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41.
Abstract— Studies of several samples of the large Caddo County IAB iron meteorite reveal andesitic material enriched in Si, Na, Al, and Ca, which is essentially unique among meteorites. This material is believed to have formed from a chondritic source by partial melting and to have further segregated by grain coarsening. Such an origin implies extended metamorphism of the IAB parent body. New 39Ar‐40Ar ages for silicate from three different Caddo samples are consistent with a common age of 4.50‐4.51 Gyr. Less well‐defined Ar‐Ar degassing ages for inclusions from two other IABs, EET (Elephant Moraine) 83333 and Udei Station, are ?4.32 Gyr, whereas the age for Campo del Cielo varies considerably over about 3.23‐4.56 Gyr. New 129I‐129Xe ages for Caddo County and EET 83333 are 4557.9 ± 0.1 Myr and 4557–4560 Myr, respectively, relative to an age of 4562.3 Myr for Shallowater. Considering all reported Ar‐Ar degassing ages for IABs and related winonaites, the range is ?4.32‐4.53 Gyr, but several IABs give similar Ar ages of 4.50‐4.52 Gyr. We interpret these older Ar ages to represent cooling after the time of last significant metamorphism on the parent body and the younger ages to represent later 40Ar diffusion loss. The older Ar‐Ar ages for IABs are similar to Sm‐Nd and Rb‐Sr isochron ages reported in the literature for Caddo County. Considering the possibility that IAB parent body formation was followed by impact disruption, reassembly, and metamorphism (e.g., Benedix et al. 2000), the Ar‐Ar ages and IAB cooling rates deduced from Ni concentration profiles in IAB metal (Herpfer et al. 1994) are consistent if the time of the postassembly metamorphism was as late as about 4.53 Gyr ago. However, I‐Xe ages reported for some IABs define much older ages of about 4558–4566 Myr, which cannot easily be reconciled with the much younger Ar‐Ar and Sm‐Nd ages. An explanation for the difference in radiometric ages of IABs may reside in combinations of the following: a) I‐Xe ages have very high closure temperatures and were not reset during metamorphism about 4.53 Gyr ago; b) a bias exists in the 40K decay constants which makes these Ar‐Ar ages approximately 30 Myr too young; c) the reported Sm‐Nd and Rb‐Sr ages for Caddo are in error by amounts equal to or exceeding their reported 2‐sigma uncertainties; and d) about 30 Myr after the initial heating that produced differentiation of Caddo silicate and mixing of silicate and metal, a mild metamorphism of the IAB parent body reset the Ar‐Ar ages.  相似文献   
42.
Abstract— Y74123 is an olivine-rich, relatively unshocked ureilite and contains more interstitial pigeonitic materials than do ureilites which have been reported previously. Thus, Y74123 is especially suited for detailed study of the interstitial materials. We have studied these materials by optical microscope, electron microprobe, scanning electron microscope, high resolution transmission electron microscope (TEM) and analytical TEM to gain a better understanding of their nature and origin. Y790981, with shock partial melts, has also been examined by the same techniques. Bulk chemical compositions of the interstitial materials in Y74123 are pyroxene-like and have higher CaO and Al2O3 contents than the large pigeonite and olivine core. Interstitial materials at olivine-pigeonite grain boundaries are richer in CaO and Al2O3 than those at olivine-olivine grain boundaries. TEM observations of the interstitial material of Y74123 show that it consists of alternating pigeonite-augite lamellae more than 3.5 μm thick on (001). This texture suggests that the rim material had already crystallized before the parent body breakup. The shock-produced glassy veins in Y790981 cut through the rim materials. These observations are consistent with the idea that the interstitial materials in this ureilite are a mixture of residual liquids of high Ca melts and shock-produced partial melts of olivine and pigeonite. This mixture accumulated along the grain boundaries and some of it is trapped within grains.  相似文献   
43.
Sekiya and Takeda [2003, Earth Planets Space 55, 263-269] showed that the hydrodynamic gas flow around a dust aggregate larger than the mean free path of gas molecules prevents the growth of the body. In contrast to Wurm et al. [2004, Astrophys. J. 606, 983-987], we argue that this conclusion is not altered even if we take account of the effect of the flow through a porous dust aggregate.  相似文献   
44.
Local time variation of geomagnetic transfer functions   总被引:1,自引:0,他引:1  
The local time (LT) variation of the geomagnetic transfer function at the 32-min period was examined for observatories distributed worldwide. Two distinct variation types (types 1 and 2) were found in the real part of A. Type 1 is conspicuous at lower latitudes and its seasonal variation is small, whereas type 2 is found at higher latitudes and has its maximum in summer. These two types of LT variation are seen globally and are conspicuous when solar activity is high. The amplitudes of both types of variation vary from 0.018 to 0.078, and are independent of the mean values at each observatory. These values are relatively small, but the amplitude of Chambon la Foret is larger than the mean value, which shows that Au changes its sign in local time. The amplitudes of type 1 and 2 variations decrease and increase with geomagnetic latitude, respectively. These features suggest that they are generated by some global external fields. The most probable cause is the Sq field, although the Dp field may contribute to type 1 variation. On the other hand, for the islands of the Pacific Ocean at low latitudes, such as Honolulu and Chichijima, the type 1 variation appears not in the real but in the imaginary part of A, which suggests that currents induced in the ocean also contribute to the local time variation.  相似文献   
45.
Crystal-field theory was applied to Fe2+ ions in three types of silicates in an attempt to assign all the major absorption bands with only one parameter to adjust. Coulomb potential energy field were calculated by Fourier method based on all the actual atomic coordinates refined by X-ray diffraction studies. Perturbed d-electron splitting energies of the central Fe2+ ion were calculated by introducing Configuration Interaction (CI) method for the lowest energy spectral states. All the major absorption bands observed in powdered bronzite, augite, and olivine, were assigned to the transitions between those calculated energy levels by optimizing only one parameter that expresses expansion or contraction of d-electron cloud. The result of the calculations gives almost the same assignments as the other previous works for bronzites, different assignments for augites, and a possibility of the existence of the fourth band hidden in the composite 1-μm band of olivines.  相似文献   
46.
Nutrient-enrichment bottle experiments in the northwestern Indian Ocean surface waters were conducted to investigate phytoplankton growth following enrichments with either NH4+, NO3, Fe or Fe + NO3. Stimulation of phytoplankton growth could be achieved by the addition of either NH4+ or NO3 under the ambient Fe concentrations, but the most significant increases in Chl a, POC, and cell densities were observed in the Fe + NO3-amended culture. Iron addition caused more rapid responses of phytoplankton growth in the Fe + NO3 treatment than those in the NO3 and NH4 treatment. However, the Fe-enrichment treatment revealed minimal growth of phytoplankton because of severe major nutrient deficiency and was similar to the control treatment. Increases in the cell density of diatoms and spherical phytoplankton cells (< 10 μm) were significant in the NH4+-enriched samples, whereas NO3 enrichment alone had little effect on the diatoms. Simultaneous addition of Fe and NO3 stimulated maximal growth of phytoplankton, in particular in diatoms, coccolithophorids and Phaeocystis type colonies. However, the dominance of coccolithophorids and Phaeocystis type colonies in the Fe + NO3 treatment may be interpreted as resulting from Si-limitation. The high N/P ratio for phytoplankton nutrient uptake in the N-amended culture indicates the possibility of some P-limited growth. From these results, we conclude that in the northwestern Indian Ocean, Fe and major nutrients are co-limiting phytoplankton production during the northeast monsoon. Iron appeared to affect the ability of phytoplankton to respond quickly to transient nutrient inputs.  相似文献   
47.
Waves which propagate along a vertical wall lying in an arbitrary direction on aβ-plane are derived as a generalization of Haurwitz waves (Haurwitz, 1940) whose direction of propagation is restricted to the east-west direction. The waves are classified into two types. One consists of neutral waves, which correspond to a generalization of Haurwitz waves. The other consists of waves with complex wavenumber and without energy flux. The phase of the waves also propagates in the direction normal to the coast in an envelope except for the case in which the coast lies in the east-west direction.  相似文献   
48.
Topographically trapped (subinertia) waves that propagate along a coast lying in an arbitrary direction on aβ-plane are studied. It is found that the waves also propagate in the direction normal to the coast within an envelope due to theβ-effect. The dispersion relation is hardly affected by theβ-effect except in a long wavelength or long period range in which generalized Haurwitz waves (Takeda, 1984b) exist. In the long wavelength or long period range, two types of waves exist: topographically trapped type waves and generalized Haurwitz type waves.  相似文献   
49.
Aoshio-hypoxic water which can be distinguished from surrounding coastal water by its milky blue-green color-is often observed at the head of Tokyo Bay when coastal upwelling of sulfidic bottom water occurs during summer and early autumn. Optical properties and the biological-chemical composition of suspended matter in theaoshio water were investigated using nearby “normal” coastal water as a reference. Suspended matter in theaoshio water contributed to the large beam-attenuation coefficient and also to the strong upward radiance with maximal intensity around 550 nm as a result of the scattering process. No significant difference in bacterial density was observed between samples ofaoshio water and reference coastal water. The low chlorophylls concentration inaoshio water samples indicates that biological pigments may not play a dominant role in the color of theaoshio events. The suspended particles inaoshio water samples had much higher contents of sulfur and manganese and a lower silicon content than those in reference coastal water samples. The colloidal elemental sulfur and manganese-rich particles identified in theaoshio water appear to be oxidation products of dissolved sulfide and manganese (II) in the anoxic water. On the basis of these findings, it may be concluded that there is a high probability that elemental sulfur and manganese-rich particles are responsible for the color and turbidity inaoshio.  相似文献   
50.
The first iron (Fe) – fertilization experiment in the western North Pacific was carried out using SF6 to trace the Fe-fertilized water mass. A solution in 10,800 liters of seawater of 350 kg of Fe and 0.48 M of SF6 tracer was released into the mixed layer over a 8 × 10 km area. On the first underway transects through the patch after the Fe release, we observed a significant increase of dissolved Fe (ave. 2.89 nM). The fertilized patch was traced for 14 days by on-board SF6 analysis. A Lagrangian frame of reference was maintained by the use of a drogued GPS buoy released at the center of the patch. The patch moved westward at a rate of 6.8 km d−1. Mixed layer depth increased from 8.5 to 15 m during the experiment. Horizontal diffusivity was determined by the change of SF6 concentration in the patch. The horizontal diffusivity increased during the experiment. We evaluate here the fate of Fe in a Fe-fertilized patch using the dilution rate determined from sulphur hexafluoride (SF6) concentration. Dissolved Fe concentrations subsequently decreased rapidly to 0.15 nM on Day 13. However, the dissolved Fe half-life of 43 h was relatively longer than in previous Fe-enrichment studies, and we observed a larger increase of the centric diatom standing stock and corresponding drawdown of macro-nutrients and carbon dioxide than in the previous studies. The most important reason for the larger response was the phytoplankton species in the western North Pacific. In addition, the smaller diffusivity and shallower mixed layer were effective to sustain the higher dissolved Fe concentration compared to previous experiments. This might be one reason for the larger response of diatoms in SEEDS.  相似文献   
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