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311.
312.
Forbidden reflections of some pyroxenes described as having a lower symmetry than Pbca or C2/c have been examined, mainly using the detailed ψ-scanning method of the four-circle automated diffractometer. All reflections violating the systematic absences of Pbca orthopyroxene, C2/c spodumene, P2/n omphacite and P21/c pigeonite were found to be due to the Umweganregung process of multiple diffraction; the Umweganregung peaks observed for the ψ azimuth were indexed in terms of a four-circle geometry. Thus, the space groups of orthopyroxene, α spodumene, low omphacite and low pigeonite were confirmed to be Pbca, C2/c, P2/n and P21/c, respectively. 相似文献
313.
Yoko?YokouchiEmail author Takuya?Saito Hitoshi?Mukai 《Journal of Atmospheric Chemistry》2018,75(2):171-180
Dibromomethane (CH2Br2), a natural stratospheric ozone depleting substance, is mostly emitted from the ocean, but the relative importance of coastal (or macroalgae) and open ocean emissions is unknown. We made long-term high-frequency measurements of CH2Br2 concentrations at two remote coastal sites in Japan, on the subtropical Hateruma Island (poor in macroalgae) and at Cape Ochiishi (rich in macroalgae). CH2Br2 concentrations at Hateruma showed prominent seasonal variation, being lower in summer (around 0.94 ppt) than in winter (around 1.23 ppt). In contrast, CH2Br2 concentrations at Ochiishi were highly variable, often exceeding 2 ppt in the summer but with minimum baseline concentrations close to those from Hateruma; in the winter the concentrations were almost constant at about 1.3 ppt. Analysis of the data suggested that (1) emissions from macroalgae were not likely to extend offshore, but instead were localized near the shore, (2) strong macroalgal emissions of CH2Br2 were almost limited to the summer, but it was not reflected in the seasonality of the baseline concentrations of CH2Br2 in the atmosphere, and therefore (3) macroalgal or coastal emissions of CH2Br2 in the temperate zone might have a rather limited contribution to the global CH2Br2 sources. These findings are especially important for the understanding of the tropospheric and stratospheric bromine budget. 相似文献
314.
Hitoshi Tomaru Ryo Matsumoto Richard B. Coffin John W. Pohlman George D. Spence 《Journal of Geochemical Exploration》2007,95(1-3):40
The isotopic composition (δD and δ18O) and chloride concentration (Cl−) of pore waters from the northern Cascadia continental margin offshore Vancouver Island were measured to characterize the relations between the water flow regime and the distribution, formation and dissociation of gas hydrates. The δD values of pore waters in gas hydrate-bearing sediments are slightly higher ( 1‰) than those of seawater as the result of gas hydrate dissociation during core recovery and handling. Within the seismic blanking zone, the δD values were slightly lower (− 1‰) than values measured from sites outside the blanking area (0‰). We attribute these differences to 1) distillation of D-rich water during hydrate formation in the center of the blanking zone and 2) limited migration of pore water between inside and outside of the blanking zone due to different fluid fluxes. In contrast, the δ18O values and Cl− concentrations do not show significant spatial variation due to decreased isotopic fractionation of oxygen and small fraction of chloride relative to hydrogen isotope during gas hydrate formation. The δD value of pore water, therefore, appears to be a sensitive indicator of gas hydrate occurrence. We estimate that gas hydrate occupied at least 2.0 to 6.3% of sediment pore space using δD distribution in this area. 相似文献
315.
Yu. V. Barkin H. Hanada K. Matsumoto S. Sasaki M. Yu. Barkin 《Solar System Research》2014,48(6):403-419
An analytical theory of lunar physical librations based on its two-layer model consisting of a non-spherical solid mantle and ellipsoidal liquid core is developed. The Moon moves on a high-precision orbit in the gravitational field of the Earth and other celestial bodies. The defined fourth mode of a free libration is caused by the influence of the liquid core, with a long period of 205.7 yr, with amplitude S = 0″0395 and with an initial phase Π0 = ?134° (for the initial epoch 2000.0). Estimates of dynamic (meridional) oblatenesses of a liquid core of the Moon have been estimated: ?D = 4.42 × 10?4, μD = 2.83 × 10?4 (?D + μD = 7.24 × 10?4). These results have been obtained as a result of comparison of the developed analytical theory of physical librations of the Moon with the empirical theory of librations of the Moon constructed on the basis of laser observations. 相似文献
316.
Takaaki Noguchi Makoto Kimura Takahito Hashimoto Mitsuru Konno Tomoki Nakamura Michael E. Zolensky Ryuji Okazaki Masahiko Tanaka Akira Tsuchiyama Aiko Nakato Toshinori Ogami Hatsumi Ishida Ryosuke Sagae Shinichi Tsujimoto Toru Matsumoto Junya Matsuno Akio Fujimura Masanao Abe Toru Yada Toshifumi Mukai Munetaka Ueno Tatsuaki Okada Kei Shirai Yukihiro Ishibashi 《Meteoritics & planetary science》2014,49(2):188-214
On the basis of observations using Cs‐corrected STEM, we identified three types of surface modification probably formed by space weathering on the surfaces of Itokawa particles. They are (1) redeposition rims (2–3 nm), (2) composite rims (30–60 nm), and (3) composite vesicular rims (60–80 nm). These rims are characterized by a combination of three zones. Zone I occupies the outermost part of the surface modification, which contains elements that are not included in the unchanged substrate minerals, suggesting that this zone is composed of sputter deposits and/or impact vapor deposits originating from the surrounding minerals. Redeposition rims are composed only of Zone I and directly attaches to the unchanged minerals (Zone III). Zone I of composite and composite vesicular rims often contains nanophase (Fe,Mg)S. The composite rims and the composite vesicular rims have a two‐layered structure: a combination of Zone I and Zone II, below which Zone III exists. Zone II is the partially amorphized zone. Zone II of ferromagnesian silicates contains abundant nanophase Fe. Radiation‐induced segregation and in situ reduction are the most plausible mechanisms to form nanophase Fe in Zone II. Their lattice fringes indicate that they contain metallic iron, which probably causes the reddening of the reflectance spectra of Itokawa. Zone II of the composite vesicular rims contains vesicles. The vesicles in Zone II were probably formed by segregation of solar wind He implanted in this zone. The textures strongly suggest that solar wind irradiation damage and implantation are the major causes of surface modification and space weathering on Itokawa. 相似文献
317.
Makio C. Honda Masahide Wakita Kazuhiko Matsumoto Tetsuichi Fujiki Eko Siswanto Kosei Sasaoka Hajime Kawakami Yoshihisa Mino Chiho Sukigara Minoru Kitamura Yoshikazu Sasai Sherwood L. Smith Taketo Hashioka Chisato Yoshikawa Katsunori Kimoto Shuichi Watanabe Toru Kobari Toshi Nagata Koji Hamasaki Ryo Kaneko Mario Uchimiya Hideki Fukuda Osamu Abe Toshiro Saino 《Journal of Oceanography》2017,73(5):647-667
A comparative study of ecosystems and biogeochemistry at time-series stations in the subarctic gyre (K2) and subtropical region (S1) of the western North Pacific Ocean (K2S1 project) was conducted between 2010 and 2013 to collect essential data about the ecosystem and biological pump in each area and to provide a baseline of information for predicting changes in biologically mediated material cycles in the future. From seasonal chemical and biological observations, general oceanographic settings were verified and annual carbon budgets at both stations were determined. Annual mean of phytoplankton biomass and primary productivity at the oligotrophic station S1 were comparable to that at the eutrophic station K2. Based on chemical/physical observations and numerical simulations, the likely “missing nutrient source” was suggested to include regeneration, meso-scale eddy driven upwelling, meteorological events, and eolian inputs in addition to winter vertical mixing. Time-series observation of carbonate chemistry revealed that ocean acidification (OA) was ongoing at both stations, and that the rate of OA was faster at S1 than at K2 although OA at K2 is more critical for calcifying organisms. 相似文献
318.
319.
Hajime Kawakami Makio C. Honda Kazuhiko Matsumoto Tetsuichi Fujiki Shuichi Watanabe 《Journal of Oceanography》2010,66(1):71-83
Observations of primary productivity, 234Th, and particulate organic carbon (POC) were made from west to east across the northern North Pacific Ocean (from station
K2 to Ocean Station Papa) during September–October 2005. Primary productivities in this region varied longitudinally from
approximately 236 to 444 mgC m−2d−1 and clearly indicate the West High East Low (WHEL) trend. We estimated east-west variations in the POC flux from the surface
layer (0–100 m) by using 234Th as a tracer. POC fluxes in the western region (44–53 mgC m−2d−1) were higher than those in the eastern region (21–34 mgC m−2d−1). However, the export ratios (e-ratios) ranged from approximately 8% to 16% and did not show the WHEL trend. Contrary to our expectation, no relation between
POC flux (or e-ratio) and diatom biomass (or dominance) was apparent in autumn in the northern North Pacific. 相似文献
320.