Preferential dissolution of SiO<Subscript>2</Subscript> from enstatite to H<Subscript>2</Subscript> fluid under high pressure and temperature     

Ayako Shinozaki  Hiroyuki Kagi  Hisako Hirai  Hiroaki Ohfuji  Taku Okada  Satoshi Nakano  Takehiko Yagi 《Physics and Chemistry of Minerals》2016,43(4):277-285

Stability and phase relations of coexisting enstatite and H₂ fluid were investigated in the pressure and temperature regions of 3.1–13.9 GPa and 1500–2000 K using laser-heated diamond-anvil cells. XRD measurements showed decomposition of enstatite upon heating to form forsterite, periclase, and coesite/stishovite. In the recovered samples, SiO₂ grains were found at the margin of the heating hot spot, suggesting that the SiO₂ component dissolved in the H₂ fluid during heating, then precipitated when its solubility decreased with decreasing temperature. Raman and infrared spectra of the coexisting fluid phase revealed that SiH₄ and H₂O molecules formed through the reaction between dissolved SiO₂ and H₂. In contrast, forsterite and periclase crystals were found within the hot spot, which were assumed to have replaced the initial orthoenstatite crystals without dissolution. Preferential dissolution of SiO₂ components of enstatite in H₂ fluid, as well as that observed in the forsterite H₂ system and the quartz H₂ system, implies that H₂-rich fluid enhances Mg/Si fractionation between the fluid and solid phases of mantle minerals.  相似文献   

Effects of the introduction of rice on evapotranspiration in seasonal wetlands          下载免费PDF全文

Tetsuji Suzuki  Takeshi Ohta  Tetsuya Hiyama  Yasuhiro Izumi  Osmund Mwandemele  Morio Iijima 《水文研究》2014,28(17):4780-4794

Land use changes in wetland areas can alter evapotranspiration, a major component of the water balance, which eventually affects the water cycle and ecosystem. This study assessed the effect of introduced rice‐cropping on evapotranspiration in seasonal wetlands of northern Namibia. By using the Bowen ratio–energy balance method, measurements of evapotranspiration were performed over a period of 2.5 years at two wetland sites—a rice field (RF) and a natural vegetation field (NVF)—and at one upland field (UF) devoid of surface water. The mean evapotranspiration rates of RF (1.9 mm daytime^?1) and NVF (1.8 mm daytime^?1) were greater than that in UF (1.0 mm daytime^?1). RF and NVF showed a slight difference in seasonal variations in evapotranspiration rates. During the dry season, RF evapotranspiration was less than the NVF evapotranspiration. The net radiation in RF was less in this period because of the higher albedo of the non‐vegetated surface after rice harvesting. In the early growth period of rice during the wet season, evapotranspiration in RF was higher than that in NVF, which was attributed to a difference in the evaporation efficiency and the transfer coefficient for latent heat that were both affected by leaf area index (LAI). Evapotranspiration sharply negatively responded to an increase in LAI when surface water is present according to sensitivity analysis, probably because a higher LAI over a surface suppresses evaporation. The control of LAI is therefore a key for reducing evaporation and conserving water. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Reaction of forsterite with hydrogen molecules at high pressure and temperature     

Ayako?ShinozakiEmail author  Hisako?Hirai  Hiroyuki?Kagi  Tadashi?Kondo  Taku?Okada  Daisuke?Nishio-Hamane  Shin-ichi?Machida  Tetsuo?Irifune  Takumi?Kikegawa  Takehiko?Yagi 《Physics and Chemistry of Minerals》2012,39(2):123-129

High pressure and temperature reactions of a mixture of forsterite and hydrogen molecules have been carried out using a laser heated diamond anvil cell at 9.8–13.2 GPa and ~1,000 K. In situ X-ray diffraction measurements showed no sign of decomposition or phase transitions of the forsterite under these experimental conditions, indicating that the olivine structure was maintained throughout all runs. However, a substantial expansion of the unit cell volume of the forsterite was observed for samples down to ~3 GPa upon quenching to ambient pressure at room temperature. The Raman spectroscopy measurements under pressure showed significant shifts of the Raman peaks of the Si–O vibration modes for forsterite and of the intramolecular vibration mode for H₂ molecules toward a lower frequency after heating. Additionally, no OH vibration modes were observed by Raman and FT-IR spectroscopic measurements. These lines of evidence show that the observed volume expansion in forsterite is not explained by the incorporation of hydrogen atoms as hydroxyl, but suggest the presence of hydrogen as molecules in the forsterite structure under these high pressure and temperature conditions.  相似文献   

Sylvite and halite on particles recovered from 25143 Itokawa: A preliminary report     

T. Noguchi  M. Kimura  T. Hashimoto  M. Konno  T. Nakamura  M. E. Zolensky  A. Tsuchiyama  T. Matsumoto  J. Matsuno  R. Okazaki  M. Uesugi  Y. Karouji  T. Yada  Y. Ishibashi  K. Shirai  M. Abe  T. Okada 《Meteoritics & planetary science》2014,49(7):1305-1314

We observed cross sectional ultra‐thin sections near the surface of 12 particles recovered from the S‐type asteroid Itokawa by the Hayabusa spacecraft in 2010, using spherical aberration–corrected STEM and conventional TEM. Although their mineralogy is almost identical to the equilibrated LL chondrites and therefore basically anhydrous, micrometer‐to‐submicrometer‐sized sylvite was identified on the surface of Itokawa particle RA‐QD02‐0034. Separately, micrometer‐sized halite was also identified on the surface of Itokawa particle RA‐QD02‐0129. Detailed inspection of the sample processing procedures at the JAXA's Planetary Materials Sample Curation Facility and textural observation of the sylvite and halite indicate that they were clearly present on two Itokawa particles before they were removed from Clean Chamber #2 at JAXA. However, there is no direct evidence for their extraterrestrial origin at present. If the sylvite and halite are extraterrestrial, their presence suggests that they may be more abundant on the surface of S‐type asteroids than previously thought.  相似文献   

Orthopyroxene–cordierite mafic gneiss from the Nomamisaki metamorphic rocks,Southern Kyushu,Japan: Implication for western continuation of the Usuki–Yatsushiro Tectonic Line     

Takeshi Ikeda  Aya Hiramine  Tetsuji Onoue 《Island Arc》2010,19(2):230-242

We describe an orthopyroxene–cordierite mafic gneiss from the Nomamisaki metamorphic rocks in the Noma Peninsula, southern Kyushu, Japan. The mineral assemblage of the gneiss is orthopyroxene, cordierite, biotite, plagioclase, and ilmenite. Thermometry based on the Fe–Mg exchange reaction between orthopyroxene and biotite yields a peak metamorphic temperature of 680°C. The stability of cordierite relative to garnet, quartz, and sillimanite defines the upper limit of the peak metamorphic pressure as 4.4 kbar. These features indicate that the Nomamisaki metamorphic rocks underwent low‐pressure high‐temperature type metamorphism. Although a chronological problem still remains, the Nomamisaki metamorphic rocks can be regarded as a western continuation of the Higo Belt. The Usuki–Yatsushiro Tectonic Line, which delineates the southern border of the Higo Belt, is therefore located on the east of the Nomamisaki metamorphic rocks in southern Kyushu.  相似文献   

Inaugural Address 25:1          下载免费PDF全文

Tetsuji Muto  Yoshihiko Tamura 《Island Arc》2016,25(1):3-3

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The scientific rationale for the C1XS X-ray spectrometer on India's Chandrayaan-1 mission to the moon   总被引：1，自引：0，他引：1  

I.A. Crawford  K.H. Joy  B.J. Kellett  M. Anand  N. Bhandari  L. d’Uston  O. Gasnault  C.J. Howe  D. Koschny  B.J. Maddison  S. Narendranath  T. Okada  S.S. Russell  B. Swinyard  M. Wilding 《Planetary and Space Science》2009,57(7):725-734

The UK-built Chandrayaan-1 X-ray Spectrometer (C1XS) will fly as an ESA instrument on India's Chandrayaan-1 mission to the Moon, launched in October 2008. C1XS builds on experience gained with the earlier D-CIXS instrument on SMART-1, but will be a scientifically much more capable instrument. Here we describe the scientific objectives of this instrument, which include mapping the abundances of the major rock-forming elements (principally Mg, Al, Si, Ti, Ca and Fe) in the lunar crust. These data will aid in determining whether regional compositional differences (e.g., the Mg/Fe ratio) are consistent with models of lunar crustal evolution. C1XS data will also permit geochemical studies of smaller scale features, such as the ejecta blankets and central peaks of large impact craters, and individual lava flows and pyroclastic deposits. These objectives all bear on important, and currently unresolved, questions in lunar science, including the structure and evolution of any primordial magma ocean, as revealed by vertical and lateral geochemical variations in the crust, and the composition of the lunar mantle, which will further constrain theories of the Moon's origin, thermal history and internal structure.  相似文献   

What constitutes successful participatory disaster risk management? Insights from post-earthquake reconstruction work in rural Gujarat,India     

Subhajyoti Samaddar  Norio Okada  Junho Choi  Hirokazu Tatano 《Natural Hazards》2017,85(1):111-138

Although for decades, public participation in disaster risk management has been strongly advocated for, in reality, it remains elusive. Planners and practitioners are still struggling to find ways to meaningfully involve the local community in disaster management programs; so far, apparently successful projects and initiatives have seldom been scaled up or replicated. The reason for this is that no comprehensive framework for participatory disaster risk management exists, and no systematic evaluation has been made to assess the necessary elements and appropriate paths for meaningful public participation in disaster management. This study attempts to examine the process and identify outcome-based factors that account for successful participatory disaster risk management. To accomplish this, we have evaluated reconstruction projects in earthquake-affected rural Gujarat, India, where the government envisioned a people-centric reconstruction project, but provided no public participation framework or guidelines. As a result, several reconstruction models pursuing different levels and types of public participation ultimately emerged. We selected three dominant reconstruction approaches and examined the extent to which various processes and outcome-based factors were successful in promoting ideal levels of public participation during these reconstruction projects. This study is considered an example of pioneering research in defining factors that account for successful participatory disaster risk management.  相似文献   

Impacts of climate change on growth, migration and recruitment success of Japanese sardine (Sardinops melanostictus) in the western North Pacific     

Takeshi Okunishi  Shin-ichi Ito  Taketo Hashioka  Takashi T. Sakamoto  Naoki Yoshie  Hiroshi Sumata  Yumiko Yara  Naosuke Okada  Yasuhiro Yamanaka 《Climatic change》2012,115(3-4):485-503

We developed a multi-trophic level ecosystem model by coupling physical, biogeochemical-plankton and fish models. An oceanic general circulation model was coupled with a lower trophic level ecosystem model and a Japanese sardine migration model, and applied to the western North Pacific. To investigate the impact of global warming on the pelagic fish ecosystem, such as Japanese sardine, we conducted numerical experiments of growth and migration of Japanese sardine using physical fields for the present day and future with a global warming scenario simulated by a high-resolution climate model. The model results demonstrated possible impacts of global warming on the growth and migration pattern of Japanese sardine. The growths of fish in the current main spawning region under the global warming scenario were significantly slower than those under the present climate scenario. Fish in this region will be at disadvantage for their recruitment under the global warming condition. Prey conditions in the spawning region were projected not to markedly change under global warming condition while water temperature increased. As a result sardine spawning ground was projected to shift towards more north areas. During the feeding migration period in summer, geographical distribution of juveniles fish was projected to shift northwards by one to two degrees latitude under the global warming condition following the change in the distribution of optimal temperature region for feeding. However, this northwards shift of the optimal temperature for feeding was minimized adjacent to the western North Pacific by the cooler water supply by the intensification of the Oyashio.  相似文献   

Tomographic imaging of hydrated crust and mantle in the subducting Pacific slab beneath Hokkaido, Japan: Evidence for dehydration embrittlement as a cause of intraslab earthquakes   总被引：4，自引：3，他引：1  

Junichi Nakajima  Yusuke Tsuji  Akira Hasegawa  Saeko Kita  Tomomi Okada  Toru Matsuzawa 《Gondwana Research》2009,16(3-4):470-481

We estimate detailed three-dimensional seismic velocity structures in the subducting Pacific slab beneath Hokkaido, Japan, using a large number of arrival-time data from 6902 local earthquakes. A remarkable low-velocity layer with a thickness of ~ 10 km is imaged at the uppermost part of the slab and is interpreted as hydrated oceanic crust. The layer gradually disappears at depths of 70–80 km, suggesting the breakdown of hydrous minerals there. We find prominent low-velocity anomalies along the lower plane of the double seismic zone and above the aftershock area of the 1993 Kushiro-oki earthquake (M7.8). Since seismic velocities of unmetamorphosed peridotite are much higher than the observations, hydrous minerals are expected to exist in the lower plane as well as the hypocentral area of the 1993 earthquake. On the other hand, regions between the upper and lower planes, where seismic activity is not so high compared to the both planes, show relatively high velocities comparable to those of unmetamorphosed peridotite. Our observations suggest that intermediate-depth earthquakes occur mainly in regions with hydrous minerals, which support dehydration embrittlement hypothesis as a cause of earthquake in the subducting slab.  相似文献