Sampling strategy and climatic implications of tree-ring stable isotopes on the southeast Tibetan Plateau     

Chunming Shi  Valérie Masson-Delmotte  Camille Risi  Thomas Eglin  Michel Stievenard  Monique Pierre  Xiaochun Wang  Jing Gao  François-Marie Bréon  Qi-Bin Zhang  Valérie Daux 《Earth and Planetary Science Letters》2011,301(1-2):307-316

We explore the potential of tree-ring cellulose δ¹⁸O and δ¹³C records for reconstructing climate variability in the southeast Tibetan Plateau. Our sampling strategy was designed to investigate intra and inter-tree variability, and the effects of the age of tree on δ¹⁸O variation. We show that intra-tree δ¹³C and δ¹⁸O variability is negligible, and inter-tree coherence is sufficient to build robust tree-ring δ¹⁸O or δ¹³C chronologies based on only four trees. There is no evidence of an age effect regarding δ¹⁸O, in contrast with tree-ring width. In our warm and moist sampling site, young tree δ¹³C is not clearly correlated with monthly mean meteorological data. Tree-ring δ¹⁸O appears significantly anti-correlated with summer precipitation amount, regional cloud cover, and relative humidity. Simulations conducted with the ORCHIDEE land surface model confirm the observed contribution of relative humidity to tree cellulose δ¹⁸O, and explain the weak correlation of δ¹³C with climate by the non-linear integration linked with photosynthesis. Altogether, the tree-ring cellulose δ¹⁸O is shown to be a promising proxy to reconstruct regional summer moisture variability prior to the instrumental period.  相似文献   

Confined aquifer loading: implications for groundwater management     

Maliva RG  Coulibaly K  Guo W  Missimer TM 《Ground water》2011,49(3):302-304

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Be-daughter minerals in fluid and melt inclusions: implications for the enrichment of Be in granite–pegmatite systems     

R. Thomas  J. D. Webster  P. Davidson 《Contributions to Mineralogy and Petrology》2011,161(3):483-495

The study of re-homogenized melt inclusions in the same growth planes of quartz of pegmatites genetically linked to the Variscan granite of the Ehrenfriedersdorf complex, Erzgebirge, Germany, by ion microprobe analyses has determined high concentrations of Be, up to 10,000 ppm, in one type of melt inclusion, as well as moderate concentrations in the 100 ppm range in a second type of melt inclusion. Generally, the high Be concentrations are associated with the H₂O- and other volatile-rich type-B melt inclusions, and the lower Be concentration levels are connected to H₂O-poor type-A melt inclusions. Both inclusion types, representing conjugate melt pairs, are formed by a liquid–liquid immiscibility separation process. This extremely strong and very systematic scattering in Be provides insights into the origin of Be concentration and transport mechanisms in pegmatite-forming melts. In this contribution, we present more than 250 new analytical data and show with ion microprobe and fs-LA-ICPMS studies on quenched glasses, as well as with confocal Raman spectroscopy of daughter minerals in unheated melt inclusions, that the concentrations of Be may achieve such extreme levels during melt–melt immiscibility of H₂O-, B-, F-, P-, ± Li-enriched pegmatite-forming magmas. Starting from host granite with about 10 ppm Be, melt inclusions with 10,000 ppm Be correspond to enrichment by a factor of over 1,000. This strong enrichment of Be is the result of processes of fractional crystallization and further enrichment in melt patches of pegmatite bodies due to melt–melt immiscibility at fluid saturation. We also draw additional conclusions regarding the speciation of Be in pegmatite-forming melt systems from investigation of the Be-bearing daughter mineral phases in the most H₂O-rich melt inclusions. In the case of evolved volatile and H₂O-rich pegmatite systems, B, P, and carbonates are important for the enrichment and formation of stable Be complexes.  相似文献   

Implications of the serpentine phase transition on the behaviour of beryllium and lithium-boron of subducted ultramafic rocks     

Flurin Vils  Othmar Müntener  Thomas Ludwig 《Geochimica et cosmochimica acta》2011,75(5):1249-362

The Totalp-Platta-Malenco ophiolites in the Eastern Central Alps offer a unique opportunity to study the behaviour of Li, Be and B in ultramafic rocks in response to serpentinization and to progressive Alpine metamorphism. These units represent the remnants of a former ocean-continent transition that was intensely serpentinized during exposure on the Jurassic seafloor of the Ligurian Tethys. From north to the south, three isograd reactions (lizardite⇒antigorite+brucite;lizardite+talc⇒antigorite;lizardite+tremolite⇒antigorite+diopside) have been used to quantify the evolution of the light element content of metamorphic minerals. We determined the Li, Be and B concentrations in major silicate minerals from the ultramafic bodies of Totalp, Platta and Malenco by secondary ion mass spectrometry. Mantle minerals have Be concentrations (e.g. <0.001-0.009 μg/g in olivine) similar to the metamorphic minerals that replace them (e.g. <0.001-0.016 μg/g in serpentine). The mantle signature of Be is thus neither erased during seafloor alteration nor by progressive metamorphism from prehnite-pumpellyite to epidote-amphibolite facies. In contrast, the Li and B inventories of metamorphic minerals are related to the lizardite-to-antigorite transition. Both elements display higher concentrations in the low-temperature serpentine polymorph lizardite (max. 156 μg/g Li, max. 318 μg/g B) than in antigorite (max. 0.11 μg/g Li, max. 12 μg/g B). Calculated average B/Li ratios for lizardite (∼1395) and antigorite (∼115) indicate that Li fractionates from B during the lizardite-to-antigorite transition during prograde metamorphism in ultramafic rocks. In subduction zones, this signature is likely to be recorded in the B-rich nature of forearc fluids.Relative to oceanic mantle the Be content of mantle clinopyroxene is much higher, but similar to Be values from mantle xenoliths and subduction-related peridotite massifs. These data support previous hypothesis that the mantle rocks from the Eastern Central Alps have a subcontinental origin. We conclude that Be behaves conservatively during subduction metamorphism of ultramafic rocks, at least at low-temperature, and thus retains the fingerprint of ancient subduction-related igneous events in mantle peridotites.  相似文献   

Mo isotope composition in Mo-rich high- and low-T hydrothermal systems from the Swiss Alps     

Nicolas D. Greber  Beda A. Hofmann  Igor M. Villa  Thomas F. Nägler 《Geochimica et cosmochimica acta》2011,75(21):6600-6609

We analyzed the molybdenum (Mo) isotope compositions (IC) of 59 samples from two molybdenite mineralizations (Alpjahorn and Grimsel) and from a Mo-rich hydrothermal breccia (Grimsel) from the Aar Massif, Switzerland. The formation temperature of the Late Paleozoic Mo mineralizations (300-600 °C) is much higher than that of the Pliocene breccia (100-160 °C). The Mo IC of the molybdenites varies over 1.35‰. Even in a single hand specimen it spans 0.45‰, indicating that fractionation processes during molybdenite precipitation can vary on a cm scale. The Mo IC of most molybdenites analyzed here are significantly heavier than that of the host rock (δ^98/95Mo = (0.05 ± 0.1)‰) and show a bimodal distribution centered around δ^98/95Mo ≈ 1.1‰ and 0.2‰. This result rules out single stage Rayleigh fractionation as the relevant formation mechanism and instead, redox variations are suggested to be a main factor controlling the Mo IC of the studied high-temperature Mo deposits. The range of the Mo IC in one single deposit, the Alpjahorn, overlaps with the variation range of almost all other published values for Mo IC in Mo deposits. Compared to the molybdenites, the breccia shows an even wider variation of 3.0‰ (δ^98/95Mo between −1.6‰ and +1.4‰). In contrast to the high-T molybdenite deposits, here the Mo was transported via oxidized surface waters into the breccia system, where it was reduced and precipitated. This indicates that oxidation and reduction of Mo complexes may lead to highly variable Mo IC in hydrothermal systems.  相似文献   

Catabolic and anabolic energy for chemolithoautotrophs in deep-sea hydrothermal systems hosted in different rock types     

Jan P. Amend  Thomas M. McCollom  Wolfgang Bach 《Geochimica et cosmochimica acta》2011,75(19):5736-5748

Active deep-sea hydrothermal vents are hosted by a range of different rock types, including basalt, peridotite, and felsic rocks. The associated hydrothermal fluids exhibit substantial chemical variability, which is largely attributable to compositional differences among the underlying host rocks. Numerical models were used to evaluate the energetics of seven inorganic redox reactions (potential catabolisms of chemolithoautotrophs) and numerous biomolecule synthesis reactions (anabolism) in a representative sampling of these systems, where chemical gradients are established by mixing hydrothermal fluid with seawater. The wide ranging fluid compositions dictate demonstrable differences in Gibbs energies (ΔG_r) of these catabolic and anabolic reactions in three peridotite-hosted, six basalt-hosted, one troctolite-basalt hybrid, and two felsic rock-hosted systems. In peridotite-hosted systems at low to moderate temperatures (<∼45 °C) and high seawater:hydrothermal fluid (SW:HF) mixing ratios (>10), hydrogen oxidation yields the most catabolic energy, but the oxidation of methane, ferrous iron, and sulfide can also be moderately exergonic. At higher temperatures, and consequent SW:HF mixing ratios <10, anaerobic processes dominate the energy landscape; sulfate reduction and methanogenesis are more exergonic than any of the aerobic respiration reactions. By comparison, in the basalt-hosted and felsic rock-hosted systems, sulfide oxidation was the predominant catabolic energy source at all temperatures (and SW:HF ratios) considered. The energetics of catabolism at the troctolite-basalt hybrid system were intermediate to these extremes. Reaction energetics for anabolism in chemolithoautotrophs—represented here by the synthesis of amino acids, nucleotides, fatty acids, saccharides, and amines—were generally most favorable at moderate temperatures (22-32 °C) and corresponding SW:HF mixing ratios (∼15). In peridotite-hosted and the troctolite-basalt hybrid systems, ΔG_r for primary biomass synthesis yielded up to ∼900 J per g dry cell mass. The energetics of anabolism in basalt- and felsic rock-hosted systems were far less favorable. The results suggest that in peridotite-hosted (and troctolite-basalt hybrid) systems, compared with their basalt (and felsic rock) counterparts, microbial catabolic strategies—and consequently variations in microbial phylotypes—may be far more diverse and some biomass synthesis may yield energy rather than imposing a high energetic cost.  相似文献   

Origin of magmatic sulfides in a Proterozoic island arc—an example from the Portneuf–Mauricie Domain,Grenville Province,Canada     

Anne-Aurélie Sappin  Marc Constantin  Thomas Clark 《Mineralium Deposita》2011,46(3):211-237

The Portneuf–Mauricie Domain (PMD), located in the south-central part of the Grenville province, contains Mesoproterozoic Ni–Cu ± platinum-group element (PGE) prospects hosted in a variety of plutonic intrusions (layered, with simple structures, or zoned) and emplaced in a mature island arc setting. A two-stage model is envisaged to explain the formation of magmatic sulfides. An early loss of a small amount of sulfides in the conduits of primitive, hydrous mantle-derived melts under high fO₂, resulted in depletion of the magmas in chalcophile and precious metals (Cu/Pd ratios vary from initial mantle values up to 1.6 × 10⁶). Then, nearer the mineralized zones, the magmas interacted with sulfide-bearing country rocks, resulting in felsification of the magmas, assimilation of crustal sulfur (δ ³⁴S values up to +5.5‰), and the formation of an immiscible sulfide liquid. Liquid-sulfide formation was followed by variable interactions between the silicate and sulfide magmas, which were responsible for the enrichment of sulfides in Ni, Cu, and, locally, PGE. Indeed, low R factors are found for prospects hosted in intrusions with a simple internal structure and in layered intrusions whereas high R factors are found for prospects hosted in zoned intrusions. Finally, sulfide melt may have been partly incorporated into later pulses of magma and injected into shallow magma chambers to form the PMD prospects. The PMD prospects share common characteristics with other well-known deposits (Aguablanca, Vammala, Stormyrplunen, and deposits in Alaskan/Ural-type intrusions), attesting to the Ni, Cu, and PGE potential of deposits associated with subduction-zone settings.  相似文献   

Associated terrestrial and marine fossils in the late-glacial Presumpscot Formation, southern Maine, USA, and the marine reservoir effect on radiocarbon ages   总被引：1，自引：0，他引：1  

Woodrow B. Thompson  Carol B. Griggs  Norton G. Miller  Robert E. Nelson  Thomas K. Weddle  Taylor M. Kilian   《Quaternary Research》2011,75(3):552-565

Excavations in the late-glacial Presumpscot Formation at Portland, Maine, uncovered tree remains and other terrestrial organics associated with marine invertebrate shells in a landslide deposit. Buds of Populus balsamifera (balsam poplar) occurred with twigs of Picea glauca (white spruce) in the Presumpscot clay. Tree rings in Picea logs indicate that the trees all died during winter dormancy in the same year. Ring widths show patterns of variation indicating responses to environmental changes. Fossil mosses and insects represent a variety of species and wet to dry microsites. The late-glacial environment at the site was similar to that of today's Maine coast. Radiocarbon ages of 14 tree samples are 11,907 ± 31 to 11,650 ± 50 ¹⁴C yr BP. Wiggle matching of dated tree-ring segments to radiocarbon calibration data sets dates the landslide occurrence at ca. 13,520 + 95/−20 cal yr BP. Ages of shells juxtaposed with the logs are 12,850 ± 65 ¹⁴C yr BP (Mytilus edulis) and 12,800 ± 55 ¹⁴C yr BP (Balanus sp.), indicating a marine reservoir age of about 1000 yr. Using this value to correct previously published radiocarbon ages reduces the discrepancy between the Maine deglaciation chronology and the varve-based chronology elsewhere in New England.  相似文献   

Direct terrestrial-marine correlation demonstrates surprisingly late onset of the last interglacial in central Europe     

Mark J. Sier  Wil Roebroeks  Corrie C. Bakels  Enrico Brühl  Dimitri De Loecker  Norbert Hesse  Lutz Kindler  Thomas Laurat  Herman J. Mücher  Kirsty E.H. Penkman  Douwe J.J. van Hinsbergen 《Quaternary Research》2011,75(1):213-218

An interdisciplinary study of a small sedimentary basin at Neumark Nord 2 (NN2), Germany, has yielded a high-resolution record of the palaeomagnetic Blake Event, which we are able to place at the early part of the last interglacial pollen sequence documented from the same section. We use this data to calculate the duration of this stratigraphically important event at 3400 ± 350 yr. More importantly, the Neumark Nord 2 data enables precise terrestrial-marine correlation for the Eemian stage in central Europe. This shows a remarkably large time lag of ca. 5000 yr between the MIS 5e ‘peak’ in the marine record and the start of the last interglacial in this region.  相似文献   

Leaching of metals from copper smelter flue dust (Mufulira,Zambian Copperbelt)     

Martina Vítková  Vojtěch Ettler  Jiri Hyks  Thomas Astrup  Bohdan Kříbek 《Applied Geochemistry》2011

The leaching behaviour of electrostatic precipitator dust from the Mufulira Cu smelter (Copperbelt, Zambia) was studied using a 48-h pH-static leaching experiment (CEN/TS 14997). The release of metals (Cd, Co, Cu, Ni, Pb and Zn) and changes in mineralogical composition using X-ray diffraction and PHREEQC-2 modelling were investigated in the pH range of 3–7. The highest concentrations of metals were released at pH 3–4.5, which encompasses the natural pH of the dust suspension (～4.3). About 40% of the total Cu was leached at pH 3, yielding 107 g/kg. Chalcanthite (CuSO₄·5H₂O), magnetite (Fe₃O₄) and delafossite (CuFeO₂) represented the principal phases of the studied dust. In contact with water, chalcanthite was dissolved and hydrated Cu sulphates precipitated at pH 4–7. Gypsum (CaSO₄·2H₂O) and secondary Fe or Al phases were observed in the leached residues. Serious environmental impact due to leaching may occur in dust-contaminated soil systems in the vicinity of the smelting plants.  相似文献