Direct Determination of Lead Isotope Ratios by Laser Ablation-Inductively Coupled Plasma-Quadrupole Mass Spectrometry in Lake Sediment Samples   总被引：1，自引：0，他引：1  

Sébastien Aries  Mikael Motelica-Heino  Rémi Freydier  Thierry Grezes  Mireille Polvé 《Geostandards and Geoanalytical Research》2001,25(2-3):387-398

A direct method for the determination of lead isotopic ratios by laser ablation-inductively coupled plasma-quadrupole mass spectrometry (LA-ICP-QMS) is presented. Samples of lake sediments were ground and pressed as pellets before being analysed. Mass bias was corrected by analysing an external calibration sample manufactured with pure silica doped with NIST SRM 981 solution. The efficiency of the mass bias correction was checked by comparing the ICP-MS data with lead isotopic ratios determined by thermal ionisation mass spectrometry (TIMS). The average long term reproducibilities were 0.40%, 0.40%, 0.20% and 0.30% (RSD) respectively for the ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, ²⁰⁶Pb/²⁰⁷Pb and ²⁰⁸Pb/²⁰⁶Pb ratios. The method was applied to the study of lake sediment samples, in order to determine the amount and origin of historical contamination by lead.  相似文献   

Which variables are essential for renewable energies?     

Thierry Ranchin  Mélodie Trolliet  Lionel Ménard  Lucien Wald 《International Journal of Digital Earth》2020,13(2):253-261

ABSTRACT

Essential Variables are defined as a minimal set of variables that explain the state of the system. They are crucial for predicting its developments, and support metrics that measure its evolution. The variables should be relevant to meet requirements of stakeholders and be technically and economically feasible for systematic observation. A definition of Essential Renewable Energies Variables is proposed linked with their identification in several domains in renewable energy using a bottom-up and user-driven approach, and spanning over several years of documented interaction with stakeholders. Lists of variables are proposed in hydropower, solar, wind, and marine energies. It does not comprise the variables relating to social and economic aspects supporting decision making in investment nor those relating to civil engineering that are needed to erect a plant or farm.  相似文献   

Radiation-induced paramagnetic defects in natural kaolinites: Alpha dosimetry with ion beam irradiation     

Thierry Allard  Jean-Pierre Muller  Jean-Claude Dran  Marie-Thérèse Ménager 《Physics and Chemistry of Minerals》1994,21(1-2):85-96

Three types of paramagnetic radiation-induced defects (RID), namely A, A′ (Si-O^?-centers) and B (Al-O^?-Al center), had been identified in natural kaolinites by means of electron paramagnetic resonance spectroscopy. The A-center, stable at the scale of geological periods, was thought to be of particular relevance to quantify past transits of radionuclides in the geosphere. Alpha radiation being likely the main source of RID in kaolinite, the objective of this paper is to define the role of α-particles on the creation of RID and to test the use of A-centers for an α-dosimetry. Three kaolinites with different crystalline order and containing other clays as impurities were irradiated with He⁺ ion beams. The radiation dose range (0–750 MGy) was consistent with natural radioactivity in environments from the Earth's surface. Irradiation drastically enhanced the original signals due to RID. An important increase of concentration of the unstable B-center, partly due to unrealistic dose rate provided by accelerator ion beam, was observed from the lower doses. The most stable defects remained of the Atype all along experimental irradiations. The contribution of ancillary phyllosilicates to EPR spectra was negligible. The concentration of the three types of RID was related to radiation doses up to 30 MGy. Dosimetry growth curves for the A-centers exhibited variable efficiencies and saturation levels that were related to the structural order and the chemical purity of the kaolinites: the more ordered and purer the kaolinite, the higher the efficiency and the lower the saturation plateau. Moreover, these results are of geochemical significance: dosimetry based on A-centers could be directly used to quantify past migrations of radioelements in the geosphere, by determination of the naturally-cumulated doses (paleodose) of kaolinites.  相似文献   

Turbulence intensities and bulk coefficients in the surface layer above the sea   总被引：4，自引：0，他引：4  

Thierry Hedde  Pierre Durand 《Boundary-Layer Meteorology》1994,71(4):415-432

The structure of the atmospheric surface layer above the sea is analysed from aircraft turbulence measurements. The data are issued from two experiments performed in 1990 above the Mediterranean sea: Crau and PYREX, and correspond to moderately unstable conditions and to wind velocities ranging from 6 to 20 m/s. Low-altitude straight and level runs were used to compute the variances of the wind components, as well as of the temperature and moisture. Their dependence on the stability index —z/L is analysed. The turbulent fluxes of momentum, sensible heat and latent heat, calculated by the eddy-correlation technique, are used to estimate the neutral bulk coefficients: drag coefficient, Stanton number and Dalton number. The neutral drag coefficient clearly exhibits a dependence on the windspeed, which could be well fitted by the Charnock relation, with a constant of 0.012.  相似文献   

Thermodynamic properties of the forsterite-fayalite (Mg2SiO4-Fe2SiO4) solid solution. determination of heat of formation     

P. Thierry  C. Chatillon-Colinet  J. C. Mathieu  J. R. Regnard  J. Amossé 《Physics and Chemistry of Minerals》1981,7(1):43-46

A high temperature calorimetric solution method involving the use of a sodium and lithium metaborate (NaBO₂+LiBO₂) molten bath at 1,180 K, has been developed in order to measure the enthalpy of formation of the forsterite-fayalite (Mg₂SiO₄-Fe₂SiO₄) system. The samples used for these measurements have been obtained by synthesis. They have been carefully controlled by chemical and X-ray analysis and Mössbauer spectroscopy. The results obtained for forsterite and fayalite agree closely with the data commonly found in the literature. Owing to the uncertainty of the experimental results, it is not possible to determine conclusively whether an enthalpy of mixing exists in this system.  相似文献   

Mineral-chemistry and stable-isotope constraints on the magmatism, hydrothermal alteration, and related PGE–(base-metal sulphide) mineralisation of the Mesoarchaean Baula-Nuasahi Complex, India     

Thierry Augé  Catherine Lerouge 《Mineralium Deposita》2004,39(5-6):583-607

The Baula-Nuasahi Complex, on the southern flank of the Singhbhum Archaean nucleus in north-eastern India, exposes a series of Mesoarchaean igneous suites. These are (1) a gabbro–anorthosite unit, which is petrographically homogeneous, although mineral-chemistry data hint at a subtle eastward differentiation; (2) a peridotite unit (with three chromitite layers) together with (3) a pyroxenite unit which display cumulate textures, modal layering, and (for the peridotite unit) differentiation trends in both mineralogy and mineral chemistry; and (4) the Bangur gabbro (~3.1 Ga), which defines an oblong intrusion, crosscutting the older igneous suites in the southern part of the complex, with a curvilinear NW-trending apophysis, 2 km long and up to 40 m wide. Magmatic breccia comprising ultramafic and chromitite wall-rock clasts in a gabbro matrix is exposed at the contact of the main Bangur gabbro body and also forms the entire Bangur gabbro apophysis. Concentrations of platinum-group minerals (PGMs) are found where the breccia contains abundant chromitite clasts, and two types of platinum-group-element (PGE) mineralisation are recognised. Type 1 (Pt 1.1–14.2, Pd 0.1–2.1 ppm, with an average Pt/Pd=8–9) is a contact-type mineralisation which occurs in the breccia at the contact between the Bangur intrusion and its ultramafic host. The PGMs—Pt alloys (isoferroplatinum) and sulphides (braggite, malanite)—are enclosed by pyroxene and plagioclase, reflecting a magmatic origin. Significant wall-rock assimilation by the magma (giving rise to the Bangur gabbro) is indicated by changes in pyroxene composition and by the presence of relicts of chromite (from the host) now altered to secondary ferritchromite in the contact zone. Type 2 PGE mineralisation (Pt 0.3–1.6, Pd 1.8–6.0 ppm, with Pt/Pd~0.5–3.0) is restricted to the breccia apophysis of the Bangur gabbro where it occurs in the breccia matrix, associated with an intense hydrothermal alteration which does not exist in the contact zone. PGMs (PGE arsenides, tellurides, bismuthides and antimonides) and, where present, base-metal sulphides (BMSs) form intergrowths with hydrous silicates, reflecting a hydrothermal origin. Oxygen isotope geothermometry documents the main stages of hydrothermal alteration within a decreasing temperature range between 700–1,000 and 500–600 °C, and oxygen, hydrogen and sulphur isotopes show that the hydrothermal fluids were derived from the magma rather than an external source. Pervasive hydrothermal alteration in the breccia apophysis likely represents upward channelling of late-magmatic fluids along a narrow, near-vertical, subplanar conduit which led away from the main magma chamber. We suggest that Type 2 mineralisation was produced by late-magmatic hydrothermal remobilisation and reconcentration of Type 1 PGE mineralisation, and that the composition of the hydrothermal fluids controlled whether BMSs were enriched along with the PGMs.Editorial handling: P. Lightfoot  相似文献   

Un réseau fluviatile d'âge Burdigalien terminal dans le Sud-Est de la France : remplissage,extension, âge,implications     

David Besson  Olivier Parize  Jean-Loup Rubino  Jean-Pierre Aguilar  Marie-Pierre Aubry  Bernard Beaudoin  William A. Berggren  Georges Clauzon  Philippe Crumeyrolle  Yann Dexcoté  Nicolas Fiet  Silvia Iaccarino  Gonzalo Jiménez-Moreno  Cécile Laporte-Galaa  Jacques Michaux  Katharina von Salis  Jean-Pierre Suc  Jean-Yves Reynaud  Roland Wernli 《Comptes Rendus Geoscience》2005,337(12):1045-1054

An integrated study combining facies analysis, multiple group biostratigraphy, identification of depositional sequences and mapping has been conducted on the Miocene Molasse Basin of the external Alps (southeastern France). The filling of the basin is described as resulting from a succession of fluvial incisions subsequently filled during marine transgressions. The major incision is dated as Latest Burdigalian and the major transgression as Langhian. This revised interpretation of the Miocene physiographic evolution of the Molasse Basin implies a re-examination of previous stratigraphic correlations within the basin. To cite this article: D. Besson et al., C. R. Geoscience 337 (2005).  相似文献   

Comparative research on integrated development of large river basins: a case study of the Yangtze and the Rhone     

LIU Hui  Jean-Paul Bravard  CAI Zongxia  Thierry Sanjuan 《地理学报》2006,16(3):378-382

Since 2001, the French and Chinese researchers have done a cooperative research on the comparison of integrated development of large river basins. The Yangtze River was chosen as a crux of this research and linked with other older river experiments like the Rhone, the Nile and the Mississippi. This research includes not only the environmental issues but also economic and social issues. One special issue journal has been published in French for our research results. Other two collective and comparative books in French and Chinese will be finished at the end of this year. In the future, the comparison should be widened to Italy (the Po), Egypt (the Nile development planning) and the United States (the Mississippi Basin) and we would like to enlarge our research group and want to link up different teams and research projects, in order to get a global understanding of large river regions phenomenon.  相似文献   

Sur l’origine karstique et l’age plio-quaternaire des accumulations bréchiques dites ?brèches marines et paléocènes? d’Amélie-les-Bains (Pyrénées-Orientales, France)     

Joseph Canerot  Bernard Laumonier  Thierry Baudin 《Eclogae Geologicae Helvetiae》2006,99(1):49-64

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Relationship between point rainfall, average sampled rainfall and ground truth at the event scale in the Sahel   总被引：1，自引：0，他引：1  

Abou Amani  Thierry Lebel 《Stochastic Hydrology and Hydraulics》1998,12(2):141-154

Geostatistical techniques are used to quantify the reference mean areal rainfall (ground truth) from sparse raingaugenetworks. Based on the EPSAT-Niger event cumulative rainfall, a linear relationship between the ground truth considered as the mean area rainfall estimated from the densely available raingauge network and the area rainfall estimated from sparse network are derived. Also, a linear relationship between the ground truth and point rainfall is established. As it was reported experimentally by some authors, the slope of these relationships is less than one. Based on the geostatistical framework, the slope and the ordinate at the origin can be estimated as a function of the spatial structure of the rainfall process. It is shown that the slope is smaller than one. For the special case of one gauge inside a fixed area or a Field Of View (FOV), an areal reduction factor is derived. It has a limit value which depends only on the size of the area and the spatial structure of the rainfall process. The relative variance error of estimating the FOV cumulative rainfall from point rainfall is also given.  相似文献