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31.
The temperature and pressure differences between Tokyo and Nagasaki were used to reconstruct past climate conditions. January and July in each available year since the 1820s were classified into several types with characteristic sea level atmospheric pressure patterns. This results in 18 years of pre-1881 data and a continuous series thereafter. The series indicate that the warming after 1900 (after the end of the so-called Little Ice Age) and again after 1960 can at least partly be attributed to an increase in the frequency of warm circulation pattern types at the expense of cold types. The difference in nature of the shifts in circulation types that occurred in the late nineteenth century compared with that in the late twentieth centuries suggests that the mechanism behind the warming in the late nineteenth century differs from that in the late twentieth century.  相似文献   
32.
In pelitic schists composed mainly of quartz and albite grains, the morphology of intergranular pores, which were filled with water, was studied by transmission electron microscopy (TEM). Although some pores are defined by crystallographic planes (F-face), most of their form has an ideal shape determined by interface tensions between grains and fluid. High-resolution TEM observations demonstrate that pore-free regions at grain boundaries are tight even at the nanometer scale, showing that the wetting angle is larger than 0° in this rock. The pore distribution in two-grain junctions can be compared to a "necklace microstructure" developed by instability of a fluid film along the boundary induced by microcracking. Wetting angles for pores located at grain edges of quartz and albite decrease in the order albite/albite, quartz/quartz, and quartz/albite. The quartz/quartz wetting angle in a calcite-free sample is smaller than that in a calcite-containing sample. This angle also changes due to grain misorientation. Our results confirm that solid-solid and solid-fluid interfacial energies control the geometry of intergranular fluid in natural rocks.  相似文献   
33.
Synthetic clinoenstatite (MgSiO3) has been converted to a single phase with the perovskite structure in complete reactions at approx. 300 kbar in experiments that utilize the laser-heated diamond-anvil pressure apparatus. The structure of this phase after quenching was determined by powder X-ray diffraction intensity measurement to be similar to that of the distorted rare-earth, orthoferrite-type, orthorhombic perovskites, but it is suggested that such distortion from ideal cubic perovskite would diminish at high pressure. The unit cell dimensions and density of perovskite-type MgSiO3 at ambient conditions (1 bar, 25°C) are a=4.780(1) Å, b=4.933(1) Å, c=6.902(1) Å, V=162.75 Å3, and ρ=4.098(1) g/cm3. This phase is 3.1% denser than the isochemical oxide mixture [periclase (MgO)+stishovite (SiO2)]. The small crystal-field stabilization energy of the cation site in the perovskite structure may play an important role in limiting the high-pressure stability field of perovskites that contain transition metal cations. Approximate calculations of the crystal-field effects indicate that perovskite of pure FeSiO3 composition may become stable at 400–600 kbar; pressures greater than 800 kbar would be required to stabilize CoSiO3 or NiSiO3 perovskite.  相似文献   
34.
The impervious surface area (ISA) has emerged not only as an indicator of the degree of urbanization, but also as a major indicator of environmental quality for drainage basin management. However, since almost all of the methods for estimating ISA have been developed for urban environments, it is questionable whether these methods can be successfully applied to drainage basins, such as those found in Japan, which usually have more complicated vegetation components (e.g. paddy field, plowed field and dense forest). This paper presents a pre-screened and normalized multiple endmember spectral mixture analysis (PNMESMA) method, which includes a new endmember selection strategy and an integration of the normalized spectral mixture analysis (NSMA) and multiple endmember spectral mixture analysis (MESMA), for estimating the ISA fraction in Lake Kasumigaura Basin, Japan. This new proposed method is superior to the previous methods in that the estimation error of the proposed method is much smaller than the previous SMA- or NSMA-based methods for drainage basin environments. The overall root mean square error was reduced to 5.2%, and no obvious underestimation or overestimation occurred for high or low ISA areas. Through the assessment of environmental quality in Lake Kasumigaura Basin using the ISA fraction, the results showed that the basin has been in the impacted category since 1987, and that in the two decades since, the environmental quality has continued to decline. If this decline continues, then Lake Kasumigaura Basin will fall into the degraded category by 2017.  相似文献   
35.
We present a vertical vibration isolator having a piecewise‐constant restoring force, which belongs to a class of passive and nonlinear vibration isolators. In vertical vibration isolation, direct use of low‐stiffness elements leads to unacceptably large deformations due to self‐weight. To overcome the difficulty, we apply a combination of constant‐force springs, each of which sustains a constant load regardless of its stretch. By arranging the constant‐force springs, so that the isolator has a piecewise‐constant restoring force, we alleviate the problem of the excessive deformation caused by self‐weight, provide stability at the static equilibrium state along with the self‐centering capability, and realize a large stroke while keeping the mechanism simple and compact. Further, we attempt to limit the response acceleration within a tolerance regardless of the frequency spectrum and the magnitude of earthquake ground motions. We demonstrate the effectiveness of the present isolator through shaking table tests and numerical simulations. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
36.
Tephra fingerprinting techniques contributing to volcanology and palaeoenvironmental studies have been developed using a combination of laser-ablation inductively coupled-plasma mass spectrometry (LA-ICP-MS) and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS). In particular, femtosecond LA-ICP-MS can determine major- and trace element abundances in individual glass shards. On the basis of the major oxide and trace element composition of the glass shards, using those methods, we re-examined the identification of four lower Pleistocene tephras originating from north-east Japan. All trace element abundances exhibited the typical pattern of tephras from the Hokkaido–Tohoku area, and major element concentrations were distinct. As a result, we re-examined the correlation of the widespread Tmg-R4 tephra (2.0 Ma), and newly defined the widespread Kd44-Naka tephra (1.968–1.781 Ma), both originating from the Sengan geothermal region. Furthermore, we re-examined identifications of Sr-Asn-Kd8 (1.219 Ma) and Sr-Kc-U8 (0.922–0.910 Ma) in central Japan, both derived from the Aizu volcanic region. The extensive distributions of the former two tephras suggest the occurrence of two large caldera-forming eruptions (Volcanic Explosivity Index 7) during a short period. Also, the distributions and volumes of the latter two tephras are broader and larger than those previously assumed. The results provide insight into large volcanic eruption history and terrestrial and marine palaeoenvironmental history.  相似文献   
37.
A Middle Pleistocene widespread tephra, defined here as Hegawa-Kasamori 5 tephra (Hgw-Ks5), has been newly recognized over a broad area of Japan. Large-scale pyroclastic flow deposits associated with co-ignimbrite ash fall deposits (CAFDs) of Hgw-Ks5 have been identified in the proximal southern Kyushu area, south-west Japan. Hgw-Ks5 possibly originated from the Aira caldera in southern Kyushu, and it is widely spread and intercalated with deposits of the Kasamori Formation, Honshu Island, more than 1000 km away from the source. In the north-west area of the Aira Caldera, the tephra is sparsely distributed in the form of non-welded ignimbrites, and is exposed stratigraphically above the well-known Kobayashi-Kasamori tephra. Hgw-Ks5 is characterized through petrographic features, major element geochemistry of glass shards, and refractive indices of orthopyroxene. The results of previous stratigraphic isotope studies indicate that the eruptive age of Hgw-Ks5 is 434–458 ka (Marine Isotope Stage 12). Assuming that the CAFDs originating from the Aira Caldera are distributed concentrically, the apparent volume of Hgw-Ks5, estimated from the area of distribution and CAFD thickness, is ~100 km3. Therefore, a volcanic explosivity index of 7 is assigned to the Hgw-Ks5 eruption.  相似文献   
38.
Sediment core samples from the center of Lake Kasumigaura, Japan, were collected from 1979 to 2007 at intervals of 1 month to 5 yr. We evaluated the degree of modification in N isotope composition during sedimentation and diagenesis. We estimated the degree of isotope discrimination during diagenesis by comparing historical changes in N isotope composition of the surface sediment (top 2 cm) against the vertical profile of the isotope composition of sediment core samples (15 cm depth). The degree of 15N enrichment during sedimentation appeared to be significant under the preferential N decomposition that occurred in the periods with low C/N ratio values of suspended particulate organic matter. We documented 15N depletion in sediment deeper than approximately 3 cm during diagenesis. The contrasting directions of N isotope discrimination during sedimentation and diagenesis suggest changing mechanisms of isotopic shift across an oxidation-reduction boundary.  相似文献   
39.
This paper presents a study of the usefulness of flood layers as a time marker in sediments and a report of a case study of Lake Kizaki in central Japan. A flood layer can be identified as a layer having a higher density, coarser grain size, lower TN content, and higher C/N ratio than those of the upper and lower horizons. It can also be characterized by a hyperpycnal sequence composed of a basal coarsening-upward unit and a top fining-upward unit. When flood layers can be correlated with heavy rains in meteorological records, detailed age markers are well established in the sediment. Five flood layers were identified in the surface sediment of Lake Kizaki, and they could be attributed to the historical heavy rainfalls that took place on July 12, 1995; September 28, 1983; August 25, 1974; September 26, 1959; and September 1, 1949 under the constraint of an age model. A precise age model is essential to clarify the environmental changes such as the pollutant history in detail.  相似文献   
40.
Lattice preferred orientations (LPO) developed in perovskite and post-perovskite structured CaIrO3 were studied using the radial X-ray diffraction technique combined with a diamond anvil cell. Starting materials of each phase were deformed from 0.1 MPa to 6 GPa at room temperature. Only weak LPO was formed in the perovskite phase, whereas strong LPO was formed in the post-perovskite phase with an alignment of the (010) plane perpendicular to the compression axis. The present result suggests that the (010) is a dominant slip plane in the post-perovskite phase and it is in good agreement with the crystallographic prediction, dislocation observations via transmission electron microscopy, and a recent result of simple shear deformation experiment at 1 GPa–1,173 K. However, the present result contrasts markedly from the results on MgGeO3 and (Mg,Fe)SiO3, which suggested that the (100) or (110) is a dominant slip plane with respect to the post-perovskite structure. Therefore it is difficult to discuss the behavior of the post-perovskite phase in the Earth’s deep interior based on existing data of MgGeO3, (Mg,Fe)SiO3 and CaIrO3. The possible sources of the differences between MgGeO3, (Mg,Fe)SiO3 and CaIrO3 are discussed.  相似文献   
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