ELNES spectroscopy of mixed Si coordination minerals     

B. Poe  F. Seifert  T. Sharp  Z. Wu 《Physics and Chemistry of Minerals》1997,24(7):477-487

 Si K- and L-edge ELNES spectroscopy and multiple-scattering (MS) calculations are used to examine mixed Si coordination compounds varying in Si^VI:Si^IV ratio. As in previous studies, the edges are influenced mainly by silicon coordination (tetrahedral vs. octahedral), as supported by the MS calculations. We demonstrate two methods semi-quantitatively to extract the value of Si^VI/(Si^VI+Si^IV): (1) A linear relationship between the L_2,3-L₁ splitting and Si^VI/(Si^VI+Si^IV) is observed, (2) a fitting method based on the coaddition of reference tetrahedral and octahedral Si spectra is applied to both Si K- and L-edge ELNES spectra. Received: February 10, 1997 / Revised, accepted: May 23, 1997  相似文献   

Distribution of isomorphous cations within octahedral sheets in montmorillonite from Camp-Bertaux     

F. Muller  G. Besson  A. Manceau  V.-A. Drits 《Physics and Chemistry of Minerals》1997,24(3):159-166

 Ni-saturated montmorillonite from Camp-Bertaux heated at different temperatures has been studied by X-ray powder diffraction, X-ray absorption (EXAFS) and vibration IR spectroscopy. Analysis of the experimental data has shown that heating of samples at temperatures higher than 150° C was accompanied by migration of Ni cations into vacant cis-octahedra of 2:1 layers. In the octahedral sheet the Ni cation has two “heavy” (Fe) and four “light” (Al and Mg) nearest octahedral cations. A model for the octahedral cation distribution in Camp-Bertaux montmorillonite was proposed in which Fe and Mg octahedral cations are segregated in small clusters. Received July 7, 1996 / Revised, accepted August 23, 1996  相似文献   

中国汽车工业──改革开放后的重整与国际化   总被引：4，自引：0，他引：4  

薛凤旋  刘卫东 《地理研究》1997,16(3):1-11

大规模的重整和广泛的国际化是改革开放后中国汽车工业发展的两个主要特征。作者首先从企业组织结构、生产能力与品种结构、规模经济和空间分布等四个方面分析了近二十年来中国汽车工业重整的效果及所形成的行业特征;其次根据利用的外资和技术的来源以及涉及的技术形态分析了其国际化的程度及在世界汽车工业中的位置;最后总结了中国汽车工业面临的若干问题,并提出在散乱的格局和跨国公司竞争的双重压力下,中国汽车工业正处于成长的关键时期。  相似文献   

Diatom assemblages from Costa Rican lakes: an initial ecological assessment     

Kurt A. Haberyan  Sally P. Horn  Brian F. Cumming 《Journal of Paleolimnology》1997,17(3):263-274

We compared the distributions of 59 diatom species in surface sediments of 25 Costa Rican lakes with 21 environmental variables using canonical correspondence analysis (CCA). The distribution of taxa was related to the chemical and physical characteristics of the lakes. The most influential chemical variables were cation concentrations (especially magnesium) and related variables such as water hardness, pH, and temperature. Lake area and lake depth were among the most important physical variables.A number of taxa were identified as potential environmental indicators. The diatoms Brachysira serians var. brachysira and Frustulia rhomboides seem to be associated with low values of alkalinity, hardness, Ca, Mg, and SiO2. Cymbella minuta var. silesiaca is associated with low to moderate values of alkalinity, hardness, Ca, and Mg. Nitzschia cf. amphibia may be an indicator of moderate-to-high concentrations of Mg. Pinnularia braunii var. amphicephala seems to prefer low values of hardness, Ca, Mg, and SiO2.In many closed lakes, these environmental variables (Mg/Ca/hardness/alkalinity) increase with effective evaporation. Consequently, these diatoms may be indirectly tracking P:E ratios. Results from this initial, small data set indicate the potential of diatoms for inferring lake paleochemistry, and perhaps P:E ratios, in Costa Rica.  相似文献   

Diatoms in sediments of perennially ice-covered Lake Hoare, and implications for interpreting lake history in the McMurdo Dry Valleys of Antarctica     

S. A. Spaulding  D. M. McKnight  E. F. Stoermer  P. T. Doran 《Journal of Paleolimnology》1997,17(4):403-420

Diatom assemblages in surficial sediments, sediment cores, sediment traps, and inflowing streams of perennially ice-covered Lake Hoare, South Victorialand, Antarctica were examined to determine the distribution of diatom taxa, and to ascertain if diatom species composition has changed over time. Lake Hoare is a closed-basin lake with an area of 1.8 km², maximum depth of 34 m, and mean depth of 14 m, although lake level has been rising at a rate of 0.09 m yr^-1 in recent decades. The lake has an unusual regime of sediment deposition: coarse grained sediments accumulate on the ice surface and are deposited episodically on the lake bottom. Benthic microbial mats are covered in situ by the coarse episodic deposits, and the new surfaces are recolonized. Ice cover prevents wind-induced mixing, creating the unique depositional environment in which sediment cores record the history of a particular site, rather than a lake-wide integration. Shallow-water (<1 m) diatom assemblages (Stauroneis anceps, Navicula molesta, Diadesmis contenta var. parallela, Navicula peraustralis) were distinct from mid-depth (4–16 m) assemblages (Diadesmis contenta, Luticola muticopsis fo. reducta, Stauroneis anceps, Diadesmis contenta var. parallela, Luticola murrayi) and deep-water (26–31 m) assemblages (Luticola murrayi, Luticola muticopsis fo. reducta, Navicula molesta). Analysis of a sediment core (30 cm long, from 11 m water depth) from Lake Hoare revealed two abrupt changes in diatom assemblages. The upper section of the sediment core contained the greatest biomass of benthic microbial mat, as well as the greatest total abundance and diversity of diatoms. Relative abundances of diatoms in this section are similar to the surficial samples from mid-depths. An intermediate zone contained less organic material and lower densities of diatoms. The bottom section of core contained the least amount of microbial mat and organic material, and the lowest density of diatoms. The dominant process influencing species composition and abundance of diatom assemblages in the benthic microbial mats is episodic deposition of coarse sediment from the ice surface.  相似文献   

A record of accelerated erosion in the recent sediments of Blelham Tarn in the English Lake district   总被引：1，自引：0，他引：1  

K. D. van der Post  F. Oldfield  E. Y. Haworth  P. R. J. Crooks  P. G. Appleby 《Journal of Paleolimnology》1997,18(2):103-120

Two frozen cores from Blelham Tarn were subsampled and measured using mineral magnetic, loss-on-ignition (LOI), radiometric, granulometric and diatom analyses. A detailed chronology was established using varves, radioisotopes and diatoms. This has enabled an accurately dated reconstruction of sedimentation over the past forty years. Despite a large increase in lake productivity, evidence suggests that the observed exponential increase in sedimentation rates can be attributed to erosion within the catchment. The predominant sediment source has been identified as surface soil. A comparison between the trend of accelerated sedimentation and the record of increased sheep stocking density for the area within which the most of the catchment lies, as well as observations of contemporary surface processes within the catchment, both suggest that much of the recent erosion is a direct response to increased pressure from sheep grazing.  相似文献   

An auto-biographical approach to understanding migration: the case of Hong Kong emigrants   总被引：1，自引：0，他引：1  

A M Findlay  F L N Li 《Area》1997,29(1):34-44

Summary This paper seeks to make a methodological contribution by evaluating the autobiographical approach and its application to migration research. The migration act is seen as a manifestation of an individual's identity. This is moulded by many social influences over an individual's lifecourse. The paper explores the realm of practical consciousness (Giddens 1984) using a biographical approach in an attempt to identify the values underpinning the intentions of professional emigrants from Hong Kong.  相似文献   

Lower-crustal rifting in the Rukwa Graben, East Africa     

Ming Zhao  Charles A. Langston  rew A. Nyblade  Thomas J. Owens 《Geophysical Journal International》1997,129(2):412-420

An M_w 5.9 earthquake occurred in the Lake Rukwa rift, Tanzania, on 1994 August 18, and was well recorded by 20 broad-band seismic stations at distances of 160 to 800 km and 21 broad-band stations at teleseismic distances. The regional and teleseismic waveforms have been used to investigate the source characteristics of the main shock, and also to locate aftershocks that occurred within three weeks of the main shock. Teleseismic body-wave modelling yields the following source parameters for the main shock: source depth of 25 ± 2 km, a normal fault orientation, with a horizontal tension axis striking NE-SW and an almost vertical pressure axis (Nodal Plane I: strike 126°–142°, dip 63°–66°, and rake 280°–290°; Nodal Plane II: strike 273°–289°, dip 28°–31°, and rake 235°–245°), a scalar moment of 4.1 times 10¹⁷ N m, and a 2 s impulsive source time function. Four of the largest aftershocks also nucleated at depths of 25 km, as deduced from regional sPmp–Pmp times. The nodal planes are broadly consistent with the orientation of both the Lupa and Ufipa faults, which bound the Rukwa rift to the northeast and southwest, respectively. The rupture radius of the main shock, assuming a circular fault, is estimated to be 4 km with a corresponding stress drop of 6.5 MPa. Published estimates of crustal thickness beneath the Rukwa rift indicate that the foci of the main shock and aftershocks lie at least 10 km above the Moho. The presence of lower-crustal seismicity beneath the Rukwa rift suggests that the pre-rift thermal structure of the rifted crust has not been strongly modified by the rifting, at least to depths of 25 km.  相似文献   

Secondary ferrimagnetic minerals in Welsh soils: a comparison of mineral magnetic detection methods and implications for mineral formation   总被引：20，自引：0，他引：20  

J. A. Dearing  P. M. Bird  R. J. L. Dann  S. F. Benjamin 《Geophysical Journal International》1997,130(3):727-736

A study of mineral magnetic parameters was carried out on a Late Pleistocene and Holocene sedimentary sequence (of nearly 18 m) from Lake Bledowo (central Poland). Sediments of Lake Bledowo have already been analysed for bulk sediment mineralogy and biogenic materials. The mineral magnetic stratigraphy confirms the major changes in palaeo-environmental conditions that have been deduced from other methods. The most important mineral magnetic change results from the authigenetic formation of ferrimagnetic greigite, Fe₃S₄, during the beginning of lacustrine conditions (± 12 000 yr BP). Our data also indicate a detrital origin of overlying ferrimagnetic iron oxides. It is suggested that they originate from brown soils developed on the boulder clay constituting the west side of the lake shore. Variations of ferrimagnetic iron oxide size are related to the early diagenetic processes in the sediment. Larger particles are present in periods with early diagenesis of organic matter in anoxic conditions. This indicates the dissolution of fine magnetic particles by iron-oxide-reducing bacteria and results in homogeneous magnetic grain sizes, despite their origin from soils, characterized by a multimodal grain-size distribution.  相似文献   

Convergent flow of ice within the Astrolabe subglacial basin, Trre Adélie, East Antarctica: an hypothesis derived from nummerical modelling experiments     

MARTIN J. SIEGERT  NEIL F. GLASSER 《Polar research》1997,16(1):63-72

The existence of a large subglacial lake beneath the antarctic Ice Sheet at Terre Adélie indicates the presence of basal ice at its pressure-melting temperature. A numerical model of the ice-sheet thermal regime is employed using the balance velocity of the ice sheet as an initial model input in order to calculate ice-sheet basal temperatures. However, the results from this model show the Terre Adélie area to be characterised by basal freezing. Heat in addition to that accounted for in the model is thus required at the ice-sheet base in order for pressure melting temperatures to be attained. The sources for such heat are (1) an enhanced geothermal heat flux and (2) an increase in frictional heating caused by the flow of ice. In this paper the latter possibility is expanded by hypothesising that subglacial topography induces convergent ice flow around Terre Adélie, causing enhanced basal ice velocities. Model experiments indicate that an increase in ice velocity (from 7 to at least 42 m yr⁻¹) is required to raise the temperature of the basal ice to the pressure melting value. Increased ice velocity, and consequent frictional heat production due to convergent ice flow, may therefore be important in explaining the location of the subglacial lake in this region. These results allow the process of convergent ice flow within a contemporary ice sheet to be quantified. A verification (or otherwise) of the model results may be possible if ice surface velocity measurements from modem GPS methods are made.  相似文献