Deciphering the weathering processes using environmental mineralogy and geochemistry: Towards an integrated model of laterite and podzol genesis in the Upper Amazon Basin     

Emmanuel Fritsch  Etienne Balan  Nadia Régina Do Nascimento  Thierry Allard  Marion Bardy  Guilherme Bueno  Sylvie Derenne  Adolpho José Melfi  Georges Calas 《Comptes Rendus Geoscience》2011,343(2-3):188-198

This article reports major results from collaborative research between France and Brazil on soil and water systems, carried out in the Upper Amazon Basin. It reveals the weathering processes acting in the partly inundated, low elevation plateaus of the Basin, mostly covered by evergreen forest. Our findings are based on geochemical data and mineral spectroscopy that probe the crystal chemistry of Fe and Al in mineral phases (mainly kaolinite, Al- and Fe-(hydr)oxides) of tropical soils (laterites). These techniques reveal crystal alterations in mineral populations of different ages and changes of metal speciation associated with mineral or organic phases. These results provide an integrated model of soil formation and changes (from laterites to podzols) in distinct hydrological compartments of the Amazon landscapes and under altered water regimes.  相似文献   

Characterization of the glide planes of the [001] screw dislocations in olivine using electron tomography     

Alexandre Mussi  Patrick Cordier  Sylvie Demouchy  Claude Vanmansart 《Physics and Chemistry of Minerals》2014,41(7):537-545

A San Carlos olivine polycrystal has been deformed under uppermost mantle conditions, by compression at 900 °C, at a strain rate of 1.1 × 10^?5 s^?1, under a confining pressure of 300 MPa, using the Paterson press. Transmission electron tomography of dislocations has been performed by scanning transmission electron microscopy, by conventional transmission electron microscopy using the weak-beam dark-field technique, associated with precession or not, in order to determine the glide planes of [001] screw dislocations. This recent technique is the most suitable one since most [001] dislocations exhibit straight screw segments due to the high lattice friction on this character at low temperature. We find that [001] dislocations glide in (100), (010) and {110} as already reported, but also more unexpectedly in {120} and {130}. We show that at 900 °C, [001] {110} glide is dominant in polycrystals. We have, however, noted and characterized numerous cross-slip events in the specimen.  相似文献   

Late Permian to Middle Triassic correlations and palaeogeographical reconstructions in south-western European basins: New sedimentological data from Minorca (Balearic Islands, Spain)     

Bastien Linol  Antoine Bercovici  Sylvie Bourquin  Jos Bienvenido Diez  Jos Lpez-Gmez  Jean Broutin  Marc Durand  Uxue Villanueva-Amadoz 《Sedimentary Geology》2009,220(1-2):77-94

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Microwave assisted extraction and hydrolysis: An alternative to pyrolysis for the analysis of recalcitrant organic matter? Application to a forest soil (Landes de Gascogne,France)     

Batrice Allard  Sylvie Derenne 《Organic Geochemistry》2009,40(9):1005-1017

A comparison was made between the composition of the recalcitrant organic matter (ROM) isolated from a sandy forest soil, as revealed with microwave assisted extractions and/or hydrolysis, and using common pyrolysis techniques. Successive microwave irradiation treatments were performed in H₂O, 0.1 and 1 M HCl and 0.1 and 1 M KOH. At each step the insoluble residue was examined via Curie point pyrolysis (CuPy) and Curie point thermally assisted hydrolysis and methylation (CuTHM). Sequential irradiation treatment resulted in ca. 35% degradation of the ROM. Compounds released on microwave irradiation in H₂O and in HCl were dominated by glucose, suggesting the occurrence of carbohydrate-containing molecular associations in the soil organic matter (SOM) which were not disrupted during acid hydrolysis and extraction as applied for the isolation of the ROM. The product distribution from the microwave irradiation in KOH showed an important contribution to the ROM from the higher plant polyesters cutin and suberin, and to a lesser extent from lignin. Different lignin-derived compounds were specifically released upon microwave acid or base hydrolysis. This suggested that two types of lignin monomers, ether- or ester-linked, occurred in the ROM. The changes in the composition of the CuPy pyrolysates of the residues from the different microwave hydrolyses are consistent with the near complete removal of carbohydrates by microwave HCl hydrolysis. The changes in the composition of the CuTHM pyrolysates of the residues from the different microwave acid and base hydrolyses are in agreement with a major release of cutin- and suberin-derived compounds upon microwave KOH hydrolysis. The CuPy and CuTHM pyrolysates of the final residue consist predominantly of lignin-derived compounds. The study emphasizes the potential of microwave assisted hydrolysis to give a better estimate of the actual contribution of cutin to ROM than pyrolysis. However, the technique appears to be unable to completely release the lignin-based constituent of the ROM. Microwave irradiation appears to provide great potential as a tool for extraction and chemical characterisation of complex OM and could be an attractive additional technique to pyrolysis.  相似文献   

Solute concentrations of overland flow water in a cultivated field: spatial variations,intra‐ and inter‐storm trends     

Patrick Durand  Sylvie Cros‐Cayot  Chantal Gascuel‐Odoux  Djilali Heddadj 《水文研究》1999,13(10):1465-1477

Major solute concentrations in overland flow water (OFW) were measured in an agricultural field of Brittany (western France). Two storm events were monitored in detail to examine the short time‐scale processes. During one year, samples were taken at different positions on the slope after each storm event to describe the spatial and seasonal variations of OFW chemistry. Although the total dissolved load in OFW is not much higher than in rain water, distinctive features are observed. K⁺, Ca²⁺, NH₄ , Cl⁻ and SOare the major solutes. The main origin of the elements (sea salts, exchangeable soil complex or fertilizers) determined most of the variations observed. Spatial variations along the slope are mainly seen for exchangeable cations, while seasonal variations are predominant for sea salts. Rainfall intensity and suspended sediment load induce strong differences between the two storm events studied in detail. However, the within‐storm variations and the seasonal monitoring show that this relationship is complex. Within‐storm variations suggest that, in addition to desorption processes, mixing with pre‐event water may occur. The lack of a relationship between sediment load and dissolved load is attributed to the high rate of the exchange processes, which has been checked by a simple experiment in vitro. It is concluded that the conditions of the transit of water on the field (velocity, length, status of the surface, crusted or not) may well play a major role in the chemical changes between rain water and OFW. The results suggest that vegetated buffer strips designed to reduce the sediment load only, and not the amount of overland flow, will have little effect on the transfer of dissolved pollutants to the watercourses. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Sensitivity of simulated Asian and African summer monsoons to orbitally induced variations in insolation 126, 115 and 6 kBP   总被引：1，自引：1，他引：0  

Nathalie de Noblet  Pascale Braconnot  Sylvie Joussaume  Valérie Masson 《Climate Dynamics》1996,12(9):589-603

We have conducted four numerical experiments with an atmospheric general circulation model (AGCM) to investigate the sensitivity of Asian and African monsoons to small changes (–5 to +12%), with respect to present-day, in incoming solar radiation at the top of the atmosphere. We show that, during the mid-Holocene (6 kBP where kBP means thousands of years before present-day) and the last interglacial (126 kBP), the Northern Hemisphere seasonal contrast was increased, with warmer summers and colder winters. At the time of glacial inception (115 kBP) however, summers were cooler and winters milder. As a consequence, Asia and tropical North Africa experienced stronger (weaker) summer monsoons 6 and 126 kBP (115 kBP), in agreement with previous numerical studies. This present study shows that summer warming/cooling of Eurasia and North Africa induced a shift of the main low-level convergence cell along a northwest/southeast transect. When land was warmer (during the summer months 6 and 126 kBP), the monsoon winds converged further inland bringing more moisture into northern India, western China and the southern Sahara. The southern tips of India, Indochina and southeastern China, as well as equatorial North Africa became drier. When land was cooler (during the summer 115 kBP), the main convergence zone was located over the west Pacific and the wet (dry) areas were those that were dry (wet) 6 and 126 kBP. The location and intensity of the simulated precipitation maxima were therefore very sensitive to changes in insolation. However the total amount of monsoon rain in Asia as well as in Africa remained remarkably stable through the time periods studied. These simulated migrations of convective activities were accompanied by changes in the nature of precipitation events: increased monsoon rains in these experiments were always associated with more high precipitation events (> 5 mm day ^–1), and fewer light showers (1 mm day^–). Rainy days with rates between 1 and 5 mm day^–1 were almost unchanged.  相似文献   

The last 750 ka in loess–palaeosol sequences from northern France: environmental background and dating of the western European Palaeolithic     

Pierre Antoine  Sylvie Coutard  Jean-Jacques Bahain  Jean-Luc Locht  David Hérisson  Emilie Goval 《第四纪科学杂志》2021,36(8):1293-1310

This study presents an overview of Middle Pleistocene loess–palaeosol sequences (LPS) in northern France and discusses the palaeoclimatic significance of the pedosedimentary record in the context of western European LPS and of global climatic cycles for the last 750 ka. In this area, the oldest loess deposits (early Middle Pleistocene) are preserved in sedimentary traps (leeward scarps of fluvial terraces and dissolution sinkholes). They result from local deflation processes reworking Pleistocene sandy fluvial deposits or relicts of Tertiary sands. A large extension of typical calcareous loess over the landscape, the Loess Revolution, is then observed during MIS 6, with heavy mineral assemblages testifying to long-distance transport from the polar desert area of the dried eastern Channel. A correlation scheme is proposed between the global records of northern France in continental environments and both global palaeoclimatic records and other main western European LPS. After 30 years of research, northern France LPS stand as a fundamental archive of the impact of interglacial–glacial climatic cycles as well as millennial events. Finally, these works provide a robust chronoclimatic framework for the study of the western European Late Acheulean and Middle Palaeolithic and for the relative dating of the various fluvial terraces that they fossilise.  相似文献   

Post‐rift uplift of the Dhofar margin (Gulf of Aden)     

François Bache  Sylvie Leroy  Céline Baurion  Jérémy Robinet  Christian Gorini  Francis Lucazeau  Philippe Razin  Elia d'Acremont  Khalfan Al‐Toubi 《地学学报》2011,23(1):11-18

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In the aftermath of the end‐Permian extinction: the microbialite refuge?     

Marie‐Béatrice Forel  Sylvie Crasquin  Steve Kershaw  Pierre‐Yves Collin 《地学学报》2013,25(2):137-143

We present the first study of micro‐crustaceans (ostracods) associated with microbial crusts in the aftermath of the most devastating extinction, the end‐Permian extinction (EPE). These post‐extinction microbialites dominated shallow shelf marine environments and were traditionally considered as devoid of any associated fauna. We present a micro‐palaeontological analysis of a large record from microbial and non‐microbial settings following the EPE. This dataset documents the proliferation of ostracods strictly associated with microbialites. Based on the diet of extant ostracods and uniformitarianism, we propose that the abundant microbes in the mats served as an unlimited food supply. Photosynthetic cyanobacteria may also have locally provided oxygen under low oxygen conditions interpreted by others for the microbialites. Microbialites provided a specialised environment that may have acted as refuge for ostracods in the immediate aftermath of the EPE. The surviving faunas may have been progenitors for the starting of the latter radiation.  相似文献   

Petrographical and geochemical characterization of Comblanchien limestone (Bourgogne,France): A fingerprint of the building stone provenance     

Claudine Malfilatre  Philippe Boulvais  Marie-Pierre Dabard  Sylvie Bourquin  Erwan Hallot  Didier Pallix  Denis Gapais 《Comptes Rendus Geoscience》2012,344(1):14-24

The Comblanchien limestone is a well-known building stone that deserves a quantitative characterization in order to be able to certify its origin. We compare petrographical and geochemical characteristics of limestones commercialized under the name of Comblanchien to those of one of their competitors (VATC, a Portuguese coated grain-bearing limestone). From macroscopic and microscopic observations, the distinction is somehow difficult but the coated grain-bearing Comblanchien samples have δ¹³C values (from +1.75 to +2.25‰) different from those of the VATC sample (negative δ¹³C value). As an example of application of these results, three samples from a building site near Paris are also studied in order to verify their provenance. We conclude that they do not come from quarries from the Comblanchien area, but likely from Portugal. The study shows that a detailed analysis of building limestones may provide a robust tool for discriminating between currently mined stones of different provenances, and thus open the possibility to attach to a given limestone a fingerprint, an identity card, and if required a commercial label.  相似文献