Where Does the Ground Water in Small Watersheds Come From?     

Thomas C. Winter  Donald O. Rosenberry  James W. LaBaugh 《Ground water》2003,41(7):989-1000

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An Environmentally Friendly Decontamination Protocol for Ground Water Sampling Devices     

Louise V. Parker  Thomas A. Ranney 《Ground Water Monitoring & Remediation》2003,23(2):84-91

Several detergent-washing/air-drying decontamination protocols were tested to determine their ability to remove residual contamination from two types of ground water sampling devices. We tested a relatively simply constructed device, a bailer, and a much more complex, and theoretically more difficult to decontaminate, bladder pump. The devices were decontaminated after sampling ground water that was contaminated with organics that varied in their hydrophobic nature and propensity to be sorbed by the materials in the devices. These studies showed that a hot-detergent wash, hot-water rinse, and hot-air drying protocol was effective.  相似文献   

Sedimentary facies during early stages of flooding in an extensional basin: the Brèche Rouge de Carboneras (Late Miocene, Almería/SE Spain)     

Uwe M. R. Krautworst  Thomas C. Brachert 《International Journal of Earth Sciences》2003,92(4):610-623

The intramontane basins of the Betic Cordilleras (SE Spain) formed subsequent to the main phase of orogenic deformation during the middle Miocene in a close genetic relation to the Trans-Alboran Shear zone. Left lateral movements along a local branch (Carboneras fault zone, CF; strike NE–SW) of this zone played a major role in controlling the formation and dynamics of the Nijar-Carboneras Basin. To the south of the fault, a major phase of strike-slip faulting is recorded during the late Tortonian. The expression of this event is the Brèche Rouge de Carboneras (BRC), which seals a deep denudational surface on top of dislocated fault blocks formed by volcanics of the Cabo de Gata complex and early Tortonian shallow marine calcarenite. The sedimentary facies of this widely distributed unit in the Carboneras-Subbasin mirror the submarine topography and the distribution of the fault zones. Along strike-slip fault zones, autoclastic breccias and neptunian dikes preferentially oriented NW–SE and NE–SW occur, which are interpreted to represent the near-surface expression of the faults. Red limestone forms the groundmass of the autoclastic breccia and infills of neptunian dikes, which exhibit multiple phases of opening of fissures, gravitational sedimentary infill, lithification, and renewed creation of cracks. Steep relief, probably along fault scarps, was mantled by epiclastic volcanic conglomerate with a red carbonate matrix. Well-lithified coarse skeletal limestone rich in planktonic foraminifera formed pavements along sediment starved rocky surfaces in deep water. Laterally, within topographic depressions, the pavement limestone grades into thick accumulations of skeletal rudstone composed of fragmented azooxanthellate corals and stylasterid hydrozoans, which were concentrated by powerful bottom currents and gravitiy flows. Within the shallow water zone of dip slope ramps, cross-bedded calcarenite and calcirudite formed. Based on textures, fabrics and biota, rocks of the BRC were grouped into nine genetic lithofacies which document cryptic, deep-aphotic and shallow-photic environments typical of a sediment starved extensional basin.  相似文献   

The Mobility of Rare Earth Elements and Redox Sensitive Elements in the Groundwater/Seawater Mixing Zone of a Shallow Coastal Aquifer   总被引：1，自引：0，他引：1  

Thomas Duncan  Timothy J. Shaw 《Aquatic Geochemistry》2003,9(3):233-255

The concentrations of Rare Earth Elements (REE) and Redox Sensitive Elements (RSE) were measured in groundwaters along a transect of the forest-marsh interface of a surficial aquifer system in North Inlet, SC. The well transect extended from a forest recharge area across the marsh and tidal creek to a tidal recharge area of beach ridge. The concentrations of the RSE (Fe, Mn, and U) were consistent with reducing conditions through the transect. Fe was present at concentrations ranging from a few micromolar to greater than one hundred micromolar in most wells. U was depleted with respect to salinity predicted concentrations, indicating removal with respect to the seawater endmember. Dissolved Mn concentrations were generally low in all wells, indicating no significant solid source of Mn (as MnOx) in this system. When extrapolated to a global scale, estimates of U removal during seawater exchange with the aquifer solids equaled 10–20% of the total riverine dissolved U input flux. REE concentrations in the forest recharge area were high in shallow wells, and showed a light enriched fractionation pattern, characteristic of soil leaching by Natural Organic Matter (NOM) rich waters. A decrease in REE concentration with depth in the forest wells coupled with a trend towards Heavy REE (HREE) enriched fractionation pattern indicated removal of the REE coincident with NOM and Dissolved Organic Carbon (DOC) removal. The saline waters of the beach ridge wells show a Light REE (LREE) enriched fractionation pattern and have the highest overall concentrations of the REE, indicating a significant REE source to the seawater endmember waters. The concentration gradients along the beach ridge flow path indicate a large source in the deep wells, and net export of dissolved REE to the tidal creek system and the coastal ocean. Ultrafiltration experiments indicate a transition from a colloidal dominated reservoir for the REE in the forest wells to a colloidal and dissolved reservoir in the beach ridge wells. The ultrafiltration data coupled with a correlation with Dissolved Inorganic Carbon (DIC) release suggest that there is diagenetic mobilization of an REE rich organic carbon phase in the saline endmember wells. We suggest here that degradation of this relic terrestrial organic carbon and REE rich phase results in the export of dissolved REE equal to or exceeding river inputs in this region.  相似文献   

Reply to Baker and Genty’s comments on “A test of annual resolution in stalagmite using tree rings”     

Julio L. Betancourt  Henri D. Grissino-Mayer  Matt W. Saltzer  Thomas W. Swetnam 《Quaternary Research》2003,59(3):479

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Structural, chemical, and isotopic microanalytical investigations of graphite from supernovae     

T.Kevin Croat  Thomas Bernatowicz  Scott Messenger 《Geochimica et cosmochimica acta》2003,67(24):4705-4725

We report the results of coordinated ion microprobe and transmission electron microscope (TEM) studies of presolar graphites from the KE3 separate (1.65-1.72 g/cm³) of the Murchison CM2 meteorite. Isotopic analysis of individual graphites (1-12 μm) with the ion microprobe shows many to have large ¹⁸O excesses combined with large silicon isotopic anomalies, indicative of a supernova (SN) origin. Transmission electron microscopy (TEM) of ultramicrotome slices of these SN graphites revealed a high abundance (25-2400 ppm) of internal titanium carbides (TiCs), with a single graphite in some cases containing hundreds of TiCs. Isotopic compositions of individual TiCs by nanoscale resolution secondary ion mass spectrometry (NanoSIMS) confirmed their presolar origin. In addition to TiCs, composite TiC/Fe grains (TiCs with attached iron-nickel subgrains) and solitary kamacite internal grains were found. In the composite grains, the attached iron phase (kamacite [0-24 at. % Ni] or taenite [up to 60 at. % Ni]) was epitaxially grown onto one or more TiC faces. In contrast to the denser Murchison KFC1 graphites, no Zr-Ti-Mo carbides were observed. The average TiC diameters were quite variable among the SN graphites, from 30 to 232 nm, and were generally independent of the host graphite size. TiC grain morphologies ranged from euhedral to anhedral, with the grain surfaces exhibiting variable degrees of corrosion, and sometimes partially amorphous rims (3 to 15 nm thick). Partially amorphous rims of similar thickness were also observed on some solitary kamacite grains. We speculate that the rims on the internal grains are most plausibly the result of atom bombardment caused by drift of grains with respect to the ambient gas, requiring relative outflow speeds ∼100 km/s (i.e., a few percent of the SN mass outflow speed).Energy dispersive X-ray spectrometry (EDXS) of TiCs revealed significant V in solid solution, with an average V/Ti ratio over all TiCs of ∼83% of the solar value of 0.122. Significant variations about the mean V/Ti ratio were also seen among TiCs in the same graphite, likely indicating chemical equilibration with the surrounding gas over a range of temperatures. In general, the diversity in internal TiC properties suggests that TiCs formed first and had substantially diverse histories before incorporation into the graphite, implying some degree of turbulent mixing in the SN outflows.In most graphites, there is a decrease in the number density of TiCs as a function of increasing radial dis- tance, caused by either preferential depletion of TiCs from the gas or an acceleration of graphite growth with decreasing ambient temperature. In several graphites, TiCs showed a trend of larger V/Ti ratios with increasing distance from the graphite center, an indication of progressive equilibration with the surrounding gas before they were sequestered in the graphites. In all but one graphite, no trend was seen in the TiC size vs. distance from the graphite center, implying that appreciable TiC growth had effectively stopped before the graphites formed, or else that graphite growth was rapid compared to TiC growth. Taken together, the chemical variations among internal grains as well as the presence of partially amorphous rims and epitaxial Fe phases on some TiCs clearly indicate that the phase condensation sequence was TiC, followed by the iron phases (only found in some graphites) and finally graphite. Since graphite typically condenses at a higher temperature than iron at low pressures (<10⁻³ bars) in a gas with C > O and otherwise solar composition, the observed condensation sequence implies a relative iron enrichment in the gas or greater supersaturation of graphite relative to iron.The TEM observations allow inferences to be made about the physical conditions in the gas from which the grains condensed. Given the TiC sizes and abundances, the gas was evidently quite dusty. From the observed TiC size range of ∼20 nm to ∼500 nm (assuming ∼1 yr growth time and T ∼ 1800°K), we infer minimum Ti number densities in the gas to be ∼7 × 10⁴ to ∼2 × 10⁶ atoms/cc, respectively. Although the gas composition is clearly not solar, for scale, these number densities would correspond to a pressure range of ∼0.2 μbar to ∼5.0 μbar in a gas of solar composition. They also correspond to minimum TiC grain number densities of ∼3 × 10⁻⁴ to ∼0.2 grains/cc, assuming complete condensation of Ti in TiC. We estimate the maximum ratio of mean TiC grain separation distance in the gas to grain diameter from the Ti number densities as ∼3 × 10⁵ to ∼1 × 10⁶.  相似文献   

Formation of meteorite hydrocarbons from thermal decomposition of siderite (FeCO₃)     

Thomas M. McCollom 《Geochimica et cosmochimica acta》2003,67(2):311-317

Thermal decomposition of siderite has been proposed as a source of magnetite in martian meteorites. Laboratory experiments were conducted to evaluate the possibility that this process might also result in abiotic synthesis of organic compounds. Siderite decomposition in the presence of water vapor at 300°C generated a variety of organic products dominated by alkylated and hydroxylated aromatic compounds. The results suggest that formation of magnetite by thermal decomposition of siderite on the precursor rock of the martian meteorite ALH84001 would have been accompanied by formation of organic compounds and may represent a source of extraterrestrial organic matter in the meteorite and on Mars. The results also suggest that thermal decomposition of siderite during metamorphism could account for some of the reduced carbon observed in metasedimentary rocks from the early Earth.  相似文献   

A late quaternary record of eolian silt deposition in a maar lake, St. Michael Island, western Alaska     

Daniel R Muhs  Thomas A AgerJosh Been  J.Platt BradburyWalter E Dean 《Quaternary Research》2003,60(1):110-122

Recent stratigraphic studies in central Alaska have yielded the unexpected finding that there is little evidence for full-glacial (late Wisconsin) loess deposition. Because the loess record of western Alaska is poorly exposed and not well known, we analyzed a core from Zagoskin Lake, a maar lake on St. Michael Island, to determine if a full-glacial eolian record could be found in that region. Particle size and geochemical data indicate that the mineral fraction of the lake sediments is not derived from the local basalt and is probably eolian. Silt deposition took place from at least the latter part of the mid-Wisconsin interstadial period through the Holocene, based on radiocarbon dating. Based on the locations of likely loess sources, eolian silt in western Alaska was probably deflated by northeasterly winds from glaciofluvial sediments. If last-glacial winds that deposited loess were indeed from the northeast, this reconstruction is in conflict with a model-derived reconstruction of paleowinds in Alaska. Mass accumulation rates in Zagoskin Lake were higher during the Pleistocene than during the Holocene. In addition, more eolian sediment is recorded in the lake sediments than as loess on the adjacent landscape. The thinner loess record on land may be due to the sparse, herb tundra vegetation that dominated the landscape in full-glacial time. Herb tundra would have been an inefficient loess trap compared to forest or even shrub tundra due to its low roughness height. The lack of abundant, full-glacial, eolian silt deposition in the loess stratigraphic record of central Alaska may be due, therefore, to a mimimal ability of the landscape to trap loess, rather than a lack of available eolian sediment.  相似文献   

Book Review: Experiments: Planning,Analysis, and Parameter Design Optimization. By C. F. Jeff Wu and Michael Hamada. John Wiley & Sons,Inc., New York, 2000, 630 p., U.S.$89.95 (hb), ISBN 0-471-25511-4     

Jones  Thomas A. 《Mathematical Geosciences》2003,35(2):227-229

Mathematical Geosciences -  相似文献   

A comparison of three image-object methods for the multiscale analysis of landscape structure   总被引：4，自引：0，他引：4  

Geoffrey J. Hay  Thomas Blaschke  Danielle J. Marceau  Andr Bouchard 《ISPRS Journal of Photogrammetry and Remote Sensing》2003,57(5-6):327

Within the conceptual framework of Complex Systems, we discuss the importance and challenges in extracting and linking multiscale objects from high-resolution remote sensing imagery to improve the monitoring, modeling and management of complex landscapes. In particular, we emphasize that remote sensing data are a particular case of the modifiable areal unit problem (MAUP) and describe how image-objects provide a way to reduce this problem. We then hypothesize that multiscale analysis should be guided by the intrinsic scale of the dominant landscape objects composing a scene and describe three different multiscale image-processing techniques with the potential to achieve this. Each of these techniques, i.e., Fractal Net Evolution Approach (FNEA), Linear Scale-Space and Blob-Feature Detection (SS), and Multiscale Object-Specific Analysis (MOSA), facilitates the multiscale pattern analysis, exploration and hierarchical linking of image-objects based on methods that derive spatially explicit multiscale contextual information from a single resolution of remote sensing imagery. We then outline the weaknesses and strengths of each technique and provide strategies for their improvement.  相似文献