Arsenic Speciation in a Contaminated Gold Processing Tailings Dam   总被引：1，自引：0，他引：1  

Olga V. Shuvaeva  Svetlana B. Bortnikova  Tamara M. Korda  Elena V. Lazareva 《Geostandards and Geoanalytical Research》2000,24(2):247-252

Gold recovery in ores containing arsenopyrite releases significant amounts of arsenic into the environment due to mineral processing and oxidation during storage. The extent of arsenic weathering in a tailings dam has been investigated. Speciation of As in surface and pore waters and pond sediments showed that for gold tailings in the dam, As enrichment took place in the pore water relative to the surface water. In pond sediments As was predominantly present as residual arsenopyrite and partly as a substance co-precipitated with iron hydroxide. The arsenic release from the sediment results from a reductive dissolution of the arsenopyrite and Fe oxides. In the surface water, arsenate and arsenite are the main arsenic species (arsenate is dominant), but in the pore waters methylation processes play a significant role. Arsenic transport is accompanied by the transformation of As into the less toxic compounds (methylated species) co-existing with the most toxic species (arsenite).  相似文献   

Microphytobenthic primary production as C uptake in sublittoral sediments of the Gulf of Trieste (northern Adriatic Sea): Methodological aspects and data analyses     

Tamara Cibic  Oriana Blasutto  Nicoletta Burba  Serena Fonda Umani 《Estuarine, Coastal and Shelf Science》2008

From January 2003 to December 2004 microphytobenthic primary production was estimated both from in situ (MPPs) and in the laboratory (MPPp) ¹⁴C-incubation of slurries collected in a coastal site of the Gulf of Trieste (northern Adriatic Sea). MPPs values varied from −7.54 ± 3.12 to 34.59 ± 7.66 mg C m⁻² h⁻¹ over the whole period. The lowest MPPs were observed in November 2003 and August 2004, while the highest MPPs in July 2003 and May 2004, in correspondence with high PAR at the bottom. Significant correlations between MPPs and the microphytobenthic biomass (BIOM) (r = 0.75, p < 0.001), between MPPs and PAR at the bottom (r = 0.54, p < 0.01) and between MPPs and OXY (r = 0.50, p < 0.05) were revealed. MPPp values were higher than MPPs ones in 15 out of 23 observations, with the highest MPPp recorded in July 2003. At 17 m depth a seasonal pattern of sampling months was revealed by the cluster analysis. The role of abiotic parameters in determining this seasonal pattern was highlighted by the PCA, with the first axis correlated with MPPs and PAR, and the second one with temperature. Applying the fuzzy sets it resulted that spring months showed a higher degree of membership with MPPs, summer months with temperature and autumn–winter months with OXY. The microphytobenthic community did not seem to be photosynthetically active throughout the study period. From August–September to December low or negative MPPs values were recorded. We infer that during these months a shift from the autotrophic to heterotrophic metabolism of the benthic microalgae occurred in correspondence with low PAR and/or high temperature at the bottom. Despite the progressive lowering of the trophy of the study area occurred during the last 20 years, we found higher primary production values than those estimated two decades earlier.  相似文献   

Vertical Profiles of Major Organic Geochemical Constituents and Extracellular Enzymatic Activities in Sandy Sediments of Aransas and Copano Bays, TX     

Afonso C. Souza  Tamara K. Pease  Wayne S. Gardner 《Estuaries and Coasts》2012,35(1):308-323

Vertical distribution patterns of organic geochemical constituents and the enzymes aminopeptidase and β-glucosidase provide insights about the nature and reactivity of sediment organic matter in the sandy sediments of two shallow “South Texas” estuaries. Sediment total organic carbon (TOC) δ¹³C values indicated that the organic matter (OM) was derived more from a mixture of seagrass and phytoplankton than from terrigenous OM. Down-core amounts of TOC and total nitrogen (TN) were <0.2% of dry weight, respectively. Enzyme activities were highest near surface and ranged from 25 to 1 μM/h for aminopeptidase as compared to 5 to 0.2 μM/h for glucosidase. In Aransas Bay, aminopeptidase activity correlated with sediment TN content (r _s = 0.30) and β-glucosidase with TOC content (r _s = 0.27). In Copano Bay, aminopeptidase correlated with TOC, TN, and carbohydrate content (r _s = 0.89, 0.90, and 0.83, respectively). Variations of glucosidase activity also related positively to TOC, TN, and total carbohydrate content (r _s = 0.68, 0.77, and 0.48, respectively). Overall, enzyme activities in these low OM, sandy sediments resembled those for other benthic marine environments.  相似文献   

Erratum to: Vertical Profiles of Major Organic Geochemical Constituents and Extracellular Enzymatic Activities in Sandy Sediments of Aransas and Copano Bays, TX     

Afonso C. Souza  Tamara K. Pease  Wayne S. Gardner 《Estuaries and Coasts》2012,35(1):324

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Five-coordinate Cd in the crystal structure of triploidite-type Cd2(AsO4)(OH)     

Tamara Ðorđević  Uwe Kolitsch 《Mineralogy and Petrology》2013,107(2):243-251

This paper reports on hydrothermal synthesis and crystal structure refinement of dicadmium arsenate hydroxide, Cd₂(AsO₄)(OH), obtained at 220 °C and autogenous pressure. Its crystal structure is monoclinic, space group P2₁/a, with a = 13.097(3), b = 14.089(3), c = 10.566(2) Å, β = 108.38(3)°, V = 1850.2(6) ų (Z = 16). It is isotypic with the members of the triploidite group of minerals and synthetic compounds, and thus shows a close topological relationship with the triplite group. The complex framework contains edge- and corner-sharing CdO₄(OH) and CdO₄(OH)₂ polyhedra, linked via corner-sharing to AsO₄ tetrahedra (average As—O distances range between 1.682 and 1.688 Å). Four five-coordinated Cd sites are at the centers of distorted trigonal bipyramids (average Cd—O distances are between 2.225 and 2.251 Å), whereas the remaining four Cd sites have a distorted octahedral coordination environment (average Cd—O distances are between 2.297 and 2.320 Å). The positions of all the hydrogen atoms were located in a difference-Fourier map and refined with an isotropic displacement parameter. The hydrogen-bonds are weak to very weak. The unusual five-coordination of Cd is briefly discussed in relation to comparable minerals and compounds. Among triploidite-type compounds, Cd₂(AsO₄)(OH) is the member with the largest unit cell reported so far, and the second known arsenate member.  相似文献   

Potential of the LASH model for water resources management in data-scarce basins: a case study of the Fragata River basin,southern Brazil     

Samuel Beskow  Luis Carlos Timm  Vitor Emanuel Quevedo Tavares  Tamara Leitzke Caldeira  Leandro Sanzi Aquino 《水文科学杂志》2013,58(14):2567-2578

ABSTRACT

The objective of this study was to evaluate, based on a data-scarce basin in southern Brazil, the potential of the Lavras Simulation of Hydrology (LASH) model for estimating daily streamflows, annual streamflow indicators and the flow–duration curve. It was also used to simulate the different runoff components and their consistency with the basin physiographical characteristics. The statistical measures indicated that LASH can be considered suitable according to widely used classifications and when compared with other studies involving hydrological models. LASH also showed satisfactory results for annual indicators, especially for maximum and average annual streamflows, as well as for the flow–duration curve. It was found that the model was consistent with the basin characteristics when simulating runoff components. The results obtained in this study allowed us to conclude that the LASH model has the potential to aid practitioners in water resources management of basins with scarce data and similar soil and land-use conditions.