Hydrothermal evolution of the morphology,molecular composition,and distribution of organic matter in CR (Renazzo-type) chondrites     

Hitesh G. Changela  Corentin Le Guillou  Sylvain Bernard  Adrian J. Brearley 《Meteoritics & planetary science》2018,53(5):1006-1029

The morphology, molecular composition, and distribution of organic matter (OM) were investigated in a suite of CR chondrites to better constrain its hydrothermal evolution. Multiple focused ion beam sections were extracted from the matrices of seven CR chondrites. Scanning transmission X-ray microscopy and transmission electron microscopy reveal OM ubiquitously distributed across the CR matrices. OM mainly occurs as either discrete submicron rounded or irregularly shaped vein-like particles. Two spectral populations of organic particles were identified by carbon K-edge X-ray absorption near edge structure (XANES): the most abundant one, similar to insoluble organic matter (IOM) residues, contains aromatic, carbonyl, and carboxylic groups. The second population is more aromatic-rich and lacks a distinctive carbonyl peak. An additional, ubiquitous organic component occurs associated with amorphous silicates and phyllosilicates. Less aromatic but aliphatic- and carboxylic-rich, this diffuse OM is interpreted as the result of the redistribution of organic compounds by aqueous fluids. The most altered CR1 GRO 95577 contains a more mature OM and highly aliphatic- and carboxylic-rich diffuse OM. This evolution, from the CR2s to the CR1, is comparable to that of terrestrial gas shale maturation involving cracking reactions, releasing bitumen-like, aliphatic-, and carboxylic-rich compounds, and aromatic residues. Our observations support the accretion of soluble OM and its later polymerization to IOM, as well as the maturation of IOM and its partial oxidation, releasing mobile compounds. The differences in GRO 95577 are clearly attributable to the hydrothermal episode(s), but the relative role of water and temperature on the evolution of OM remains elusive.  相似文献   

Regolith breccia Northwest Africa 7533: Mineralogy and petrology with implications for early Mars          下载免费PDF全文

Roger H. Hewins  Brigitte Zanda  Munir Humayun  Alexander Nemchin  Jean‐Pierre Lorand  Sylvain Pont  Damien Deldicque  Jeremy J. Bellucci  Pierre Beck  Hugues Leroux  Maya Marinova  Laurent Remusat  Christa Göpel  Eric Lewin  Marion Grange  Allen Kennedy  Martin J. Whitehouse 《Meteoritics & planetary science》2017,52(1):89-124

Northwest Africa 7533, a polymict Martian breccia, consists of fine‐grained clast‐laden melt particles and microcrystalline matrix. While both melt and matrix contain medium‐grained noritic‐monzonitic material and crystal clasts, the matrix also contains lithic clasts with zoned pigeonite and augite plus two feldspars, microbasaltic clasts, vitrophyric and microcrystalline spherules, and shards. The clast‐laden melt rocks contain clump‐like aggregates of orthopyroxene surrounded by aureoles of plagioclase. Some shards of vesicular melt rocks resemble the pyroxene‐plagioclase clump‐aureole structures. Submicron size matrix grains show some triple junctions, but most are irregular with high intergranular porosity. The noritic‐monzonitic rocks contain exsolved pyroxenes and perthitic intergrowths, and cooled more slowly than rocks with zoned‐pyroxene or fine grain size. Noritic material contains orthopyroxene or inverted pigeonite, augite, calcic to intermediate plagioclase, and chromite to Cr‐bearing magnetite; monzonitic clasts contain augite, sodic plagioclase, K feldspar, Ti‐bearing magnetite, ilmenite, chlorapatite, and zircon. These feldspathic rocks show similarities to some rocks at Gale Crater like Black Trout, Mara, and Jake M. The most magnesian orthopyroxene clasts are close to ALH 84001 orthopyroxene in composition. All these materials are enriched in siderophile elements, indicating impact melting and incorporation of a projectile component, except for Ni‐poor pyroxene clasts which are from pristine rocks. Clast‐laden melt rocks, spherules, shards, and siderophile element contents indicate formation of NWA 7533 as a regolith breccia. The zircons, mainly derived from monzonitic (melt) rocks, crystallized at 4.43 ± 0.03 Ga (Humayun et al. 2013 ) and a ¹⁴⁷Sm‐¹⁴³Nd isochron for NWA 7034 yielding 4.42 ± 0.07 Ga (Nyquist et al. 2016 ) defines the crystallization age of all its igneous portions. The zircon from the monzonitic rocks has a higher Δ¹⁷O than other Martian meteorites explained in part by assimilation of regolith materials enriched during surface alteration (Nemchin et al. 2014 ). This record of protolith interaction with atmosphere‐hydrosphere during regolith formation before melting demonstrates a thin atmosphere, a wet early surface environment on Mars, and an evolved crust likely to have contaminated younger extrusive rocks. The latest events recorded when the breccia was on Mars are resetting of apatite, much feldspar and some zircons at 1.35–1.4 Ga (Bellucci et al. 2015 ), and formation of Ni‐bearing pyrite veins during or shortly after this disturbance (Lorand et al. 2015 ).  相似文献   

Initial Results from Fitting $$-Modes Using Intensity Observations from the Helioseismic and Magnetic Imager     

Sylvain G. Korzennik 《Solar physics》2017,292(9):138

The Helioseismic and Magnetic Imager project recently started processing the continuum-intensity images following global helioseismology procedures similar to those used to process the velocity images. The spatial decomposition of these images has produced time series of spherical harmonic coefficients for degrees up to \(\ell=300\), using a different apodization than the one used for velocity observations. The first 360 days of observations were processed and are made available. I present initial results from fitting these time series using my fitting method and compare the derived mode characteristics to those estimated using coeval velocity observations.  相似文献   

Der Weißfelchen des Bodensees und die Frage der Artbildung im Felchengeschlecht     

Paul Steinmann 《Aquatic Sciences - Research Across Boundaries》1948,10(4):3-12

Ohne Zusammenfassung  相似文献   

Bücher- und Zeitschriftenschau     

Steinmann  Schöndorf  W. Salomon 《International Journal of Earth Sciences》1915,6(1-2):94-102

Ohne Zusammenfassung  相似文献   

A possible link between gabbros bearing High Temperature Iddingsite alteration and huge pegmatoid intrusions: The Society Islands, French Polynesia     

Jean-Philippe Clment  Martial Caroff  Patrick Dudoignon  Patrick Launeau  Marcel Bohn  Joseph Cotten  Sylvain Blais  Grard Guille 《Lithos》2007,96(3-4):524-542

This paper reports new field observations and new petrological, textural and geochemical data on two gabbroic intrusions and one pegmatoid dyke from the French Polynesian islands Maupiti and Bora Bora, respectively. Olivine crystals from the Faataufi and Barque de Hiro gabbros (Maupiti) include High Temperature Iddingsite (HTI), exhibiting three distinct morphological facies. Chemical and crystallographical data performed by electron microprobe, scanning microscope, X-ray diffractometry and Near InfraRed spectroscopy show that HTI results from modifications of olivine structure through intense hydroxylation and Fe-oxidation. The HTI-free 120 m-wide Cloche de Hiro dyke (Bora Bora) exhibits a textural zonation from heterogranular/intergranular gabbro (peripheral part) to typical pegmatoid (inner area). We propose a textural tetrahedral classificatory diagram which can be used to clearly distinguish the textural characteristics of the pegmatoids from those of the other coarse-grained samples. Through comparison with a lava flow containing vesicle-rich segregation sheets, we suggest that the Cloche de Hiro dyke may correspond to a huge segregation structure derived from a Maupiti-type HTI-bearing gabbro through a vapor-differentiation process. Both intrusions might be considered as representative of two superposed levels in a vertically arranged magmatic complex. In this view, the Maupiti gabbroic bodies would represent the lower part of the postulated system. Under high oxygen fugacity, olivine crystals would have undergone important modifications of their structure, leading to HTI. The huge Bora Bora pegmatoid dyke would be the upper part of the complex. After expulsion from the HTI-bearing gabbroic solidification zone by build-up of gas pressure, vesicle-rich residual melt would have gathered into a shallow level and crystallized there as a pegmatoid body.  相似文献   

Sub-grid scale parameterisation of 2D hydrodynamic models of inundation in the urban area   总被引：1，自引：0，他引：1  

Sylvain Néelz  Gareth Pender 《Acta Geophysica》2007,55(1):65-72

This paper presents preliminary results from a study considering the parameterisation of coarse-grid 2D flood models to take into account sub-grid scale flow patterns occurring in the urban area. A simulation of a severe flood in an urbanized coastal floodplain is first run using a fine grid that can resolve the flow around and between buildings. Next, the same model is run again using the same underlying topography, although stripped from any buildings, and a set of 7 values of the roughness parameter (Manning’s n), all larger than (or equal to) the value used in the original run. A further set of simulations is carried out using a five-fold increased grid cell size. It is found that while it may be possible to model the overall effects of the buildings using strongly increased roughness parameter values, using a coarse grid otherwise has implications related to the loss of information about the site topography that results in flood flow routes being incorrectly modelled.  相似文献   

Ecohydrological modelling with EcH2O‐iso to quantify forest and grassland effects on water partitioning and flux ages     

Audrey Douinot  Doerthe Tetzlaff  Marco Maneta  Sylvain Kuppel  Hubert Schulte‐Bisping  Chris Soulsby 《水文研究》2019,33(16):2174-2191

We used the new process‐based, tracer‐aided ecohydrological model EcH₂O‐iso to assess the effects of vegetation cover on water balance partitioning and associated flux ages under temperate deciduous beech forest (F) and grassland (G) at an intensively monitored site in Northern Germany. Unique, multicriteria calibration, based on measured components of energy balance, hydrological function and biomass accumulation, resulted in good simulations reproducing measured soil surface temperatures, soil water content, transpiration, and biomass production. Model results showed the forest “used” more water than the grassland; of 620 mm average annual precipitation, losses were higher through interception (29% under F, 16% for G) and combined soil evaporation and transpiration (59% F, 47% G). Consequently, groundwater (GW) recharge was enhanced under grassland at 37% (~225 mm) of precipitation compared with 12% (~73 mm) for forest. The model tracked the ages of water in different storage compartments and associated fluxes. In shallow soil horizons, the average ages of soil water fluxes and evaporation were similar in both plots (~1.5 months), though transpiration and GW recharge were older under forest (~6 months compared with ~3 months for transpiration, and ~12 months compared with ~10 months for GW). Flux tracking using measured chloride data as a conservative tracer provided independent support for the modelling results, though highlighted effects of uncertainties in forest partitioning of evaporation and transpiration. By tracking storage—flux—age interactions under different land covers, EcH₂O‐iso could quantify the effects of vegetation on water partitioning and age distributions. Given the likelihood of drier, warmer summers, such models can help assess the implications of land use for water resource availability to inform debates over building landscape resilience to climate change. Better conceptualization of soil water mixing processes and improved calibration data on leaf area index and root distribution appear obvious respective modelling and data needs for improved simulations.  相似文献   

Mapping a geothermal anomaly using apatite (U‐Th)/He thermochronology in the Têt fault damage zone,eastern Pyrenees,France     

Gatan Milesi  Roger Soliva  Patrick Moni  Philippe Münch  Mathieu Bellanger  Olivier Bruguier  Michael Bonno  Audrey Taillefer  Sylvain Mayolle 《地学学报》2019,31(6):569-576

(U‐Th)/He ages on apatite obtained in the vicinity of the Têt fault hydrothermal system show a large variability. In the inner damage zone adjacent to the fault core, where fluid flows are concentrated, AHe ages display a large scatter (3–41 Ma) and apatite ageing. Samples from the outer damage zone show young ages with less dispersion (0.9–21.1 Ma) and apatite rejuvenation. Outside the damage zone, ages are consistent with the regional exhumation history between 20 and 12 Ma. The important age dispersion found in the damage zone is interpreted as the result of ⁴He mobility during fluid infiltration. Our results show that thermochronological data close to a fault should be interpreted with caution, but may offer a new tool for geothermal exploration.  相似文献   

Wind-Flow Dynamics Over a Vineyard     

Ali Chahine  Sylvain Dupont  Carole Sinfort  Yves Brunet 《Boundary-Layer Meteorology》2014,151(3):557-577

Wind-flow dynamics has been extensively studied over horizontally uniform canopies, but agricultural plantations structured in rows such as vineyards have received less attention. Here, the wind flow over a vineyard is studied in neutral stratification from both large-eddy simulation (LES) and in situ measurements. The impact of row structure on the wind dynamics is investigated over a range of wind directions from cross-row to down-row, and a typical range of row aspect ratio (row separation/height ratio). It is shown that the mean flow over a vineyard is similar to that observed in uniform canopies, especially for wind directions from cross-row to diagonal. For down-row winds, the mean flow exhibits noticeable spatial variability across each elementary row-gap pattern, as the wind is channeled in the inter-row. This spatial variability increases with the aspect ratio. With down-row winds the turbulent structures are also more intermittent and generate larger turbulent kinetic energy and momentum flux. The displacement height and roughness length of the vineyard vary with the aspect ratio in a way similar to their variation with canopy density in uniform canopies. Both parameters take smaller values in down-row wind flow, for which the canopy appears more open. The analysis of velocity spectra and autocorrelation functions shows that vineyard canopies share similar features to uniform canopies in terms of turbulent coherent structures, with only minor changes with wind direction.  相似文献