Synthesis of crystallographically oriented olivine aggregates using colloidal processing in a strong magnetic field     

Sanae Koizumi  Tohru S. Suzuki  Yoshio Sakka  Kosuke Yabe  Takehiko Hiraga 《Physics and Chemistry of Minerals》2016,43(10):689-706

This study develops a fabrication technique to obtain Fe-free and Fe-bearing (Fe:Mg = 1:9) olivine aggregates not only with high density and fine grain size but with crystallographic preferred orientation (CPO). A magnetic field (≤12 T) is applied to synthetic, fine-grained (~120 nm), olivine particles dispersed in solvent. The alignment of certain crystallographic axes of the particles with respect to a magnetic direction is anticipated due to magnetic anisotropy of olivine. The dispersed particles are gradually consolidated on a porous alumina mold covered with a solid–liquid separation filter during drainage of the solvent. The resultant aligned consolidated aggregate is then isostatically pressed and vacuum sintered. We find that (1) preparation of fully reacted olivine particles, with less propensity to coalesce; (2) preparation of a suspension with highly dispersed particles; and (3) application of a certain strength of the magnetic field are essential to obtain well-sintered and well-aligned aggregates. High density (i.e., <1 vol% porosity) and fine grain size (~1 μm) Fe-free and Fe-bearing olivine aggregates were successfully synthesized with uniaxially aligned a- and c-axes, respectively. Attempts to uniaxially align the magnetization hard axis and to triaxially align Fe-bearing olivine by rotating the suspension in the magnetic field succeeded in obtaining weakly developed CPO aggregates.  相似文献   

Characterizing the flush of stream chemical runoff from forested watersheds     

Zhao Zhang  Fulu Tao  Peijun Shi  Wei Xu  Yu Sun  Takehiko Fukushima  Yuichi Onda 《水文研究》2010,24(20):2960-2970

A flush can be defined as stream chemical exhibiting higher concentrations during the prophase of a storm event at an event scale, or exhibiting progressively lower concentrations during several successive storms at a seasonal scale. Investigating the flush characteristics of chemical runoff from forested watersheds is important and helpful to understand the chemical dynamics as well as to design a sampling schedule strategy during storm events. Here, three parameters describing the flush characteristic are quantified and the flush characteristics of chemicals from four Japanese forested watersheds (Mie, Kochi, Nagano and Tokyo) were investigated at both event and seasonal levels. We found that the characteristics of the flush were complicated, and depended on the constituents of the hydrochemistry, climate and runoff quality. Generally, the flush occurs more readily for particulate components than for those in solution; the flush on nitrate‐nitrogen is weaker in regions of nitrogen saturation, such as Nagano and Tokyo, than in Mie and Kochi. Rainfall feature was the main factor controlling the flush of particulate components. However, the source available in a watershed plays a main role on the flushes of dissolve chemicals. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Reaction of forsterite with hydrogen molecules at high pressure and temperature     

Ayako?ShinozakiEmail author  Hisako?Hirai  Hiroyuki?Kagi  Tadashi?Kondo  Taku?Okada  Daisuke?Nishio-Hamane  Shin-ichi?Machida  Tetsuo?Irifune  Takumi?Kikegawa  Takehiko?Yagi 《Physics and Chemistry of Minerals》2012,39(2):123-129

High pressure and temperature reactions of a mixture of forsterite and hydrogen molecules have been carried out using a laser heated diamond anvil cell at 9.8–13.2 GPa and ~1,000 K. In situ X-ray diffraction measurements showed no sign of decomposition or phase transitions of the forsterite under these experimental conditions, indicating that the olivine structure was maintained throughout all runs. However, a substantial expansion of the unit cell volume of the forsterite was observed for samples down to ~3 GPa upon quenching to ambient pressure at room temperature. The Raman spectroscopy measurements under pressure showed significant shifts of the Raman peaks of the Si–O vibration modes for forsterite and of the intramolecular vibration mode for H₂ molecules toward a lower frequency after heating. Additionally, no OH vibration modes were observed by Raman and FT-IR spectroscopic measurements. These lines of evidence show that the observed volume expansion in forsterite is not explained by the incorporation of hydrogen atoms as hydroxyl, but suggest the presence of hydrogen as molecules in the forsterite structure under these high pressure and temperature conditions.  相似文献   

Nutrient and Phytoplankton Dynamics in Harima-Nada, Eastern Seto Inland Sea, Japan During a 35-Year Period from 1973 to 2007     

Tetsuya Nishikawa  Yutaka Hori  Satoshi Nagai  Kazutaka Miyahara  Yukinobu Nakamura  Kazuhiro Harada  Minoru Tanda  Takehiko Manabe  Kuninao Tada 《Estuaries and Coasts》2010,33(2):417-427

Long-term monitoring of water quality and phytoplankton was conducted at 19 sampling stations in Harima-Nada, eastern Seto Inland Sea, Japan for 35 years from 1973 to 2007. There were two significant long-term changes, an increase in winter water temperatures of 0.042°C year^?1, and a decrease in dissolved inorganic nitrogen (DIN) from about 10 μM in the 1970s to ~5 μM in the late 1990s due to the reduction in nutrient inputs. DIN concentrations and total phytoplankton cell density were both higher during the 1970s to the early 1980s and then exhibited a significant decrease in the mid 1980s and remained relatively constant thereafter. Diatoms were the dominant phytoplankton group (>90%) over the 35-year period, and there was a dramatic shift from Skeletonema dominance (~70%) to Chaetoceros in the mid 1980s. This shift in diatom species may be attributed to differences in the life cycle of Skeletonema and Chaetoceros and the response to the decrease in DIN concentration.  相似文献   

Pressure responses of portlandite and H–D isotope effects on pressure-induced phase transitions     

Riko Iizuka  Hiroyuki Kagi  Kazuki Komatsu  Daichi Ushijima  Satoshi Nakano  Asami Sano-Furukawa  Takaya Nagai  Takehiko Yagi 《Physics and Chemistry of Minerals》2011,38(10):777-785

The pressure responses of portlandite and the isotope effect on the phase transition were investigated at room temperature from single-crystal Raman and IR spectra and from powder X-ray diffraction using diamond anvil cells under quasi-hydrostatic conditions in a helium pressure-transmitting medium. Phase transformation and subsequent peak broadening (partial amorphization) observed from the Raman and IR spectra of Ca(OH)₂ occurred at lower pressures than those of Ca(OD)₂. In contrast, no isotope effect was found on the volume and axial compressions observed from powder X-ray diffraction patterns. X-ray diffraction lines attributable to the high-pressure phase remained up to 28.5 GPa, suggesting no total amorphization in a helium pressure medium within the examined pressure region. These results suggest that the H–D isotope effect is engendered in the local environment surrounding H(D) atoms. Moreover, the ratio of sample-to-methanol–ethanol pressure medium (i.e., packing density) in the sample chamber had a significant effect on the increase in the half widths of the diffraction lines, even at pressures below the hydrostatic limit of the pressure medium.  相似文献   

Integrated field spectroscopy of E+A (post-starburst) galaxies with the Kyoto tridimensional spectrograph II     

Tomotsugu Goto  Atsushi Kawai  Atsushi Shimono  Hajime Sugai  Masafumi Yagi  Takashi Hattori 《Monthly notices of the Royal Astronomical Society》2008,386(3):1355-1365

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Horizontal structure of planetary-scale waves at the cloud top of Venus deduced from Galileo SSI images with an improved cloud-tracking technique     

Toru Kouyama  Takeshi Imamura  Masato Nakamura  Takehiko Satoh  Yoshihumi Futaana 《Planetary and Space Science》2012,60(1):207-216

An improved cloud tracking method for deriving wind velocities from successive planetary images was developed. The new method incorporates into the traditional cross-correlation method an algorithm that corrects for erroneous cloud motion vectors by re-determining the most plausible correlation peak among all of the local maxima on the correlation surface by comparing each vector with its neighboring vectors. The newly developed method was applied to the Venusian violet images obtained by the Solid State Imaging system (SSI) onboard the Galileo spacecraft during its Venus flyby. Although the results may be biased by the choice of spatial scale of atmospheric features, the cloud tracking is the most practical mean of estimating the wind velocities with extensive spatial and temporal coverage. The two-dimensional distribution of the horizontal wind vector field over 5 days was obtained. It was found from these wind maps that the solar-fixed component in 1990 was similar to that in 1982 obtained by the Pioneer Venus orbiter. The deviation of the instantaneous zonal wind field from the solar-fixed component shows a distinct wavenumber-1 structure in the equatorial region. On the assumption that this structure is a manifestation of an equatorial Kelvin wave, the phase relationship between the zonal wind and the cloud brightness suggests a short photochemical lifetime of the violet absorber. The momentum deposition by this Kelvin wave, which is subject to radiative damping, would induce a westward mean-wind acceleration of ～0.3 m s^?1 per Earth day.  相似文献   

Reconstruction of historical pressure patterns over Japan using two-point pressure–temperature datasets since the nineteenth century     

Masumi Zaiki  Gunther P. Können  Keiji Kimura  Takehiko Mikami  Togo Tsukahara 《Climatic change》2009,95(1-2):231-248

The temperature and pressure differences between Tokyo and Nagasaki were used to reconstruct past climate conditions. January and July in each available year since the 1820s were classified into several types with characteristic sea level atmospheric pressure patterns. This results in 18 years of pre-1881 data and a continuous series thereafter. The series indicate that the warming after 1900 (after the end of the so-called Little Ice Age) and again after 1960 can at least partly be attributed to an increase in the frequency of warm circulation pattern types at the expense of cold types. The difference in nature of the shifts in circulation types that occurred in the late nineteenth century compared with that in the late twentieth centuries suggests that the mechanism behind the warming in the late nineteenth century differs from that in the late twentieth century.  相似文献   

A modified method for estimating vertical profiles of turbulent dissipation rate using density inversions in the Kuril Straits     

Masahiro Yagi  Ichiro Yasuda 《Journal of Oceanography》2013,69(2):203-214

To address the lack of directly measured turbulence data in the Kuril Straits, an existing method was modified to indirectly estimate continuous vertical profiles of turbulent energy dissipation rate ε by using density inversions. A linear relationship was confirmed between directly measured ε and indirectly estimated ε from the existing method, where most of the detected density inversions were discarded as noise. The existing method thus yielded large gaps in the vertical profiles, and the gaps were much greater than the observed mean autocorrelation vertical length scale of about 10 m. To reduce these gaps and produce reasonable estimates for vertical ε profiles, the quality tests were carefully re-examined with directly measured ε data, and one of the quality tests (the water mass test) was excluded because the test rejects real density inversions even with large ε. With this modification, and interpolation and smoothing of the indirectly estimated ε with the mean correlation length scale, continuous vertical ε profiles were obtained. These profiles have an error factor of 3.3 corresponding to one standard deviation of the ratio between directly observed and estimated data, and 95 % of the data were within a factor of 10.5, with the overall correlation coefficient between smoothed directly measured ε and estimated ε equal to 0.80. This method could be useful for areas where 10^?9 < ε < 10^?6.5 W/kg, and where vertical distances between adjacent density inversions are mostly less than the mean autocorrelation scale.  相似文献   

Measurements of thermospheric temperatures at a mid-latitude station     

T. Yagi  P.L. Dyson 《Planetary and Space Science》1985,33(2):203-206

Fabry-Perot interferometer measurements of the nightglow 630.0 nm line have been made at Beveridge(37°28′S, 145°6′E) from December 1980 to September 1981.Thermospheric temperatures have been derived from these measurements and compared to the MSIS model. Good agreement is found except during summer when the experimental temperatures are consistently higher (～ 100 K) than the model values. The experimental values are well described by a function similar to that used by Hernandez (1982b) to describe 7 years of data obtained at Fritz Peak which is at a similar mid-latitude to Beveridge. The fit to the Beveridge data indicates larger seasonal and magnetic variations in the temperature than given by the MSIS model.  相似文献