New age constraints on the western Betic intramontane basins: A late Tortonian closure of the Guadalhorce Corridor?          下载免费PDF全文

Marlies van der Schee  Bas C. J. van den Berg  Walter Capella  Dirk Simon  Francisco J. Sierro  Wout Krijgsman 《地学学报》2018,30(5):325-332

Several gateways connected the Mediterranean with the Atlantic during the late Miocene but the timing of closure and therefore their role prior to and during the Messinian Salinity Crisis (5.97–5.33 Ma) is still under debate. The timing of closure of the Guadalhorce Corridor is especially disputed as the common lack of marine microfossils hampers precise age determination. Here we present new biostratigraphic age constraints on the sediments of the Ronda, Antequera and Arcos regions, which formed the northern part of the Guadalhorce Corridor. The general presence of Globorotalia menardii 4 in the youngest deep‐marine sediments of all three regions indicates a late Tortonian age, older than 7.51 Ma. We conclude that the Guadalhorce Corridor closed during the late Tortonian, well before the onset of the Messinian Salinity Crisis and that the late Tortonian tectonic uplift of the eastern Betics extended into the western Betics.  相似文献   

Global impact of a climate treaty if the Human Development Index replaces GDP as a welfare proxy     

Jeroen C. J. M. van den Bergh 《Climate Policy》2018,18(1):76-85

This study explores the implications of shifting the narrative of climate policy evaluation from one of costs/benefits or economic growth to a message of improving social welfare. Focusing on the costs of mitigation and the associated impacts on gross domestic product (GDP) may translate into a widespread concern that a climate agreement will be very costly. This article considers the well-known Human Development Index (HDI) as an alternative criterion for judging the welfare effects of climate policy. We estimate what the maximum possible annual average increase in HDI welfare per tons of CO₂ would be within the carbon budget associated with limiting warming to 2°C over the period 2015–2050. Emission pathways are determined by a policy that allows the HDI of poor countries and their emissions to increase under a business-as-usual development path, while countries with a high HDI value (>0.8) have to restrain their emissions to ensure that the global temperature rise does not exceed 2°C. For comparison, the well-known multi-regional RICE model is used to assess GDP growth under the same climate change policy goals.

Policy relevance

This is the first study that shifts the narrative of climate policy evaluation from one of GDP growth to a message of improving social welfare, as captured by the HDI. This could make it easier for political leaders and climate negotiators to publicly commit themselves to ambitious carbon emission reduction goals, such as limiting global warming to 2°C, as in the (non-binding) agreement made at COP 21 in Paris in 2015. We find that if impacts are framed in terms of growth in HDI per t CO₂ emission per capita instead of in GDP, the HDI of poor countries and their emissions are allowed to increase under a business-as-usual development path, whereas countries with a high HDI (>0.8) must control emissions so that global temperature rise remains within 2°C. Importantly, a climate agreement is more attractive for rich countries under the HDI than the GDP frame. This is good news, as these countries have to make the major contribution to emissions reductions.  相似文献   

Reducing global GHG emissions by replicating successful sector examples: the ‘good practice policies’ scenario     

Mark Roelfsema  Hanna Fekete  Niklas Höhne  Michel den Elzen  Nicklas Forsell  Takeshi Kuramochi 《Climate Policy》2018,18(9):1103-1113

This article shows the potential impact on global GHG emissions in 2030, if all countries were to implement sectoral climate policies similar to successful examples already implemented elsewhere. This assessment was represented in the IMAGE and GLOBIOM/G4M models by replicating the impact of successful national policies at the sector level in all world regions. The first step was to select successful policies in nine policy areas. In the second step, the impact on the energy and land-use systems or GHG emissions was identified and translated into model parameters, assuming that it would be possible to translate the impacts of the policies to other countries. As a result, projected annual GHG emission levels would be about 50 GtCO₂e by 2030 (2% above 2010 levels), compared to the 60 GtCO₂e in the ‘current policies’ scenario. Most reductions are achieved in the electricity sector through expanding renewable energy, followed by the reduction of fluorinated gases, reducing venting and flaring in oil and gas production, and improving industry efficiency. Materializing the calculated mitigation potential might not be as straightforward given different country priorities, policy preferences and circumstances.

Key policy insights

• Considerable emissions reductions globally would be possible, if a selection of successful policies were replicated and implemented in all countries worldwide.

• This would significantly reduce, but not close, the emissions gap with a 2°C pathway.

• From the selection of successful policies evaluated in this study, those implemented in the sector ‘electricity supply’ have the highest impact on global emissions compared to the ‘current policies’ scenario.

• Replicating the impact of these policies worldwide could lead to emission and energy trends in the renewable electricity, passenger transport, industry (including fluorinated gases) and buildings sector, that are close to those in a 2°C scenario.

• Using successful policies and translating these to policy impact per sector is a more reality-based alternative to most mitigation pathways, which need to make theoretical assumptions on policy cost-effectiveness.

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Variability in the speciation of iron in the northern North Sea     

Martha Gledhill  Constant M. G. van den Berg  Rob F. Nolting  Klaas R. Timmermans 《Marine Chemistry》1998,59(3-4)

Variations in the speciation of iron in the northern North Sea were investigated in an area covering at least two different water masses and an algal bloom, using a combination of techniques. Catalytic cathodic stripping voltammetry was used to measure the concentrations of reactive iron (Fe_R) and total iron (Fe_T) in unfiltered samples, while dissolved iron (Fe_D) was measured by GFAAS after extraction of filtered sea water. Fe_R was defined by the amount of iron that complexed with 20 μM 1-nitroso-2-napthol (NN) at pH 6.9. Fe_T was determined after UV-digestion at pH 2.4. Concentrations of natural organic iron complexing ligands and values for conditional stability constants, were determined in unfiltered samples by titration. Mean concentrations of 1.3 nM for Fe_R, 10.0 nM for Fe_T and 1.7 nM for Fe_D were obtained for the area sampled. Fe_R concentrations increased towards the south of the area investigated, as a result of the increased influence of continental run off. Fe_R concentrations were found to be enhanced below the nutricline (below 40 m) as a result of the remineralisation of organic material. Enhanced levels of Fe_T were observed in some surface samples and in samples collected below 30 m at stations in the south of the area studied, thought to be a result of high concentrations of biogenic particulate material and the resuspended sediments respectively. Fe_D concentrations varied between values similar to those of Fe_T in samples from the north of the area to values similar to those of Fe_R in the south. The bloom was thought to have influenced the distribution of both Fe_R and Fe_T, but less evidence was observed for any influence on Fe_R and Fe_D. The concentration of organic complexing ligands, which could possibly include a contribution from adsorption sites on particulate material, increased slightly in the bloom area and in North Sea waters. Iron was found to be fully (99.9%) complexed by the organic complexing ligands at a pH of 6.9 and largely complexed (82–96%) at pH 8. The ligands were almost saturated with iron suggesting that the ligand concentration could limit the concentration of iron occurring as dissolved species.  相似文献   

Responses of marine phytoplankton in iron enrichment experiments in the northern North Sea and northeast Atlantic Ocean     

Klaas R. Timmermans  Martha Gledhill  Rob F. Nolting  Marcel J. W. Veldhuis  Hein J. W. de Baar  Constant M. G.van den Berg 《Marine Chemistry》1998,61(3-4)

Short-term iron enrichment experiments were carried out with samples collected in areas with different phytoplankton activity in the northern North Sea and northeast Atlantic Ocean in the summer of 1993. The research area was dominated by high numbers of pico-phytoplankton, up to 70,000 ml⁻¹. Maximum chlorophyll a concentrations varied from about 1.0 μg l⁻¹ in a high-reflectance zone (caused by loose coccoliths, remnants from a bloom of Emiliania huxleyi) and about 3.5 μg l⁻¹ in a zone in which the phytoplankton were growing, to about 0.5 μg l⁻¹ in the northeast Atlantic Ocean. From the high-reflectance zone to the northeast Atlantic Ocean, nitrate concentrations increased from 0.5 μM to 6.0 μM. Concentrations of reactive iron in surface water showed an opposite trend and decreased from about 2.6 nM in the high-reflectance zone to <1.0 nM in the northeast Atlantic Ocean. In the research area, no signs of true iron deficiency were found, but iron enrichments in the high-reflectance zone, numerically dominated by Synechococcus sp., resulted in increased nitrate uptake. Ammonium uptake was hardly affected. Strong support for the effect of Fe on cell physiology is given by the increase in the f-ratio. Net growth rates of the phytoplankton (changes in cell numbers over 24 h) were almost unchanged. Phytoplankton collected from the northeast Atlantic Ocean, did not show changes in the nitrogen metabolism upon addition of iron. Net growth rates in these incubations were low or negative, with only slightly higher values with additional iron.  相似文献   

Metamorphic charnockite in contact aureoles around intrusive enderbite from Natal, South Africa     

Alfons M. van den Kerkhof  Geoffrey H. Grantham 《Contributions to Mineralogy and Petrology》1999,137(1-2):115-132

In the Port Edward area of southern Kwa-Zulu Natal, South Africa, charnockitic aureoles up to 10 m in width in the normally garnetiferous Nicholson's Point Granite, are developed adjacent to intrusive contacts with the Port Edward Enderbite and anhydrous pegmatitic veins. Mineralogical differences between the country rock and charnockitic aureole suggest that the dehydration reaction Bt + Qtz → Opx + Kfs + H₂O and the reaction of Grt + Qtz → Opx + Pl were responsible for the charnockitization. The compositions of fluid inclusions show systematic variation with: (1) the Port Edward Enderbite being dominated by CO₂ and N₂ fluid inclusions; (2) the non-charnockitized granite by saline aqueous inclusions with 18–23 EqWt% NaCl; (3) the charnockitic aureoles by low-salinity and pure water inclusions (<7 EqWt% NaCl); (4) the pegmatites by aqueous inclusions of various salinity with minor CO₂. As a result of the thermal event the homogenization temperatures of the inclusions in charnockite show a much larger range (up to 390 °C) compared to the fluid inclusions in granite (mostly <250 °C). Contrary to fluid-controlled charnockitization (brines, CO₂) which may have taken place along shear zones away from the intrusive body, the present “proximal” charnockitized granite formed directly at the contact with enderbite. The inclusions indicate contact metamorphism induced by the intrusion of “dry” enderbitic magma into “wet” granite resulting in local dehydration. This was confirmed by cathodoluminescence microscopy showing textures indicative for the local reduction of structural water in the charnockite quartz. Two-pyroxene thermometry on the Port Edward Enderbite suggests intrusion at temperatures of ∼1000–1050 °C into country rock with temperature of <700 °C. The temperature of aureole formation must have been between ∼700 °C (breakdown of pyrite to form pyrrhotite) and ∼1000 °C. Charnockitization was probably controlled largely by heat related to anhydrous intrusions causing dehydration reactions and resulting in the release and subsequent trapping of dehydration fluids. The salinity of the metamorphic fluid in the contact zones is supposed to have been higher at an early stage of contact metamorphism, but it has lost its salt content by K-metasomatic reactions and/or the preferential migration of the saline fluids out of the contact zones towards the enderbite. The low water activity inhibited the localized melting of the granite. Mineral thermobarometry suggests that after charnockite aureole genesis, an isobaric cooling path was followed during which reequilibration of most of the aqueous inclusions occurred. Received: 8 November 1998 / Accepted: 21 June 1999  相似文献   

X‐shooting Herbig Ae/Be stars: Accretion probed by near‐infrared He I emission     

R.D. Oudmaijer  M.E. van den Ancker  D. Baines  P. Caselli  J.E. Drew  M.G. Hoare  S.L. Lumsden  B. Montesinos  S. Sim  J.S. Vink  H.E. Wheelwright  W.J. de Wit 《Astronomische Nachrichten》2011,332(3):238-241

The Herbig Ae/Be stars are intermediate mass pre‐main sequence stars that bridge the gap between the low mass T Tauri stars and the Massive Young Stellar Objects. In this mass range, the acting star forming mechanism switches from magnetically controlled accretion to an as yet unknown mechanism, but which is likely to be direct disk accretion onto the star. We observed a large sample of Herbig Ae/Be stars with X‐shooter to address this issue from a multi‐wavelength perspective. It is the largest such study to date, not only because of the number of objects involved, but also because of the large wavelength coverage from the blue to the near‐infrared. This allows many accretion diagnostics to be studied simultaneously. By correlating the various properties with mass, temperature and age, we aim to determine where and whether the magnetically controlled mass accretion mechanism halts and the proposed direct disk accretion takes over. Here, we will give an overview of the background, present some observations and discuss our initial results. We will introduce a new accretion diagnostic for the research of Herbig Ae/Be stars, the HeI 1.083 μm line (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

The impact of disposal of fine-grained sediments from maintenance dredging works on SPM concentration and fluid mud in and outside the harbor of Zeebrugge     

Michael Fettweis  Matthias Baeye  Claudio Cardoso  Arvid Dujardin  Brigitte Lauwaert  Dries Van den Eynde  Thomas Van Hoestenberghe  Joris Vanlede  Luc Van Poucke  Carlos Velez  Chantal Martens 《Ocean Dynamics》2016,66(11):1497-1516

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UML‐Based Approach to Developing a CityGML Application Domain Extension     

Linda van den Brink  Jantien Stoter  Sisi Zlatanova 《Transactions in GIS》2013,17(6):920-942

Recently a national 3D standard was established in the Netherlands as a CityGML Application Domain Extension (called IMGeo). In line with the Dutch practice of modeling geo‐information, the ADE is developed using a model driven approach. The classes are designed in UML and automatically mapped to GML schema. The current OGC CityGML specification does not provide rules or guidance on correctly modeling an ADE in UML. This article fills this gap by studying how CityGML can be extended for specific applications starting from the UML diagrams. Six alternatives for modeling ADEs in UML are introduced and compared. The optimal alternative is selected and applied to obtain the national 3D standard. The approach was extensively discussed with international experts, who were members of both SIG3D and other working groups. As a consequence the approach was adopted by the SIG3D, the Special Interest Group 3D which, among other things, work on the 3D standard CityGML in cooperation with OGC. Therefore the approach contains many issues that can be generalized and reused by future domain extensions of CityGML. To further support this, the article formulates a model‐driven framework to model CityGML ADEs. Open issues are described in the conclusions.  相似文献   

Transient release of Ni,Mn and Fe from mixed metal sulphides under oxidising and reducing conditions     

C. Naylor  W. Davison  M. Motelica-Heino  L. M. van der Heijdt  G. A. van den Berg 《Environmental Earth Sciences》2012,65(7):2139-2146

The potential release of metals from anoxic sediments exposed to oxygen was investigated by using a synthetic preparation of metal sulphides dominated by solid phase FeS. The technique of DGT (diffusive gradients in thin-films) was used to measure sulphide and Fe, Mn and Ni in the anoxic metal-sulphide slurry, which had a pH of 6.4. Speciation calculations based on these data showed there was moderate supersaturation with respect to amorphous FeS in the solution phase. Measurements made using DGT with a range of diffusion layer thicknesses showed that when Fe, Mn and Ni are removed from solution there is fairly rapid (minutes) release from the solid phase, that is reasonably well sustained. This presumed desorptive release will be responsible for elevated concentrations of some metals in solution when sediments are resuspended. Oxidation of the slurry by bubbling with air rapidly (hours) removed Fe, Mn and Ni from the pore water solution. While Fe concentrations in solution remained low after the removal, Mn and Ni were transiently released. These results were consistent with initial rapid oxidation of Fe(II) to oxyhydroxides, which remove Mn(II) and Ni by adsorption. The slower oxidation of FeS then releases Mn and Ni, but these too are eventually removed by adsorption to iron oxyhydroxides. These data suggest that oxidation of metal sulphides will contribute to the release of metals from sediment disturbed by dredging or remedial aeration, but it is likely to be short lived, with complete removal within a day.  相似文献