Fate and Transport of Pharmaceuticals and Endocrine Disrupting Compounds During Ground Water Recharge     

Robert W. Masters  Ingrid M. Verstraeten  Thomas Heberer 《Ground Water Monitoring & Remediation》2004,24(2):54-57

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Genetic relationship of rift-stage crustal structure, terrane accretion, and foreland tectonics along the southern Appalachian-Ouachita orogen     

William A. Thomas 《Journal of Geodynamics》2004,37(3-5):549

Abrupt along-strike variations in tectonostratigraphic composition, internal structural style, and detachment level in the southern Appalachian and Ouachita foreland thrust belts are defined at a large-scale bend in strike and a truncation of Ouachita structures by the frontal Appalachian thrust fault. The along-strike variations correspond to differences in the pre-orogenic rifted Laurentian margin, in the history and nature of terrane accretion, and in the response of the foreland to these differences. Within the Ouachita embayment of the Laurentian margin, diachronous arc-continent collision migrated northwestward along a rift-stage transform margin from the Black Warrior foreland basin on the southeast in Late Mississippian time to a short-wavelength, high-amplitude foreland basin (Arkoma basin) on the northwest in front of the Ouachita thrust-belt salient in Early-Middle Pennsylvanian time. Off-shelf, deep-water strata of both passive-margin and synorogenic facies comprise an accretionary prism and subduction complex, and the Ouachita allochthon consists of mud-dominated thrust sheets that are internally disharmonic and folded. The allochthon of off-shelf strata was thrust over the passive-margin carbonate shelf, which remains in the Ouachita footwall. Along the southeast side of the Alabama promontory of the Laurentian margin, passive-margin shelf carbonates are imbricated in the Appalachian thrust belt, which is characterized by internally coherent thrust sheets and high-amplitude frontal ramps. The palinspastic extent of shelf-carbonate rocks corresponds to the extent of structurally shallow basement rocks on the upper-plate rift-stage margin of the Alabama promontory of Laurentian crust. Terranes accreted to the Laurentian margin during the Taconic and Acadian orogenies were driven over the shallow basement by continent-continent collision of Laurentia with Africa (Gondwana). Emplacement of the thrust-translated terranes tectonically stripped and replaced the shelf carbonate. The frontal thrust fault of the Appalachian thrust belt truncates the southeastern end of the slightly older frontal Ouachita thrust belt, as well as the southeastern part of the greater Black Warrior basin in the Ouachita foreland. Shallow basement beneath the Appalachian thrust belt extends cratonward beneath the low-amplitude Appalachian foreland basin.  相似文献   

Lake Koronia, Greece: Shift from autotrophy to heterotrophy with cultural eutrophication and progressive water-level reduction     

Chrysoula Mitraki  Thomas L. Crisman  George Zalidis 《Limnologica》2004,34(1-2):110

Lake Koronia, a Ramsar site, is shallow, polymictic, hypertrophic and until recently was aerially the fourth largest lake in Greece. Although exceeding 5 m in the past, lake depth has declined progressively from 3.8 m in 1980 to < 1 m in 1997, reducing surface area and water volume by 50% and 80%, respectively. Specific conductivityincreased from 1300 μS cm⁻¹ in 1977 to >6000 μS cm⁻¹ in 1991. Increased phosphate concentrations from the late 1970's (8–45 μg L⁻¹) to the late 1990's (100–1000 μg L⁻¹) document that the previously eutrophic system with a limited littoral zone switched to hypertrophy dominated by massive cyanobacteria blooms. Oxygen saturation of the water column increased progressively from about 80% in 1983 to full saturation about 1993, after which it decreased progressively to only 20% saturation in 1997. In spite of cyanobacteria dominance, community metabolism of the lake switched from progressively increasing autotrophy to rapidly advancing heterotrophy associated with progressive water-level reduction leading to fish extirpation in the lake.  相似文献   

Sampling Fauna in Stream Sediments as well as Groundwater Using One Net Sampler     

Susanne I. Schmidt  Hans J. Hahn  Gerald D. Watson  Robert J. Woodbury  Thomas J. Hatton 《洁净——土壤、空气、水》2004,32(2):131-137

Groundwater bores act as traps. Net samplers are regularly used for sampling this type of trap for fauna. To enable direct comparisons of faunal communities in groundwater bores and stream sediments, stream sediment tubes were built similar to groundwater bores and were sampled with net samplers for fauna. These stream sediment tubes consisted of a tube anchored in the stream sediment, also called interstitial space. To test the efficacy of this trap method in stream sediments, it was compared to another type of trap, Hahn's trap. Faunal communities sampled by a net in the stream sediment tubes did not differ hugely from fauna in Hahn's trap samples. Physical and chemical factors of sampled water in both the stream sediment tubes, the surrounding interstitial sediments and the second type of traps, Hahn's traps, showed that water in both the tubes and Hahn's traps was closely related to interstitial water. The net sampler is inexpensive and easy to handle. It is suggested that sampling stream tubes with nets may be an appropriate method for long‐term monitoring studies.  相似文献   

Book Review: Generalized Linear Models, With Applications in Engineering and the Sciences . By Raymond H. Myers, Douglas C. Montgomery, and G. Geoffrey Vining. John Wiley & Sons, Inc., New York, 2002, 342 p., US$90 (hardbound), ISBN 0-471-35573-9     

Thomas A. Jones 《Mathematical Geology》2004,36(3):399-401

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Book Review: Collecting Spatial Data: Optimum Design of Experiments for Random Fields (2nd Edition) . By Werner G. Müller. Physica-Verlag, Heidelberg, 2001, 196 p., US$63 (paperbound), ISBN 3-7908-1333-8     

Thomas A. Jones 《Mathematical Geology》2004,36(1):143-145

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Precise/ Small Sample Size Determinations of Lithium Isotopic Compositions of Geological Reference Materials and Modern Seawater by MC-ICP-MS   总被引：6，自引：1，他引：6  

Alistair B. Jeffcoate  Tim Elliott  Alex Thomas  Claudia Bouman 《Geostandards and Geoanalytical Research》2004,28(1):161-172

The Li isotope ratios of four international rock reference materials, USGS BHVO-2, GSJ JB-2, JG-2, JA-1 and modern seawater (Mediterranean, Pacific and North Atlantic) were determined using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). These reference materials of natural samples were chosen to span a considerable range in Li isotope ratios and cover several different matrices in order to provide a useful benchmark for future studies. Our new analytical technique achieves significantly higher precision and reproducibility (< ± O.3%o 2s) than previous methods, with the additional advantage of requiring very low sample masses of ca . 2 ng of Li.  相似文献   

Magmatic evolution of Li–F, rare-metal granites: a case study of melt inclusions in the Khangilay complex, Eastern Transbaikalia (Russia)     

E. V. Badanina  I. V. Veksler  R. Thomas  L. F. Syritso  R. B. Trumbull 《Chemical Geology》2004,210(1-4):113-133

We report compositions of homogenized quartz-hosted melt inclusions from a layered sequence of Li-, F-rich granites in the Khangilay complex that document the range of melt evolution from barren biotite granites to Ta-rich, lepidolite–amazonite–albite granites. The melt inclusions are crystalline at room temperature and were homogenized in a rapid-quench hydrothermal apparatus at 200 MPa before analysis. Homogenization runs determined solidus temperatures near 550 °C and full homogenization between 650 and 750 °C. The compositions of inclusions, determined by electron microprobe and Raman spectroscopy (for H₂O), show regular overall trends of increasing differentiation from the least-evolved Khangilay units to apical units in the Orlovka intrusion. Total volatile contents in the most-evolved melts reach over 11 wt.% (H₂O: 8.6 wt.%, F: 1.6 wt.%, B₂O₃: 1.5 wt.%). Concentrations of Rb range from about 1000 to 3600 ppm but other trace elements could not be measured reliably by electron microprobe. The resulting trends of melt evolution are similar to those described by the whole-rock samples, despite petrographic evidence for albite- and mica-rich segregations previously taken as evidence for post-magmatic metasomatism.

Melt variation trends in most samples are consistent with fractional crystallization as the main process of magma evolution and residual melt compositions plot at the granite minimum in the normative Qz–Ab–Or system. However, melts trapped in the highly evolved pegmatitic samples from Orlovka deviate from the minimum melt composition and show compositional variations in Al, Na and K that requires a different explanation. We suggest that unmixing of the late-stage residual melt into an aluminosilicate melt and a salt-rich dense aqueous fluid (hydrosaline melt) occurred. Experimental data show the effectiveness of this process to separate K (aluminosilicate melt) from Na (hydrosaline melt) and high mobility of the latter due to its low viscosity and relatively low density may explain local zones of albitization in the upper parts of the granite.  相似文献   

Holocene hydrographical changes of the eastern Laptev Sea (Siberian Arctic) recorded in δO profiles of bivalve shells     

Thomas Mueller-Lupp  Henning A. Bauch 《Quaternary Research》2004,61(1):32-41

Oxygen isotope profiles along the growth axis of fossil bivalve shells of Macoma calcarea were established to reconstruct hydrographical changes in the eastern Laptev Sea since 8400 cal yr B.P.. The variability of the oxygen isotopes (δ¹⁸O) in the individual records is mainly attributed to variations in the salinity of bottom waters in the Laptev Sea with a modern ratio of 0.50‰/salinity. The high-resolution δ¹⁸O profiles exhibit distinct and annual cycles from which the seasonal and annual salinity variations at the investigated site can be reconstructed. Based on the modern analogue approach oxygen isotope profiles of radiocarbon-dated bivalve shells from a sediment core located northeast of the Lena Delta provide seasonal and subdecadal insights into past hydrological conditions and their relation to the Holocene transgressional history of the Laptev Sea shelf. Under the assumption that the modern relationship between δ¹⁸O_w and salinity has been constant throughout the time, the δ¹⁸O of an 8400-cal-yr-old bivalves would suggest that bottom-water salinity was reduced and the temperature was slightly warmer, both suggesting a stronger mixture of riverine water to the bottom water. Reconstruction of the inundation history of the Laptev Sea shelf indicates local sea level ∼27 m below present at this time and a closer proximity of the site to the coastline and the Lena River mouth. Due to continuing sea level rise and a southward retreat of the river mouth, bottom-water salinity increased at 7200 cal yr B.P. along with an increase in seasonal variability. Conditions comparable to the modern hydrography were achieved by 3800 cal yr B.P.  相似文献   

Marine and limnic radiocarbon reservoir corrections for studies of late- and postglacial environments in Georgia Basin and Puget Lowland, British Columbia, Canada and Washington, USA     

Ian Hutchinson  Thomas S. James  Brian D. Bornhold 《Quaternary Research》2004,61(2):193-203

Models of late-glacial environmental change in coastal areas are commonly based on radiocarbon ages on marine shell and basal lake sediments, both of which may be compromised by reservoir effects. The magnitude of the oceanic reservoir age in the inland waters of the Georgia Basin and Puget Lowland of northwestern North America is inferred from radiocarbon ages on shell-wood pairs in Saanich Inlet and previously published estimates. The weighted mean oceanic reservoir correction in the early and mid Holocene is −720±90 yr, slightly smaller than, but not significantly different from, the modern value. The correction in late-glacial time is −950±50 yr. Valley-head sites yield higher reservoir values (−1200±130 yr) immediately after deglaciation. The magnitude of the gyttja reservoir effect is inferred from pairs of bulk gyttja and plant macrofossil ages from four lakes in the region. Incorporation of old carbon into basal gyttja yields ages from bulk samples that are initially about 600 yr too old. The reservoir age declines to less than 100 yr after the first millennium of lake development. When these corrections are accounted for, dates of deglaciation and late-glacial sea-level change in the study area are pushed forward in time by more than 500 yr.  相似文献