High-pressure Raman studies and heat capacity measurements on the MgSiO<Subscript>3</Subscript> analogue CaIr<Subscript>0.5</Subscript>Pt<Subscript>0.5</Subscript>O<Subscript>3</Subscript>     

Shigeto Hirai  Yohei Kojima  Hiroaki Ohfuji  Norimasa Nishiyama  Tetsuo Irifune  Stephan Klemme  Geoffrey Bromiley  J. Paul Attfield 《Physics and Chemistry of Minerals》2011,38(8):631-637

Raman spectroscopy and heat capacity measurements have been used to study the post-perovskite phase of CaIr_0.5Pt_0.5O₃, recovered from synthesis at a pressure of 15 GPa. Laser heating CaIr_0.5Pt_0.5O₃ to 1,900 K at 60 GPa produces a new perovskite phase which is not recoverable and reverts to the post-perovskite polymorph between 20 and 9 GPa on decompression. This implies that Pt-rich CaIr_1−xPt_xO₃ perovskites including the end member CaPtO₃ cannot easily be recovered to ambient pressure from high P–T synthesis. We estimate an increase in the thermodynamic Grüneisen parameter across the post-perovskite to perovskite transition of 34%, of similar magnitude to those for (Mg,Fe)SiO₃ and MgGeO₃, suggesting that CaIr_0.5Pt_0.5O₃ is a promising analogue for experimental studies of the competition in energetics between perovskite and post-perovskite phases of magnesium silicates in Earth’s lowermost mantle. Low-temperature heat capacity measurements show that CaIrO₃ has a significant Sommerfeld coefficient of 11.7 mJ/mol K² and an entropy change of only 1.1% of Rln2 at the 108 K Curie transition, consistent with the near-itinerant electron magnetism. Heat capacity results for post-perovskite CaIr_0.5Rh_0.5O₃ are also reported.  相似文献   

Heterogeneous condensation of presolar titanium carbide core‐graphite mantle spherules     

Takeshi Chigai  Tetsuo Yamamoto  Takashi Kozasa 《Meteoritics & planetary science》2002,37(12):1937-1951

Abstract— We investigate heterogeneous nucleation and growth of graphite on precondensed TiC grains in the gas outflows from carbon‐rich asymptotic giant branch (AGB) stars employing a newly‐derived heterogeneous nucleation rate taking into account of the chemical reactions at condensation. Competition between heterogeneous and homogeneous nucleations and growths of graphite is investigated to reveal the formation conditions of the TiC core‐graphite mantle spherules found in the Murchison meteorite. It is shown that no homogeneous graphite grain condenses whenever TiC condenses prior to graphite in the plausible ranges of the stellar parameters. Heterogeneous condensation of graphite occurs on the surfaces of growing TiC grains, and prevents the TiC cores from reaching the sizes realized if all available Ti atoms were incorporated into TiC grains. The physical conditions at the formation sites of the TiC core‐graphite mantle spherules observed in the Murchison meteorite are expressed by the relation 0.2 < n?_0.1 (M₅/ζ)^?1/2L₄^1/4 < 0.7, where v_0.1 is the gas outflow velocity at the formation site in units of 0.1 km s^?1, M₅ the mass loss rate in 10^?5 M⊙ year^?1, L₄ the stellar luminosity in 10⁴ L⊙, and M/ζ is the effective mass loss rate taking account of non‐spherical symmetry of the gas outflows. The total gas pressures P_c at the formation sites for the effective mass loss rates M/ζ = 10^?5‐10^?3 M⊙ year^?1 correspond to 0.01 < P_c < 0.9 dyn cm^?2, implying that the observed TiC core‐graphite mantle spherules are formed not only at the superwind stage but also at the earlier stage of low mass loss rates. The constraint on the C/O abundance ratio, 1 < ? ? 1.03, is imposed to reproduce the observed sizes of the TiC cores. The derived upper limit of the C/O ratio is lower than the values estimated from the calculations without taking into account of heterogeneous condensation of graphite, and is close to the lower end of the C/O ratios inferred from the astronomical observations of carbon‐rich AGB stars. Brief discussion is given on other types of graphite spherules.  相似文献   

Induced fabric under cyclic and rotational loads in a strain space multiple mechanism model for granular materials     

Susumu Iai  Tetsuo Tobita  Osamu Ozutsumi 《国际地质力学数值与分析法杂志》2013,37(2):150-180

The strain space multiple mechanism model idealizes the behavior of granular materials on the basis of a multitude of virtual simple shear mechanisms oriented in arbitrary directions. Within this modeling framework, the virtual simple shear stress is defined as a quantity dependent on the contact distribution function as well as the normal and tangential components of interparticle contact forces, which evolve independently during the loading process. In other terms, the virtual simple shear stress is an intermediate quantity in the upscaling process from the microscopic level (characterized by contact distribution and interparticle contact forces) to the macroscopic stress. The stress space fabric produces macroscopic stress through the tensorial average. Thus, the stress space fabric characterizes the fundamental and higher modes of anisotropy induced in granular materials. Herein, the induced fabric is associated with monotonic and cyclic loadings, loading with the rotation of the principal stress, and general loading. Upon loading with the rotation of the principal stress axis, some of the virtual simple shear mechanisms undergo loading whereas others undergo unloading. This process of fabric evolution is the primary cause of noncoaxiality between the axes of principal stresses and strains. Although cyclic behavior and behavior under the rotation of the principal stress axis seem to originate from two distinct mechanisms, the strain space multiple mechanism model demonstrates that these behaviors are closely related through the hysteretic damping factor. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Seasonal changes in runoff characteristics on a permafrost watershed in the southern mountainous region of eastern Siberia     

Yusuke Yamazaki  Jumpei Kubota  Tetsuo Ohata  Varely Vuglinsky  Takahisa Mizuyama 《水文研究》2006,20(3):453-467

We attempted to clarify the runoff characteristics of a permafrost watershed in the southern mountainous region of eastern Siberia using hydrological and meteorological data obtained by the State Hydrological Institute in Russia from 1976 to 1985. We analysed seasonal changes in the direct runoff ratio and recession gradient during the permafrost thawing period. Thawing depth began to increase from the beginning of May and continued to increase until the end of September, exceeding 150 cm. Annual precipitation and discharge were in the range 525–649 mm and 205–391 mm respectively. The sum of the annual evapotranspiration and changes in water storage ranged from 235 to 365 mm. The mean daily evapotranspiration in June, July, August and September was 1·5 mm day^?1, 1·7 mm day^?1, 1·5 mm day^?1, and 0·5 mm day^?1 respectively. The direct runoff ratio was highest in June, decreasing from 0·8 in June to 0·2 in September. The recession gradient also decreased from June to September. Since the frozen soil functioned as an impermeable layer, the soil water storage capacity in the thawing part of the soil, the depth of which changed over time, controlled the runoff characteristics. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Raman spectroscopic study of hydroxyl-clinohumite at various pressures and temperatures     

C.-C. Lin  L.-G. Liu  T. P. Mernagh  T. Irifune 《Physics and Chemistry of Minerals》2000,27(5):320-331

 Variations of Raman spectra of hydroxyl-clinohumite were studied up to ∼370 kbar at room temperature, and in the range 81–873 K at atmospheric pressure. With the exception of the symmetric OH-stretch bands, the Raman frequencies of all bands were observed to increase monotonically with increasing pressure, and decrease with increasing temperature. This behavior is in line with those observed for other humite members (norbergite and chondrodite) so far studied. The symmetric OH-stretching band shows a mode softening with increasing pressure, and splits into two bands at either high pressure or low temperature. In the quasihydrostatic experiment, the compression and decompression paths of one of the asymmetric OH-stretch bands form a hysteresis loop, but the same behavior was not observed in the nonhydrostatic experiment. These results indicate that the two kinds of OH groups in hydroxyl-clinohumite have nonequivalent movement paths on compression, and with one OH group experiencing a release of spatial hindrance during compression. This behavior appears to be modified by shear stress. The same complication of the OH groups was not observed in the temperature variation study. The pressure and temperature variations of the Raman frequencies for the various vibrations involving the SiO₄ tetrahedra and MgO₆ octahedra below ∼1000 cm⁻¹ for clinohumite behave similarly to other hydrous magnesium silicates. On the basis of the relationship between isothermal bulk modulus and Raman data, it is suggested that the linear pressure dependences of vibrational frequencies of various Raman bands reported in the literature are inadequate. Received: 20 March 1999 / Revised, accepted: 24 August 1999  相似文献   

A model for the infrared brightening of a Nova shell     

Tetsuo Yamamoto  Junji Seki 《Astrophysics and Space Science》1979,64(1):153-164

A model for grain formation in an expanding Nova shell is presented. It is shown that individual grains complete the growth within a very short time interval. In consequence the infrared brightening accompanied with visual darkening observed in several Novae is interpreted in terms of extension of dusty region in the ejected gas shell. Developments of infrared luminosity and visual magnitude are computed on the basis of a model, and compared with the observations of Nova Vul 1976, Nova Ser 1970, and Nova Aql 1975. The constancy and uniformity of grain temperatures for a long period after the infrared maximum observed in Nova Vul 1976 are also discussed.  相似文献   

Behavior of zircon in the upper-amphibolite to granulite facies schist/migmatite transition, Ryoke metamorphic belt, SW Japan: constraints from the melt inclusions in zircon     

Tetsuo Kawakami  Isao Yamaguchi  Akira Miyake  Tomoyuki Shibata  Kenshi Maki  Takaomi D. Yokoyama  Takafumi Hirata 《Contributions to Mineralogy and Petrology》2013,165(3):575-591

Behavior of zircon at the schist/migmatite transition is investigated. Syn-metamorphic overgrowth is rare in zircon in schists, whereas zircon in migmatites has rims with low Th/U that give 90.3 ± 2.2 Ma U–Pb concordia age. Between inherited core and the metamorphic rim, a thin, dark-CL annulus containing melt inclusion is commonly developed, suggesting that it formed contemporaneous with the rim in the presence of melt. In diatexites, the annulus is further truncated by the brighter-CL overgrowth, suggesting the resorption and regrowth of the zircon after near-peak metamorphism. Part of the zircon rim crystallized during the solidification of the melt in migmatites. Preservation of angular-shaped inherited core of 5–10 μm in zircon included in garnet suggests that zircon of this size did not experience resorption but developed overgrowths during near-peak metamorphism. The Ostwald ripening process consuming zircon less than 5–10 μm is required to form new overgrowths. Curved crystal size distribution pattern for fine-grained zircons in a diatexite sample may indicate the contribution of this process. Zircon less than 20 μm is confirmed to be an important sink of Zr in metatexites, and ca. 35-μm zircon without detrital core are common in diatexites, supporting new nucleation of zircon in migmatites. In the Ryoke metamorphic belt at the Aoyama area, monazite from migmatites records the prograde growth age of 96.5 ± 1.9 Ma. Using the difference of growth timing of monazite and zircon, the duration of metamorphism higher than the amphibolite facies grade is estimated to be ca. 6 Myr.  相似文献   

The Umov effect for single irregularly shaped particles with sizes comparable with wavelength     

Evgenij Zubko  Gorden Videen  Karri Muinonen  Tetsuo Yamamoto 《Icarus》2011,212(1):403-415

The Umov effect manifests itself as an inverse correlation between the linear polarization maximum of an object’s scattered light P_max and its geometric albedo A. This effect is observed for the Moon, Mercury and Mars, and there are data suggesting this effect is valid for asteroids. The Umov effect is due to the contribution of interparticle multiple scattering that increases albedo and decreases polarization. We here study if the Umov effect can be extended to the case of single irregularly shaped particles with sizes comparable with the wavelength. This, in particular, is important for cometary dust polarimetry. We show the Umov effect being valid for weakly absorbing irregular particles (Im(m) ? 0.02) almost through the entire range of size parameters x considered. Highly absorbing particles (Im(m) > 0.02) follow the Umov effect only if x exceeds 14. In the case of weakly absorbing particles, the inverse correlation is essentially non-linear, which is caused by the contribution of particles with small x. However, averaging over many different types of irregularly shaped particles could make it significantly more linear. The size averaging does not change qualitatively the diagram log(P_max)-log(A) for weakly absorbing particles. For single irregular particles whose sizes are comparable with wavelength, there is no reliable correlation between the slope of the polarization curve h near the inversion phase angle and geometric albedo A. Using the extended Umov Law, we estimate the geometric albedo of dust particles forming cometary circumnuclear haloes A = 0.1 − 0.2, which is a few times larger than the average geometric albedo over the entire comae. Note that, using the obtained values for A of cometary particles, one can derive their number density in circumnuclear haloes from photometric observations.  相似文献   

Impact of land-use changes on snow in a forested region with heavy snowfall in Hokkaido,Japan     

Kazuyoshi Suzuki  Yuji Kodama  Taro Nakai  Glen E. Liston  Kazukiyo Yamamoto  Tetsuo Ohata 《水文科学杂志》2013,58(3):443-467

Abstract

We simulated snow processes in a forested region with heavy snowfall in Japan, and evaluated both the regional-scale snow distribution and the potential impact of land-use changes on the snow cover and water balances over the entire domain. SnowModel reproduced the snow processes at open and forested sites, which were confirmed by snow water equivalent (SWE) measurements at two intensive observation sites and snow depth measurements at the Automated Meteorological Data Acquisition System sites. SnowModel also reproduced the observed snow distribution (from the MODIS snow cover data) over the simulation domain during thaw. The observed SWE was less at the forested site than at the open site. The SnowModel simulations showed that this difference was caused mainly by differences in sublimation. The type of land use changed the maximum SWE, onset and duration of snowmelt, and the daily snowmelt rate due to canopy snow interception.

Citation Suzuki, K., Kodama, Y., Nakai, T., Liston, G. E., Yamamoto, K., Ohata, T., Ishii, Y., Sumida, A., Hara, T. & Ohta, T. (2011) Impact of land-use changes in a forested region with heavy snowfall in Hokkaido, Japan. Hydrol. Sci. J. 56(3), 443–467.  相似文献   

The role of declining Arctic sea ice in recent decreasing terrestrial Arctic snow depths   总被引：1，自引：1，他引：0  

Hotaek Park  John E. Walsh  Yongwon Kim  Taro Nakai  Tetsuo Ohata 《Polar Science》2013,7(2):174-187

The dramatic decline in Arctic sea ice cover is anticipated to influence atmospheric temperatures and circulation patterns. These changes will affect the terrestrial climate beyond the boundary of the Arctic, consequently modulating terrestrial snow cover. Therefore, an improved understanding of the relationship between Arctic sea ice and snow depth over the terrestrial Arctic is warranted. We examined responses of snow depth to the declining Arctic sea ice extent in September, during the period of 1979–2006. The major reason for a focus on snow depth, rather than snow cover, is because its variability has a climatic memory that impacts hydrothermal processes during the following summer season. Analyses of combined data sets of satellite measurements of sea ice extent and snow depth, simulated by a land surface model (CHANGE), suggested that an anomalously larger snow depth over northeastern Siberia during autumn and winter was significantly correlated to the declining September Arctic sea ice extent, which has resulted in cooling temperatures, along with an increase in precipitation. Meanwhile, the reduction of Arctic sea ice has amplified warming temperatures in North America, which has readily offset the input of precipitation to snow cover, consequently further decreasing snow depth. However, a part of the Canadian Arctic recorded an increase in snow depth driven locally by the diminishing September Arctic sea ice extent. Decreasing snow depth at the hemispheric scale, outside the northernmost regions (i.e., northeastern Siberia and Canadian Arctic), indicated that Arctic amplification related to the diminishing Arctic sea ice has already impacted the terrestrial Arctic snow depth. The strong reduction in Arctic sea ice anticipated in the future also suggests a potential long-range impact on Arctic snow cover. Moreover, the snow depth during the early snow season tends to contribute to the warming of soil temperatures in the following summer, at least in the northernmost regions.  相似文献