Cation distribution in pentlandites (Fe,Ni)9S8: Dependence on pressure and temperature and kinetics of the cation exchange reaction     

Katsuhiro Tsukimura  Hiromoto Nakazawa  Tadashi Endo  Osamu Fukunaga 《Physics and Chemistry of Minerals》1992,19(4):203-212

This paper describes the distribution of Fe and Ni between the octahedral and tetrahedral sites in pentlandite (Fe,Ni)₉S₈. The dependence of the distribution on pressure and temperature and the activation energy of the cation exchange reaction were determined through annealing experiments. Synthetic crystals were annealed at 433–723 K and pressures up to 4 GPa, and natural crystals were annealed at 423, 448 and 473 K in evacuated silica capillary tubes for various durations. The cation distributions in the synthetic crystals were determined with an X-ray powder method employing the anomalous dispersion effect of CuK. and FeK radiations, while those of natural crystals were calculated from the cell dimensions. The values of U, S and V for the Fe/Ni exchange reaction are –6818 J mol^–1, 20.52 J K^–1 mol^–1, and 6.99 × 10^–6 m³ mol^–1, respectively. The dependence of the Fe/Ni distribution on pressure (Pa) and temperature (Kelvin) was determined as lnK = 2.47+8.20 × 10² T ^–1+8.41 x 10^–7 T ^–1 P, where K = (Fe/Ni)_octahedral /(Fe/Ni)_tetrahedral. The activation energy of the cation exchange reaction was 185 kJ mol^–1.  相似文献   

The effects of the spinel—garnet phase transition on the formation of rifted sedimentary basins     

Tadashi Yamasaki  Masao Nakada 《Geophysical Journal International》1997,130(3):681-692

We have examined the effects of the spinel-garnet phase transition on subsidence of extensional sedimentary basins. For a constant positive Clapeyron slope ( dP/dT ), the phase boundary moves downwards in the syn-rift and upwards in the post-rift phase. For a non-linear Clapeyron curve ( dP/dT > 0 above 900°C and dP/dT < 0 below 900°C), theory predicts for the reaction of the spinel-garnet phase transition, the direction of phase boundary movement is dependent on the stretching factor, the position of the Clapeyron curve and the lithospheric thickness. A smaller syn-rift and larger post-rift subsidence are predicted for a deeper phase boundary and a thicker lithosphere. The model with a non-linear Clapeyron curve is applied to the subsidence histories of a young extensional basin (Gulf of Lion) and an old continental margin (eastern Canada). The observed syn-rift uplift and the larger post-rift subsidence can be reasonably explained by this model, where the optimum depth of the phase boundary for eastern Canada (˜90 km) is consistent with the estimate from seismic observations and is larger than that for the Gulf of Lion (˜ 50 km). The depth of the spinel-garnet phase boundary is sensitive to the composition of mantle rocks and increases with the extraction of basaltic components from the lithosphere, compatible with our result that the phase boundary is deeper for an older and thicker lithosphere. Thus the surface movement associated with the rifting for these areas may reflect the chemical evolution of the continental lithosphere.  相似文献   

Paleogeographic maps of the Japanese Islands: Plate tectonic synthesis from 750 Ma to the present   总被引：73，自引：1，他引：73  

Shigenori  Maruyama  Yukio  Isozaki  Gaku  Kimura Masaru  Terabayashi 《Island Arc》1997,6(1):121-142

Abstract A series of paleogeographic maps of the Japanese Islands, from their birth at ca 750–700 Ma to the present, is newly compiled from the viewpoint of plate tectonics. This series consists of 20 maps that cover all of the major events in the geotectonic evolution of Japan. These include the birth of Japan at the rifted continental margin of the Yangtze craton ( ca 750-700 Ma), the tectonic inversion of the continental margin from passive to active ( ca 500 Ma), the Paleozoic accretionary growth incorporating fragments from seamounts and oceanic plateaux ( ca 480-250 Ma), the collision between Sino-Korea and Yangtze (250–210 Ma), the Mesozoic to Cenozoic accretionary growth (210 Ma-present) including the formation of the Cretaceous paired metamorphic belts (90 Ma), and the Miocene back-arc opening of the Japan Sea that separated Japan as an island arc (25-15 Ma).  相似文献   

Fundamental study on the response characteristics of drivers during an earthquake based on driving simulator experiments     

Yoshihisa Maruyama  Fumio Yamazaki 《地震工程与结构动力学》2004,33(6):775-792

After the 1995 Kobe earthquake, the expressway structures in Japan were retrofitted and they will not now be seriously damaged under a certain level of strong earthquake motion. However, the stability of a moving vehicle has not been investigated yet. It has been reported that drivers feel seismically induced vibrations, especially in the transverse direction of vehicles. Owing to this phenomenon, drivers have some difficulty in controlling the vehicles during strong shaking. For further safety promotion of the expressway networks, it is important to understand the drivers' reactions to seismic motion. The present authors have performed a series of seismic response analyses of a moving vehicle to investigate its response characteristics based on numerical simulation. However, the responses of the driver were not considered in the simulation process. In order to investigate the drivers' reactions during an earthquake, a series of virtual tests were conducted using a driving simulator. This driving simulator has six servomotor‐powered electric actuators that control its motions. Several types of tests were carried out for different examinees to investigate drivers' responses while controlling the simulator under seismic motion. The results of this study showed that a larger response time lag to strong shaking and over turning of the steering wheel may shift the vehicle into the next lane. According to this finding, trafficaccidents could possibly occur under strong ground shaking in the case of heavy traffic. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Experimental and theoretical study of stability of dense hydrous magnesium silicates in the deep upper mantle     

Tetsuya Komabayashi  Soichi Omori  Shigenori Maruyama 《Physics of the Earth and Planetary Interiors》2005,153(4):191-209

Fluid-undersaturated experiments were conducted to determine the phase relations in the simplified peridotite system MgO-SiO₂-H₂O (MSH) at 11.0-14.5 GPa and 800-1400 °C. Stability relations of dense hydrous magnesium silicates (DHMSs) under fluid-undersaturated conditions were experimentally examined. From the fluid-absent experimental results, we retrieved thermodynamic data for clinohumite, phase A, phase E, and hydrous wadsleyite, consistent with the published data set for dry mantle minerals. With this new data set, we have calculated phase equilibria in the MSH system including dehydration reactions. The dehydration reactions calculated with lower water activities of 0.68-0.60 match the fluid-present experiments of this study above 11.0 GPa and 1000 °C, indicating that considerable amounts of silicate component were dissolved into the fluid phase. The calculated phase equilibria illustrate the stability of the post-antigorite phase A-bearing assemblages. In the cold subducting slab peridotite, phase A + enstatite assemblage survives into the transition zone, whereas phase A + forsterite + enstatite assemblage forms hydrous wadsleyite at a much shallower depth of about 360-km. The slab is subducted with no dehydration reactions occurring when entering the transition zone. The phase equilibria also show the high temperature stability of phase E. Phase E is stable up to 1200 °C at 13.5 GPa, a plausible condition in the mantle of relatively low temperature, i.e., beneath subduction zones. Phase E is a possible water reservoir in the mantle as well as wadsleyite and ringwoodite.  相似文献   

Measures for groundwater security during and after the Hanshin-Awaji earthquake (1995) and the Great East Japan earthquake (2011), Japan     

Tadashi Tanaka 《Hydrogeology Journal》2016,24(2):277-286

Many big earthquakes have occurred in the tectonic regions of the world, especially in Japan. Earthquakes often cause damage to crucial life services such as water, gas and electricity supply systems and even the sewage system in urban and rural areas. The most severe problem for people affected by earthquakes is access to water for their drinking/cooking and toilet flushing. Securing safe water for daily life in an earthquake emergency requires the establishment of countermeasures, especially in a mega city like Tokyo. This paper described some examples of groundwater use in earthquake emergencies, with reference to reports, books and newspapers published in Japan. The consensus is that groundwater, as a source of water, plays a major role in earthquake emergencies, especially where the accessibility of wells coincides with the emergency need. It is also important to introduce a registration system for citizen-owned and company wells that can form the basis of a cooperative during a disaster; such a registration system was implemented by many Japanese local governments after the Hanshin-Awaji Earthquake in 1995 and the Great East Japan Earthquake in 2011, and is one of the most effective countermeasures for groundwater use in an earthquake emergency. Emphasis is also placed the importance of establishing of a continuous monitoring system of groundwater conditions for both quantity and quality during non-emergency periods.  相似文献   

High-reliability zircon separation for hunting the oldest material on Earth: An automatic zircon separator with image-processing/microtweezers-manipulating system and double-step dating     

Yukio Isozaki  Shinji Yamamoto  Shuhei Sakata  Hideyuki Obayashi  Takafumi Hirata  Ken-ichi Obori  Toshinori Maebayashi  Satoshi Takeshima  Toshikazu Ebisuzaki  Shigenori Maruyama 《地学前缘(英文版)》2018,9(4):1073-1083

Despite the recent development in radiometric dating of numerous zircons by LA-ICPMS, mineral separation still remains a major obstacle, particularly in the search for the oldest material on Earth. To improve the efficiency in zircon separation by an order of magnitude, we have designed/developed a new machine-an automatic zircon separator(AZS). This is designed particularly for automatic pick-up of100 μm-sized zircon grains out of a heavy mineral fraction after conventional separation procedures. The AZS operates in three modes:(1) image processing to choose targeted individual zircon grains out of all heavy minerals spread on a tray,(2) automatic capturing of the individual zircon grains with microtweezers, and(3) placing them one-by-one in a coordinated alignment on a receiving tray. The automatic capturing was designed/created for continuous mineral selecting without human presence for many hours. This software also enables the registration of each separated zircon grain for dating, by recording digital photo-image, optical(color) indices, and coordinates on a receiving tray. We developed two new approaches for the dating; i.e.(1) direct dating of zircons selected by LA-ICPMS without conventional resin-mounting/polishing,(2) high speed U-Pb dating, combined with conventional sample preparation procedures using the new equipment with multiple-ion counting detectors(LA-MIC-ICPMS).With the first approach, Pb-Pb ages obtained from the surface of a mineral were crosschecked with the interior of the same grain after resin-mounting/polishing. With the second approach, the amount of time required for dating one zircon grain is ca. 20 s, and a sample throughput of 150 grains per hour can be achieved with sufficient precision(ca. 0.5%).We tested the practical efficiency of the AZS, by analyzing an Archean Jack Hills conglomerate in Western Australia with the known oldest(4.3 Ga) zircon on Earth. Preliminary results are positive; we were able to obtain more than 194 zircons that are over 4.0 Ga out of ca. 3800 checked grains, and 9 grains were over 4300 Ma with the oldest at 4371 ± 7 Ma. This separation system by AZS, combined with the new approaches, guarantees much higher yield in the hunt for old zircons.  相似文献   

U-Pb ages of detrital zircons from modern sediments of the Yangtze River and stages of orogeny in Southeast Asia   总被引：1，自引：0，他引：1  

I. Yu. Safonova  Sh. Rino  Sh. Maruyama 《Doklady Earth Sciences》2010,431(1):280-284

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Pressure and temperature dependence of cation distribution in Mg-Mn olivine     

Tadashi Akamatsu  Kiyoshi Fujino  Mineo Kumazawa  Akio Fujimura  Manabu Kato  Hiroshi Sawamoto  Takamitsu Yamanaka 《Physics and Chemistry of Minerals》1988,16(2):105-113

Synthetic (Mg_0.51, Mn_0.49)₂SiO₄ olivine samples are heat-treated at three different pressures; 0, 8 and 12 GPa, all at the same temperature (～500° C). X-ray structure analyses on these single crystals are made in order to see the pressure effect on cation distribution. The intersite distribution coefficient of Mg and Mn in M1 and M2 sites, K _D = (Mn/Mg) _M1/(Mn/Mg) _M2, of these samples are 0.192 (0 GPa), 0.246 (8 GPa) and 0.281 (12 GPa), indicating cationic disordering with pressure. The small differences of cell dimensions between these samples are determined by powder X-ray diffraction. Cell dimensions b and c decrease, whereas a increases with pressure of equilibration. Cell volume decreases with pressure as a result of a large contraction of the b cell dimension. The effect of pressure on the free energy of the cation exchange reaction is evaluated by the observed relation between the cell volume and the site occupancy numbers. The magnitude of the pressure effect on cation distribution is only a fifth of that predicted from the observed change in volume combined with thermodynamic theory. This phenomenon is attributed to nonideality in this solid solution, and nonideal parameters are required to describe cation distribution determined in the present and previous experiments. We use a five-parameter equation to specify the cationic equilibrium on the basic of thermodynamic theory. It includes one energy parameter of ideal mixing, two parameters for nonideal effects, one volume parameter, and one thermal parameter originated from the lattice vibrational energy. The present data combined with some of the existing data are used to determine the five parameters, and the cation distribution in Mg-Mn olivine is described as a function of temperature, pressure, and composition. The basic framework of describing the cationic behavior in olivine-type mineral is worked out, although the result is preliminary: each of the determined parameters is not accurate enough to enable us to make a reliable prediction.  相似文献   

Tectonic evolution of the ultrahigh-pressure (UHP) and high-pressure (HP) metamorphic belts from central China   总被引：28，自引：0，他引：28  

Shigenori  Maruyama  J. G. Liou  Ruyuan  Zhang 《Island Arc》1994,3(2):112-121

Abstract In the Triassic suture between the Sino-Korean and Yangtze cratons, the Dabie metamorphic Complex in central China includes three tectonic units: the northern Dabie migmatitic terrane, the central ultrahigh-P coesite- and diamond-bearing eclogite belt, and the southern high-P blueschist-eclogite belt. This complex is bounded to the north by a north-dipping normal fault with a Paleozoic accretionary complex and to the south by a north-dipping reverse fault with Yangtze basement plus its foreland fold-and-thrust sequence. Great differences in metamorphic pressure suggests that these units reached different depths during metamorphism and their juxtaposition occurred by wedge extrusion of subducted old continental fragments. These units were subsequently subjected to (i) Barrovian type regional metamorphism and deformation at shallow depths; (ii) intrusion of Cretaceous granitic plutons; and (iii) doming and segmentation into several blocks by normal and strike-slip faults. A new speculative model of tectonic exhumation of UHP rocks is proposed.  相似文献