulated mean diurnal variations of isoprene and monoterpenes in the 2010 and 2011 growing seasons were evaluated for the validation of the empirical model. Under observed atmospheric conditions, the sensitivity analysis showed that emissions of isoprene and monoterpenes were more sensitive to changes in PAR than to water vapor content or to the magnitude of the scattering factor. The emissions of isoprene and monoterpenes in the 2010 and 2011 growing seasons (from June to September) were estimated using this empirical model along with hourly observational data, with mean hourly emissions of 1.71 and 1.55 mg m?2 h?1 for isoprene, and 0.48 and 0.47 mg m?2 h?1 for monoterpenes in 2010 and 2011, respectively. As formaldehyde (HCHO) is considered as the main oxidation product of isoprene and monoterpenes, it is necessary to investigate the link between HCHO and BVOC emissions. GOME-2 HCHO vertical column densities (VCDs) can be used to estimate BVOC emission fluxes in the Changbai Mountain temperate forest. 相似文献
66.
Dana?L.?DrewEmail author Ilya?N.?Bindeman Matthew?W.?Loewen Paul?J.?Wallace 《Contributions to Mineralogy and Petrology》2016,171(1):10
During the onset of caldera cluster volcanism at a new location in the Snake River Plain (SRP), there is an increase in basalt fluxing into the crust and diverse silicic volcanic products are generated. The SRP contains abundant and compositionally diverse hot, dry, and often low-δ18O silicic volcanic rocks produced through time during the formation of individual caldera clusters, but more H2O-rich eruptive products are rare. We report analyses of quartz-hosted melt inclusions from pumice clasts from the upper and lower Arbon Valley Tuff (AVT) to gain insight into the initiation of caldera cluster volcanism. The AVT, a voluminous, caldera-forming rhyolite, represents the commencement of volcanism (10.44 Ma) at the Picabo volcanic field of the Yellowstone hotspot track. This is a normal δ18O rhyolite consisting of early and late erupted members (lower and upper AVT, respectively) with extremely radiogenic Sr isotopes and unradiogenic Nd isotopes, requiring that ~50 % of the mass of these elements is derived from melts of Archean upper crust. Our data reveal distinctive features of the early erupted lower AVT melt including: variable F concentrations up to 1.4 wt%, homogenous and low Cl concentrations (~0.08 wt%), H2O contents ranging from 2.3 to 6.4 wt%, CO2 contents ranging from 79 to 410 ppm, and enrichment of incompatible elements compared to the late erupted AVT, subsequent Picabo rhyolites, SRP rhyolites, and melt inclusions from other metaluminous rhyolites (e.g., Bishop Tuff, Mesa Falls Tuff). We couple melt inclusion data with Ti measurements and cathodoluminescence (CL) imaging of the host quartz phenocrysts to elucidate the petrogenetic evolution of the AVT rhyolitic magma. We observe complex and multistage CL zoning patterns, the most critical being multiple truncations indicative of several dissolution–reprecipitation episodes with bright CL cores (higher Ti) and occasional bright CL rims (higher Ti). We interpret the high H2O, F, F/Cl, and incompatible trace element concentrations in the context of a model involving melting of Archean crust and mixing of the crustal melt with basaltic differentiates, followed by multiple stages of fractional crystallization, remelting, and melt extraction. This multistage process, which we refer to as distillation, is further supported by the complex CL zoning patterns in quartz. We interpret new Δ18O(Qz-Mt) isotope measurements, demonstrating a 0.4 ‰ or ~180 °C temperature difference, and strong Sr isotopic and chemical differences between the upper and lower AVT to represent two separate eruptions. Similarities between the AVT and the first caldera-forming eruptions of other caldera clusters in the SRP (Yellowstone, Heise and Bruneau Jarbidge) suggest that the more evolved, lower-temperature, more H2O-rich rhyolites of the SRP are important in the initiation of a caldera cluster during the onset of plume impingement. 相似文献
67.
Mileva Samardžić‐Petrović Suzana Dragićević Miloš Kovačević Branislav Bajat 《Transactions in GIS》2016,20(5):718-734
Support Vector Machines (SVM) is a machine learning (ML) algorithm commonly applied to the classification of remotely sensing data and more recently for modeling land use changes. However, in most geospatial applications the current literature does not elaborate on specifications of the SVM method with respect to data sampling, attribute selection and optimal parameters choices. Therefore the main objective of this study is to present and investigate the SVM technique for modeling urban land use change. The SVM model building procedure is presented together with the detailed evaluation of the output results with respect to the choice of datasets, attributes and the change of SVM parameters. Geospatial datasets containing nine land use classes and spatial attributes for the Municipality of Zemun, Republic of Serbia were used for years 2001, 2003, 2007 and 2011. The Correlation‐based Feature Subset method, kappa coefficient, Area Under Receiver Operating Characteristic Curve (AUC) and kappa simulation were used to perform the model evaluation and compare the model outputs with the real land use datasets. The obtained results indicate that the SVM‐based models perform better when implementing balanced data sampling, reduced data sets to informative subsets of attributes and properly identify the optimal learning parameters. 相似文献
68.
Recursive algorithm for fast GNSS orbit fitting 总被引:1,自引:0,他引:1
Gaussian elimination is an efficient and numerically stable algorithm for estimating parameters and their precision. However, before estimating the parameters, it is often prudent to perform statistical tests to achieve the best fitting model. We use Gaussian elimination to select the best fitting model among candidate models. A succinct relationship between the weighted sum of squared residuals and the previous one is revealed by a volume formula. For quick parameter estimation and determination of weighted sum of squared residuals, a recursive elimination algorithm is proposed in the context of Gaussian elimination. In order to improve the model selection efficiency, the parameter estimation and the determination of the weighted sum of squared residuals are carried out in parallel using the proposed recursive elimination algorithm in which the improvement at each recursive stage is judged by the Bayesian information criterion. Ultimately, the computational complexity and numerical stability of the recursive elimination proposed are briefly discussed, and a GNSS orbit interpolation example is used to verify the results. It shows that the proposed recursive elimination algorithm inherits the numerical stability of the Gaussian elimination, and this algorithm can be used to examine the gain from the newly introduced parameter, dynamically assess the fitting model, and fix the optimal model efficiently. The optimal fitting model with the lowest information is very close to the real situation verified by checkpoints. 相似文献
69.
Giovanni?Pugliano Umberto?RobustelliEmail authorView authors OrcID profile Fabio?Rossi Raffaele?Santamaria 《GPS Solutions》2016,20(3):499-508
Multipath remains one of the major challenges in Global Navigation Satellite System (GNSS) positioning because it is considered the dominant source of ranging errors, which can be classified into specular and diffuse types. We present a new method using wavelets to extract the pseudorange multipath in the time domain and breaking it down into the two components. The main idea is an analysis-reconstruction approach based on application of both continuous wavelet transform (CWT) and discrete wavelet transform (DWT). The proposed procedure involves the use of L1 code-minus-carrier (CMC) observable where higher-frequency terms are isolated as residuals. CMC residuals are analyzed by applying the CWT, and we propose the scalogram as a technique for discerning time–frequency variations of the multipath signal. Unlike Fourier transform, the potential of the CWT scalogram for examining the non-stationary and multifrequency nature of the multipath is confirmed as it simultaneously allows fine detection and time localization of the most representative frequencies of the signal. This interpretation of the CWT scalogram is relevant when choosing the levels of reconstruction with DWT, allowing accurate time domain extraction of both the specular and diffuse multipath. The performance and robustness of the method and its boundary applicability are assessed. The experiment was carried out using a receiver of Campania GNSS Network. The results are given in which specular multipath error is achieved using DWT level 7 approximation component and diffuse multipath error is achieved using DWT level 6 denoised detail component. 相似文献
70.
D. Nenadić T. Gaudenyi K. Bogićević R. Tošović 《Stratigraphy and Geological Correlation》2016,24(4):427-437
The Quaternary sediments in the Danube and Sava riparian area near Belgrade have a considerable thickness. Several categories of deposits (fluvial-lacustrine, fluvial and aeolian) of Pliocene and Quaternary age have been identified. Their thickness, granulometric composition and paleontological features change depending on the distance from the recent Danube and Sava riverbeds. The Pleistocene fluvial deposits are underlain by sediments of the Late Miocene (Sarmatian and Pannonian) or the Plio-Pleistocene age, and are overlain by fluvial-palustrine deposits of the Pleistocene age and recent alluvial deposits. Pleistocene fluvial deposits that form a major part of the Quaternary sediments, have a great significance, since they are proved to be excellent collectors of ground water. Although these deposits are at lower altitudes in the area of Srem, they could be correlated with the high Danube and Morava terraces in Serbia and Drava in Croatia on the basis of their lithologic and paleontological features. 相似文献