Suction-controlled experiments on Boom clay     

F. Bernier  G. Volckaert  E. Alonso  M. Villar 《Engineering Geology》1997,47(4):135-338

The understanding of the thermo-hydro-mechanical behaviour of a clay barrier is needed for the prediction of its final in situ properties after the hydration and thermal transient in a radioactive waste repository.

As part of the CEC 1990–1994 R&D programme on radioactive waste management and storage, the CEA (Fr), CIEMAT (Sp), ENRESA (Sp), SCK · CEN (B), UPC (Sp) and UWCC (UK) have carried out a joint project on unsaturated clay behaviour (Volckaert et al., 1996). The aim of the study is to analyse and model the behaviour of a clay-based engineered barrier during its hydration phase under real repository conditions. The hydro-mechanical and thermo-hydraulic models developed in this project have been coupled to describe stress/strain behaviour, moisture migration and heat transfer. A thermo-hydraulic model has also been coupled to a geochemical code to describe the migration and formation of chemical species.

In this project, suction-controlled experiments have been performed on Boom clay (B), FoCa clay (Fr) and Almeria bentonite (Sp). The aim of these experiments is to test the validity of the interpretive model developed by Alonso and Gens (Alonso et al., 1990), and to build a database of unsaturated clay thermo-hydro-mechanical parameters. Such a database can then be used for validation exercises in which in situ experiments are simulated.

The Boom clay is a moderately swelling clay of Rupellian age. It is studied at the SCK · CEN in Belgium as a potential host rock for a radioactive waste repository. In this paper, suction-controlled experiments carried out on Boom clay by SCK · CEN are described. SCK · CEN has performed experiments to measure the relation between suction, water content and temperature and the relation between suction, stress and deformation. The applied suction-control techniques and experimental setups are detailed. The results of these experiments are discussed in the perspective of the model of Alonso and Gens. The influence of temperature on water uptake was rather small. The measured swelling-collapse behaviour can be explained by the Alonso and Gens model.  相似文献   

Interparticle forces and displacements in granular materials   总被引：1，自引：0，他引：1  

F. Emeriault  C. S. Chang 《Computers and Geotechnics》1997,20(3-4):223-244

In a micromechanics framework, the main issue is the relationship between the microscale variables and the macroscale variables. These variables are used to describe either the statics or kinematics of the system. The relationships can be classified in two ways, namely, the “averaging” relationships and the “tracking” relationships. The averaging relationships express the macroscale variable as an averaging of the microscale variables; for example, the stress as a function of contact forces. The “tracking” relationships express the microscale variable as a function of the macroscale variables; for example, the contact force at a given orientation as a function of the stress. Based on fundamental premises, a unique averaging relationship exists for either the statics or the kinematics case. However, it is generally impossible to have a unique expression of the “tracking” relationship because they are generally derived with certain assumptions. In this paper, we will present expressions of the “tracking” based on three different approaches, namely, (1) energy conservation principle, (2) representation theory, and (3) indirect scheme. The assumptions used in each approach are discussed. The results are compared among the three approaches as well as that obtained from the Discrete Element Method (DEM).  相似文献   

Mineral inclusions in diamonds from the Sputnik kimberlite pipe, Yakutia   总被引：9，自引：0，他引：9  

N. V. Sobolev  F. V. Kaminsky  W. L. Griffin  E. S. Yefimova  T. T. Win  C. G. Ryan  A. I. Botkunov 《Lithos》1997,39(3-4):135-157

The Sputnik kimberlite pipe is a small “satellite” of the larger Mir pipe in central Yakutia (Sakha), Russia. Study of 38 large diamonds (0.7-4.9 carats) showed that nine contain inclusions of the eclogitic paragenesis, while the remainder contain inclusions of the peridotitic paragenesis, or of uncertain paragenesis. The peridotitic inclusion suite comprises olivine, enstatite, Cr-diopside, chromite, Cr-pyrope garnet (both lherzolitic and harzburgitic), ilmenite, Ni-rich sulfide and a Ti-Cr-Fe-Mg-Sr-K phase of the lindsleyite-mathiasite (LIMA) series. The eclogitic inclusion suite comprises omphacite, garnet, Ni-poor sulfide, phlogopite and rutile. Peridotitic ilmenite inclusions have high Mg, Cr and Ni contents and high Nb/Zr ratios; they may be related to metasomatic ilmenites known from peridotite xenoliths in kimberlite. Eclogitic phlogopite is intergrown with omphacite, coexists with garnet, and has an unusually high TiO₂ content. Comparison with inclusions in diamonds from Mir shows general similarities, but differences in details of trace-element patterns. Large compositional variations among inclusions of one phase (olivine, garnet, chromite) within single diamonds indicate that the chemical environment of diamond crystallisation changed rapidly relative to diamond growth rates in many cases. P-T conditions of formation were calculated from multiphase inclusions and from trace element geothermobarometry of single inclusions. The geotherm at the time of diamond formation was near a 35 mW/m² conductive model; that is indistinguishable from the Paleozoic geotherm derived by studies of xenoliths and concentrate minerals from Mir. A range of Ni temperatures between garnet inclusions in single diamonds from both Mir and Sputnik suggests that many of the diamonds grew during thermal events affecting a relatively narrow depth range of the lithosphere, within the diamond stability field. The minor differences between inclusions in Mir and Sputnik may reflect lateral heterogeneity in the upper mantle.  相似文献   

Nitrogen isotope indicators of seasonal source variability to groundwater   总被引：5，自引：0，他引：5  

M. Z. Iqbal  N. C. Krothe  R. F. Spalding 《Environmental Geology》1997,32(3):210-218

 A nitrogen isotope study of soil water and groundwater in southern Indiana, USA, in 1991–1992 demonstrated considerable variations in nitrate degradation processes compared to an earlier investigation in 1986–1987. Although N-fertilizers were applied in May 1991, the δ¹⁵N values in soil water decreased in February 1992, indicating its delayed release into the system after substantial rainfall. The δ¹⁵N values of groundwater decreased from +12.3‰ in November 1991 to +11.3‰ in February 1992, and to +7.5‰ in March 1992. The increased residence time of nitrate in the soil resulted in increased denitrification, ammonia volatilization and plant uptake, and reduced threat to the groundwater quality. The 1986–1987 study in the area reported that excessive rainfall during the summer rapidly transported the nitrate to deeper horizons and drastically reduced volatilization and microbial reduction of nitrate, thus increasing the immediate threat to the groundwater quality in the area. The present study demonstrated that nitrogen isotopic signatures can be used to determine the effects of local soil type, rainfall, and land-use practices on the fate of nitrate in the subsurface. Received: 18 February 1997 · Accepted: 17 June 1997  相似文献   

Geochemistry and petrogenesis of Sikait leucogranite, Egypt: an example of S-type granite in a metapelitic sequence   总被引：1，自引：0，他引：1  

F. H. Mohamed  M. A. Hassanen 《International Journal of Earth Sciences》1997,86(1):81-92

 The Sikait leucogranite (SLG) is a body of porphyritic garnet granite intruded a metapelitic sequence and interlayered orthogneisses. Multiple deformation and low- to medium-grade metamorphism of the sequence was closely associated with pluton emplacement. Textural features of the SLG indicate that subsolidus plastic deformation was induced during the extensive thrusting. The granite is strongly peraluminous, alkali-rich and HFS (high field-strength) elements-depleted with low contents of REE, all facts that substantiate the geochemical characteristics of S-type granites. The geologic and geochemical features are consistent with a dehydration melting model of the hosted metapelites to generate the peraluminous SLG. However, geochemical modelling of trace elements and REEs suggest that the anatectic partial melt was subsequently affected by fractional crystallization of feldspars. This could explain much of the chemical attributes of SLG. Received: 20 September 1994 / Accepted: 2 August 1996  相似文献   

Hydrochemical Evolution of Sodium-Sulfate and Sodium-Chloride Groundwater Beneath the Northern Chihuahuan Desert, Trans-Pecos, Texas, USA   总被引：15，自引：1，他引：15  

R. Stephen Fisher  William F. Mullican  III 《Hydrogeology Journal》1997,5(2):4-16

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The economic mineral potential of the mid-Proterozoic Waterberg Group, northwestern Kaapvaal craton, South Africa     

P. G. Eriksson  B. F. F. Reczko  C. C. Callaghan 《Mineralium Deposita》1997,32(4):401-409

The 1900–1700 Ma Waterberg Group in the main Waterberg fault-bounded basin consists of dominantly coarse siliciclastic red beds with minor volcanic rocks. The sedimentary rocks were deposited mainly by alluvial fans, fluvial braidplains and transgressive shallow marine environments, with lesser lacustrine and aeolian settings. Uplifted, largely granitic source areas were located along the Thabazimbi-Murchison lineament (TML) fault system in the south, and along the Palala shear zone in the northeast. Palaeoplacer titanomagnetite-ilmenite-zircon heavy mineral deposits, best developed in the Cleremont Formation in the centre of the basin, reflect initial fluvial reworking and subsequent littoral marine concentration. Coarse alluvial cassiterite placer deposits are found in the Gatkop area in the southwest of the basin, and appear to have been derived from stanniferous Bushveld Complex lithologies south of the TML. Hydrothermal zinc and U-Cu mineralisation in the Alma lithologies in the same area appears to be related to the TML fault system. Small manganese deposits and anomalous tungsten values occur in the south of the basin, where they are again closely spatially associated with the TML. Copper-barium mineralisation is found associated with dolerite dykes, and in stratigraphically controlled, inferred syngenetic settings. The most interesting of these apparently syngenetic occurrences is found within green coloured reduced mudrocks and inferred volcanic rocks, at an unconformity developed within the overall red bed sequence of the Waterberg Group, adjacent to the TML in the southwest of the basin. The most important potential mineralisation in the main Waterberg basin thus encompasses shoreline placer Ti and the possibility of substantial sediment-hosted copper deposits. Received: 31 May 1996 / Accepted: 17 February 1997  相似文献   

New mineral data from the kamafugitecarbonatite association: The melilitolite from Pian di Celle, Italy     

F. Stoppa  V. V. Sharygin  A. Cundari 《Mineralogy and Petrology》1997,61(1-4):27-45

Summary A detailed mineralogical investigation of a Pian di Celle sill rock (San Venanzo, Italy), classified asmelilitolite and associated withvenanzite and carbonatitic pyroclasts, revealed new and rare mineral parageneses, considered as characteristic of thekamafugite-carbonatite association. These are formed by several accessory minerals, including minerals of the cuspidine family, götzenite, khibinskite, minerals of the rhodesite- delhayelite- macdonaldite family, pyrrhotite, bartonite and (Fe, Ni, Co) monoarsenide, mostly optically and chemically identified also in fluid inclusions. The chemical composition of these minerals and their probable crystallisation succession, deduced from textural relationships, demonstrates extensive atomic substitutions, notably for Ca, Ti, Mg and alkali, essentially reflecting high concentrations of REE, Sr, Ba, Nb and Zr, which significantly varied during crystallisation. Molecular alkali excess over Al and high Ca content in (H₂O, F, CO₂)-rich, Siundersaturated liquid(s) are considered the dominant factors in controlling the stability of disilicate-type minerals. Separation of the carbonatite liquid from the silicate magma, constrained by textural and fluid inclusion data, was fundamental in moving the residuum onto a strongly peralkaline trend which stabilised the sulphides under changed redox conditions.

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Die Bedeutung seltener und neuer Mineral-Paragenesen aus der kamafugit-karbonatit-Assoziation: Der melilitolit von San Venanzo, Italien

Zusammenfassung Eine eingehende mineralogische Untersuchung eines Lagerganges von Pian di Celle, der als Melilitolit klassifiziert and mit Venanzit and karbonatitischen Pyroklasten assoziiert ist, ergab neue and seltene Mineral-Paragenesen, die als charakteristisch für die Kamafugit-Karbonatit-Assoziation gelten. Diese bestehen aus verschiedenen akzessorischen Mineralien, darunter Perovskit, Cuspidin, Götzenit, Khibinskit, Delhayelit, Macdonaldit, Bardonit and (Fe, Ni, Co) Monoarsenit; diese werden in Flüssigkeitseinschlüssen mit optischen and chemischen Methoden identifiziert. Die chemische Zusammensetzung dieser Minerale and ihre wahrscheinliche Kristallisationsabfolge, aus texturellen Beziehungen abgeleitet, zeigt extensive Substitutionen, vor allem für Ca, Ti, Mg and Alkelien, die im wesentlichen hohe Gehalte an SEE, Sr, Ba, Mb and Zr andeuten, die während der Kristallisation beträchtlichen Schwankungen unterlagen. Molekularer Alkali überschuß über Al in (H₂O, F, CO₂)-reichen Si-untersättigten Fluiden werden als wichtigste Faktoren für die Stabilität von Mineralen des DisilikatTyps gesehen. Trennung des Karbonatites vom Silikat, die durch texturelle und Flüssigkeitseinschluß-Daten genau fixiert werden konnte, war wichtig für die Verschiebung des Residuums auf einen deutlich peralkalinen Trend, welcher die Sulfide unter veränderten Redox-Bedingungen stabilisieren konnte.

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With 2 Figures  相似文献   

Geochemical exploration for platinum-group elements in the Bushveld Complex, South Africa   总被引：2，自引：0，他引：2  

H. J. Wilhelm  H. Zhang  F. L. Chen  J. H. Elsenbroek  M. Lombard  D. de Bruin 《Mineralium Deposita》1997,32(4):349-361

Analyses of stream sediment and soil samples from the Bushveld Complex, South Africa have revealed enhanced precious metal concentrations, which can be related both to mining activities and the presence of hidden concentrations of platinum-group elements (PGEs) and gold. The economically important PGE deposits hosted by the Upper Critical Zone of the Rustenburg Layered Suite are revealed by a high PGE and Au content in the overlying soils. A second zone of elevated precious metal concentrations straddles the boundary between the Main and Upper Zones and has to date been traced for more than 100 km. This zone follows the igneous layering of the Rustenburg Layered Suite and is offset by the Brits Graben. It is therefore thought to be the reflection of a magmatic PGE-Au mineralisation. Received: 31 May 1996 / Accepted: 7 January 1997  相似文献   

Quantitative methods in the earth sciences     

A. F?rster  D. F. Merriam 《Mathematical Geology》1997,29(2):315

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