Laboratory simulation of an oxidizing perturbation in a deep granite environment     

Laurent TrotignonValrie Michaud  Jean-Eric Lartigue  Jean-Paul AmbrosiLaurent Eisenlohr  Lise GriffaultMichel de Combarieu  Sylvie Daumas 《Geochimica et cosmochimica acta》2002,66(14):2583-2601

An experiment designed to study oxidizing perturbations in deep crystalline rock, a potential host for nuclear waste disposal, was conducted. This experiment simulated a fracture surface in contact with circulating groundwater, in which dissolved oxygen was injected periodically. Major physicochemical and biological parameters were monitored during this 1-yr experiment. Modeling of the results indicates that the kinetics of oxygen uptake may be represented by a simple steady-state rate law combining enzymatic catalysis (Monod) and a first-order rate law. Combined chemical and biological data demonstrate the coupling of organic/inorganic processes during the uptake of dissolved oxygen and the progressive return to reducing conditions. Timescales for these stages are discussed. Experimental results also suggest that iron-reducing bacteria, which are robust and well-adapted microorganisms, play a key role in these interfacial processes. These results show that an operational definition of the “redox buffering capacity” in a granitic medium cannot ignore the effect of bacteria and therefore the controls on bacterial substrates (organic carbon, H₂, CH₄, CO₂).  相似文献   

Les événements de la limite Permien–Trias : derniers survivants et/ou premiers re-colonisateurs parmi les ostracodes du Taurus (Sud-Ouest de la Turquie)The events of the Permian–Trias boundary: last survivors and/or first colonisers among the ostracods of the Taurides (southwestern Turkey)     

Sylvie Crasquin-Soleau  Sylvain Richoz  Jean Marcoux  Lucia Angiolini  Alda Nicora  Aymon Baud 《Comptes Rendus Geoscience》2002,334(7):489-495

Very few data on Early Triassic marine ostracods are available. In most of cases, the data concern the upper part of the Early Triassic. The Çürük da? section, located in the Western Taurides (Turkey), well stratigraphically constrained by conodonts and foraminifera, has been re-sampled for ostracod study. A significant fauna has been discovered in the Late Permian and the levels of the Earliest Triassic (Hindeodus parvus and Isarcicella isarcica staeschei zones). The ostracods of the basis of the Kokarkuyu Fm. are the oldest Triassic forms ever discovered. The occurrence of Palaeocopes in the earliest Triassic and similarity between the Permian and Induan assemblages suggest that the Lower Triassic Çürük da? ostracods represent a survival assemblage after the Permo-Triassic mass-extinction. To cite this article: S. Crasquin-Soleau et al., C. R. Geoscience 334 (2002) 489–495.  相似文献   

Post-rift volcanism and high heat-flow at the ocean-continent transition of the eastern Gulf of Aden     

Francis Lucazeau  Sylvie Leroy  Julia Autin  Alain Bonneville  Bruno Goutorbe  Louise Watremez  Elia d'Acremont  Doga Düsünur  Frédérique Rolandone  Philippe Huchon  Nicolas Bellahsen  Patrick Tuchais 《地学学报》2009,21(4):285-292

A high heat-flow (∼900 mW m⁻²) has been observed over a volcanic structure at the Ocean-Continent Transition in the Eastern Gulf of Aden (Oman margin). The anomaly is superposed to a progressive increase of heat-flow across the margin and can be interpreted either by (1) heat refraction, (2) fluid discharge or (3) cooling magma. The two first explanations cannot be ruled out definitely by modelling analysis, but require unlikely thermal conductivity or permeability values. The third one implies that the latest activity of the volcano was about 100 000 years old and therefore continued c. 18 Ma after the break-up of Africa and Arabia. This potential mechanism is consistent with other lines of evidence of post-rifting activity in the Gulf of Aden and could invalidate the conventional assumption that rifted-margins become passive after the break-up of continents.  相似文献   

Impact of coherent eddies on airborne measurements of vertical turbulent fluxes     

Marie Lothon  Fleur Couvreux  Sylvie Donier  Françoise Guichard  Pierre Lacarrère  Donald H. Lenschow  Joël Noilhan  Frédérique Saïd 《Boundary-Layer Meteorology》2007,124(3):425-447

During the Hydrological-Atmospheric Pilot Experiment (HAPEX)-Sahel, which took place in Niger in the transitional period between the wet and dry seasons, two French aircraft probed the Sahelian boundary layer to measure sensible and latent heat fluxes. The measurements over the Niamey area often revealed organised structures of a few km scale that were associated with both thermals and dry intrusions. We study the impact of these coherent structures using a single day’s aircraft-measured fluxes and a numerical simulation of that day with a mesoscale model. The numerical simulation at high horizontal resolution (250 m) contains structures that evolve from streaks in the early morning to cells by noon. This simulation shows distribution, variance and skewness similar to the observations. In particular, the numerical simulation shows dry intrusions that can penetrate deeply into the atmospheric boundary layer (ABL), and even reach the surface in some cases, which is in accordance with the observed highly negatively skewed water vapour fluctuations. Dry intrusions and thermals organised at a few km scale give skewed flux statistics and can introduce large errors in measured fluxes. We use the numerical simulation to: (i) evaluate the contribution of the organised structures to the total flux, and (ii) estimate the impact of the organised structures on the systematic and random errors resulting from the 1D sampling of the aircraft as opposed to the 2D numerical simulation estimate. We find a significant contribution by the organised structures to the total resolved fluxes. When rolls occur, and for a leg length of about 30 times the ABL depth, the 1D sampled flux is shown to be sometimes 20% lower than the corresponding 2D flux when the 1D sampling direction is the same as the main axis of the rolls, whereas the systematic error is much lower when the direction of the leg is transverse to the rolls. In the case of cells, an underestimate of around 10% can still be observed with the 1D approach independent of direction, due to poor sampling of the energy-containing scales.  相似文献   

DMSP and DMS in the Northwest Atlantic: Late-summer distributions,production rates and sea-air fluxes     

Michael G. Scarratt  Maurice Levasseur  Sonia Michaud  Sylvie Roy 《Aquatic Sciences - Research Across Boundaries》2007,69(3):292-304

  相似文献   

Ostracods and palaeobotany from the middle Permian of Oman: implications on Pangaea reconstruction     

Sylvie Crasquin-Soleau  Jean Broutin  Jean Besse  & Martine Berthelin 《地学学报》2001,13(1):38-43

Discovery of a middle Permian ostracod fauna in the marine Khuff Formation (Sultanate of Oman), combined with palaeobotanical data from the immediately underlying continental Gharif Formation, supports new interpretations of the palaeobiogeography of the Tethys during the late Palaeozoic. A mixed ostracod fauna existed on the Arabian platform. This new record of Permian ostracods, combined with recent data obtained in other Tethyan areas, emphasizes the close relationship between the south-western Tethys realm and South China. The macro- and microfloral assemblages of the continental Gharif Formation demonstrate that this palaeoflora represents a true mixed association in which Gondwanan, Cathaysian and Euramerian elements are intermingled. Two main models exist for the reconstruction of Pangaea during the late Palaeozoic. Both ostracods and palaeobotanical evidence favour the reduction of the oceanic area between South China and Arabian plate as in the B Pangaea model favoured by recent palaeomagnetic data.  相似文献   

Origin and formation pathways of kerogen-like organic matter in recent sediments off the Danube delta (northwestern Black Sea)   总被引：1，自引：0，他引：1  

Anouk Garcette-Lepecq  Sylvie Derenne  Claude Largeau  Ioanna Bouloubassi  Alain Saliot 《Organic Geochemistry》2000,31(12):204

The chemical structure, source(s), and formation pathway(s) of kerogen-like organic matter (KL) were investigated in recent sediments from the northwestern Black Sea, off the Danube delta. Three sections from a sediment core collected at the mouth of the Sulina branch of the delta, under an oxic water column, were examined: S₀ (0–0.5 cm bsf), S₁₀ (10–13 cm bsf), and S₂₀ (20–25 cm bsf). The bulk geochemical features of these sediments (total organic carbon, organic C/N atomic ratio, δ¹³C_org) were determined. Thereafter, KL was isolated from the samples, as the insoluble residue obtained after HF/HCl treatment. KL chemical composition was investigated via spectroscopic (FTIR, solid state ¹³C and ¹⁵N NMR) and pyrolytic (Curie point pyrolysis–gas chromatography–mass spectrometry) methods, and the morphological features were examined by scanning and transmission electron microscopy. Similar morphological features and chemical composition were observed for the three KLs and they suggested that the selective preservation of land-plant derived material as well as of resistant aliphatic biomacromolecules (probably derived from cell walls of freshwater microalgae) was the main process involved in KL formation. Besides, some melanoidin-type macromolecules (formed via the degradation-recondensation of products mainly derived from proteinaceous material) and/or some encapsulated proteins also contributed to the KL chemical structure.  相似文献   

Effects of fungal infection on lipid extract composition of higher plant remains: comparison of shoots of a Cenomanian conifer, uninfected and infected by extinct fungi     

Thanh Thuy Nguyen Tu  Sylvie Derenne  Claude Largeau  Andr Mariotti  Herv Bocherens  Denise Pons 《Organic Geochemistry》2000,31(12):25

The lipid fraction extracted from uninfected shoots of a fossil conifer, Frenelopsis alata, was analysed by gas-chromatography–mass-spectrometry, and compared with shoots of the same conifer infected by extinct epiphyllous fungi, so as to study the effects of fungal infection on the chemical composition of extracts from higher plant remains. The extracts from the uninfected shoots appeared to be composed of (i) common constituents of higher plant lipids such as n-alkanes and fatty acids, (ii) elemental sulphur, and (iii) substantial amounts of terpenoids characteristic of conifers, such as cadalene, beyerane, dehydroabietane and related compounds. Comparison of this extract with that of fungal-infected shoots revealed, in addition to the aforementioned compounds, the presence of substantial amounts of hydroxysuccinic acid and functionalised benzoic compounds that were interpreted as degradation products of lignin by fungi. This study afforded preliminary indications of the composition of extracts from higher plant remains infected by fungi.  相似文献   

Trends and low-frequency variability of storminess over western Europe, 1878–2007     

Xiaolan L. Wang  Hui Wan  Francis W. Zwiers  Val R. Swail  Gilbert P. Compo  Robert J. Allan  Russell S. Vose  Sylvie Jourdain  Xungang Yin 《Climate Dynamics》2011,37(11-12):2355-2371

This study analyzes extremes of geostrophic wind speeds derived from sub-daily surface pressure observations at 13 sites in the European region from the Iberian peninsula to Scandinavia for the period from 1878 or later to 2007. It extends previous studies on storminess conditions in the Northeast (NE) Atlantic-European region. It also briefly discusses the relationship between storminess and the North Atlantic Oscillation (NAO). The results show that storminess conditions in the region from the Northeast Atlantic to western Europe have undergone substantial decadal or longer time scale fluctuations, with considerable seasonal and regional differences (especially between winter and summer, and between the British Isles-North Sea area and other parts of the region). In the North Sea and the Alps areas, there has been a notable increase in the occurrence frequency of strong geostrophic winds from the mid to the late twentieth century. The results also show that, in the cold season (December–March), the NAO-storminess relationship is significantly positive in the north-central part of this region, but negative in the south-southeastern part.  相似文献   

Multi-level filtering segmentation to measure individual tree parameters based on Lidar data: Application to a mountainous forest with heterogeneous stands     

Cédric Véga  Sylvie Durrieu 《International Journal of Applied Earth Observation and Geoinformation》2011

This paper presents a method for individual tree crown extraction and characterisation from a canopy surface model (CSM). The method is based on a conventional algorithm used for localising LM on a smoothed version of the CSM and subsequently for modelling the tree crowns around each maximum at the plot level. The novelty of the approach lies in the introduction of controls on both the degree of CSM filtering and the shape of elliptic crowns, in addition to a multi-filtering level crown fusion approach to balance omission and commission errors. The algorithm derives the total tree height and the mean crown diameter from the elliptic tree crowns generated. The method was tested and validated on a mountainous forested area mainly covered by mature and even-aged black pine (Pinus nigra ssp. nigra [Arn.]) stands. Mean stem detection per plot, using this method, was 73.97%. Algorithm performance was affected slightly by both stand density and heterogeneity (i.e. tree diameter classes’ distribution). The total tree height and the mean crown diameter were estimated with root mean squared error values of 1.83 m and 1.48 m respectively. Tree heights were slightly underestimated in flat areas and overestimated on slopes. The average crown diameter was underestimated by 17.46% on average.  相似文献