Geologic factors controlling groundwater chemistry in the coastal aquifer system of Douala/Cameroon: implication for groundwater system functioning     

Huguette C. Emvoutou  Béatrice Ketchemen Tandia  Suzanne Ngo Boum Nkot  Rodrigue C. S. Ebonji  Yvon B. Nlend  Georges E. Ekodeck  Christine Stumpp  Piotr Maloszewski  Serigne Faye 《Environmental Earth Sciences》2018,77(5):219

Douala city, located in the littoral province of Cameroon, receives abundant rainfall quantities due to its geographical position in the Gulf of Guinea and bears considerable surface water and groundwater resources. Due to socioeconomic development and rapid demographic growth in the city and its consequences of unplanned urbanization and improper sanitation system, these water resources are poorly protected and managed. Streams in the Wouri watershed receive large amounts of wastewater discharge, and hundreds of boreholes have been drilled into the aquifer system without any management plan. A detailed hydrodynamic and hydrogeochemistry study in Douala town and its environs was conducted to get a better insight into the groundwater system functioning in order to provide information for the sustainable management and protection of the groundwater resource. Two field campaigns were carried out with 187 samples collected and analyzed for major ions, stable isotopes (¹⁸O, ²H), and tritium ³H. The results of the sampling have shown that the weathering of silicate minerals is the dominant geochemical process affecting groundwater chemistry in this system. However, acid rainfall in the humid climate has also caused carbonate mineral dissolution, amorphous silica deposition, and ion exchange reactions to occur in aquifers in the region. The various water types identified were categorized into four major clusters C1 to C4, based on the major ion composition and the local hydrogeological conditions. Environmental isotope data reveal that modern-to-submodern waters occur in the phreatic Quaternary/Mio-Pliocene and Oligocene/Upper Eocene aquifers, respectively. These results corroborate with the conceptual model built where modern groundwater types indicated silicate mineral weathering and calcite dissolution (C1 and C2), whereas submodern groundwater mostly showed silica deposition, ion exchange, and, to a lesser extent, carbonate mineral dissolution (C3 and C4). This improved understanding of the aquifer system functioning is essential to provide a reasonable basis for effective control measures and sustainable water management.  相似文献   

Temporal correlation of magmatic-tectonic events in the lower and upper crust in north-east Australia     

Valeria Murgulov  William L. Griffin  Suzanne Y. O’Reilly 《International Journal of Earth Sciences》2012,101(5):1091-1109

Hf model ages yielded by rutiles in a garnet-rich lower-crustal granulite xenolith from the McBride Province and whole-rock Nd and Hf model ages for the plagioclase- and garnet-rich Chudleigh and McBride granulites overlap with the well-defined U–Pb ages for detrital zircons and zircons in granitoids (Murgulov et al. Chem Geol 245:198–218, 2007; Mineral Petrol 95:17–45, 2009), suggesting temporal correlation of magmatic-tectonic events in the lower and upper crust in the north-east Australian craton. Intrusion of basaltic magmas into and below the lower crust beneath the Chudleigh Province around 1.4, 1.7 and 2.3?Ga and beneath the McBride Province around 1.5, 1.7, 2.3 and 2.5?Ga provided heat for remelting and supplied magmas with juvenile mantle isotope signatures to the upper crust. Similar magmas provided enough heat to cause melting in the lower crust beneath the Chudleigh Province around 0.12 and 0.8–0.9?Ga and beneath the McBride Province around 0.42, 0.8–0.9?Ga, 1.1 and 1.3?Ga but were not sufficient to cause significant melting in the upper crust. A wide range in initial ¹⁷⁶Hf/¹⁷⁷Hf values and a ~1.55?Ga Hf model age yielded by rutiles in the McBride granulite provide a link to the genesis of ~420?Ma granitoids. The data for a plagioclase-rich granulite from the Atherton Province are similar to those for the Chudleigh and McBride granulites. However, additional samples are required to test whether the lower crust of the Tasman orogenic belt is lithologically and isotopically similar to the lower crust of the craton.  相似文献   

Comparison of regression-based and combined versions of Inverse Distance Weighted methods for spatial interpolation of daily mean temperature data     

Emine?Tan?r Kay?k??Email author  Selma?Zengin Kazanc? 《Arabian Journal of Geosciences》2016,9(17):690

This paper focuses on the performance of two regression-based and one Inverse Distance Weighted (IDW) and two combined versions of IDW methods for interpolation of daily mean temperature at the Black Sea Region of Turkey. Simple linear regression (SLR) and multiple linear regression (MLR) are used as regression-based methods. Combinations of IDW with TLR (temperature lapse rate) and gradient plus inverse distance squared (GIDS) are used as combined versions of IDW. This study targets to compare five spatial interpolation methods based on RMSE (root-mean-square error) statistics of interpolation errors for daily mean temperatures from 1981 to 2012. In order to compare the interpolation errors of the five methods, the leave-one-out cross-validation method was applied over long periods of 32 years on 52 different sites. The algorithms of the five interpolation methods’ codes were written in MATLAB by the authors of the paper.  相似文献   

Water contents of Roberts Victor xenolithic eclogites: primary and metasomatic controls     

Jin-Xiang?HuangEmail author  Pei?Li  William?L.?Griffin  Qun-Ke?Xia  Yoann?Gréau  Norman?J.?Pearson  Suzanne?Y.?O’Reilly 《Contributions to Mineralogy and Petrology》2014,168(6):1092

A suite of eclogites from the Roberts Victor kimberlite has been extensively characterized in terms of petrology and geochemical compositions (Gréau et al. in Geochim Cosmochim Acta 75(22):6927–6954, 2011; Huang et al. in Lithos 142–143:161–181, 2012a). In the present study, the water contents of eclogitic garnet and omphacite were analyzed by Fourier transform infrared spectrometry. Garnet does not contain measureable OH in any sample. The water content of omphacite in the studied eclogites ranges from 211 to 1,496 ppm. Mantle metasomatism has modified the water content of some of the eclogites, while others retain water contents characteristic of their original environment. The OH contents of the metasomatized eclogites may be mainly controlled by the H₂O fugacity and mineral compositions. The OH contents of the non-metasomatized samples are interpreted to be more sensitive to their mantle equilibration temperature, pressure, and the local fugacities of H₂O and O₂. The calculated water content of the metasomatic medium is similar to that of carbonatitic–kimberlitic melts/fluids. Eclogites contain more water than peridotites recorded in the literature (341 ± 161 vs 122 ± 54 ppm) and represent an important water reservoir in the lithospheric mantle wherever they occur. This is an important parameter to be considered in the interpretation of mantle processes and geophysical data such as seismic wave speeds and electrical conductivity, and in geodynamic modeling.  相似文献   

From Headwaters to Coast: Influence of Human Activities on Water Quality of the Potomac River Estuary     

Suzanne B. Bricker  Karen C. Rice  Owen P. Bricker III 《Aquatic Geochemistry》2014,20(2-3):291-323

The natural aging process of Chesapeake Bay and its tributary estuaries has been accelerated by human activities around the shoreline and within the watershed, increasing sediment and nutrient loads delivered to the bay. Riverine nutrients cause algal growth in the bay leading to reductions in light penetration with consequent declines in sea grass growth, smothering of bottom-dwelling organisms, and decreases in bottom-water dissolved oxygen as algal blooms decay. Historically, bay waters were filtered by oysters, but declines in oyster populations from overfishing and disease have led to higher concentrations of fine-sediment particles and phytoplankton in the water column. Assessments of water and biological resource quality in Chesapeake Bay and tributaries, such as the Potomac River, show a continual degraded state. In this paper, we pay tribute to Owen Bricker’s comprehensive, holistic scientific perspective using an approach that examines the connection between watershed and estuary. We evaluated nitrogen inputs from Potomac River headwaters, nutrient-related conditions within the estuary, and considered the use of shellfish aquaculture as an in-the-water nutrient management measure. Data from headwaters, nontidal, and estuarine portions of the Potomac River watershed and estuary were analyzed to examine the contribution from different parts of the watershed to total nitrogen loads to the estuary. An eutrophication model was applied to these data to evaluate eutrophication status and changes since the early 1990s and for comparison to regional and national conditions. A farm-scale aquaculture model was applied and results scaled to the estuary to determine the potential for shellfish (oyster) aquaculture to mediate eutrophication impacts. Results showed that (1) the contribution to nitrogen loads from headwater streams is small (about 2 %) of total inputs to the Potomac River Estuary; (2) eutrophic conditions in the Potomac River Estuary have improved in the upper estuary since the early 1990s, but have worsened in the lower estuary. The overall system-wide eutrophication impact is high, despite a decrease in nitrogen loads from the upper basin and declining surface water nitrate nitrogen concentrations over that period; (3) eutrophic conditions in the Potomac River Estuary are representative of Chesapeake Bay region and other US estuaries; moderate to high levels of nutrient-related degradation occur in about 65 % of US estuaries, particularly river-dominated low-flow systems such as the Potomac River Estuary; and (4) shellfish (oyster) aquaculture could remove eutrophication impacts directly from the estuary through harvest but should be considered a complement—not a substitute—for land-based measures. The total nitrogen load could be removed if 40 % of the Potomac River Estuary bottom was in shellfish cultivation; a combination of aquaculture and restoration of oyster reefs may provide larger benefits.  相似文献   

Preface to Owen P. Bricker III Special Issue of Aquatic Geochemistry     

Suzanne B. Bricker  Fred T. Mackenzie  Jill S. Baron  Jason R. Price 《Aquatic Geochemistry》2014,20(2-3):81-86

This special volume of aquatic geochemistry is dedicated to the memory of Owen Peterson Bricker III (1936–2011) and serves as a tribute to his life and career. Owen had a distinguished and productive research career in both academics at Johns Hopkins University (Fig. 1) and as a public servant with the Maryland Geological Survey, the US Environmental Protection Agency, and the US Geological Survey. He was a pioneer and leader in aqueous geochemistry, who applied a study approach that quantified mineral weathering reactions and equilibrium thermodynamic relations to better understand the chemical evolution of stream water in small watersheds. He will be especially remembered for his efforts to establish rigorous field studies in small catchments around the United States as a means of quantifying the sources of acid-neutralizing capacity that affect the chemical status and biological health of natural waters.