Drivers of interannual and intra‐annual variability of dissolved organic carbon concentration in the River Thames between 1884 and 2013     

Valentina Noacco  Christopher J. Duffy  Thorsten Wagener  Fred Worrall  Matteo Fasiolo  Nicholas J.K. Howden 《水文研究》2019,33(6):994-1012

The world's longest record of river water quality (River Thames—130 years) provides a unique opportunity to understand fluvial dissolved organic carbon (DOC) concentrations dynamics. Understanding riverine DOC variability through long‐term studies is crucial to capture patterns and drivers influencing sources of DOC at scales relevant for decision making. The Thames basin (United Kingdom) has undergone massive land‐use change, as well as increased urbanisation and population during the period considered. We aimed to investigate the drivers of intra‐annual to interannual DOC variability, assess the variability due to natural and anthropogenic factors, and understand the causes for the increased DOC variability over the period. Two approaches were used to achieve these aims. The first method was singular spectrum analysis, which was used to reconstruct the major oscillatory modes of DOC, hydroclimatic variables, and atmospheric circulation patterns and to visualise the interaction between these variables. The second approach used was generalised additive modelling, which was used to investigate other non‐natural drivers of DOC variability. Our study shows that DOC variability increased by 80% over the data period, with the greatest increase occurring from the beginning of World War II onwards. The primary driver of the increase in DOC variability was the increase in the average value of fluvial DOC over the period of record, which was itself linked to the increase in basin population and diffuse DOC sources to the river due to land‐use and land‐management changes. Seasonal DOC variability was linked to streamflow and temperature. Our study allows to identify drivers of fluvial intra‐annual and interannual DOC variability and therefore empowers actions to reduce high DOC concentrations.  相似文献   

Catchment similarity concepts for understanding dynamic biogeochemical behaviour of river basins          下载免费PDF全文

Stefan Krause  Jim Freer  David M. Hannah  Nicholas J. K. Howden  Thorsten Wagener  Fred Worrall 《水文研究》2014,28(3):1554-1560

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Estimating the regional climate responses over river basins to changes in tropical sea surface temperature patterns     

Chii-Yun Tsai  Chris E. Forest  Thorsten Wagener 《Climate Dynamics》2015,45(7-8):1965-1982

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Late Cretaceous extension overprinting a steep belt in the Northern Calcareous Alps (Schesaplana, R?tikon, Switzerland and Austria)     

Nikolaus Froitzheim  Sebastian Weber  Thorsten J. Nagel  Tobias Ibele  Heinz Furrer 《International Journal of Earth Sciences》2012,101(5):1315-1329

The Triassic to Cretaceous sediment succession of the Lechtal Nappe in the western part of the Northern Calcareous Alps (NCA) has been deformed into large-scale folds and crosscut by thrust and extensional faults during Late Cretaceous (Eoalpine) and Tertiary orogenic processes. The following sequence of deformation is developed from overprinting relations in the field: (D1) NW-vergent folds related to thrusting; (D2) N–S shortening leading to east–west-trending folds and to the formation of a steep belt (Arlberg Steep Zone) along the southern border of the NCA; (D3) E–W to NE–SW extension and vertical shortening, leading to low-angle normal faulting and recumbent “collapse folds” like the Wildberg Syncline. D1 and D2 are Cretaceous in age and predate the Eocene emplacement of the Austroalpine on the Penninic Nappes along the Austroalpine basal thrust; the same is probably true for D3. Finally, the basal thrust was deformed by folds related to out-of-sequence thrusting. These results suggest that the NCA were at least partly in a state of extension during the sedimentation of the Gosau Group in the Late Cretaceous.  相似文献   

Nanoparticles and their influence on radionuclide mobility in deep geological formations     

Thorsten Schäfer  Florian Huber  Holger Seher  Tiziana Missana  Ursula Alonso  Michael Kumke  Sascha Eidner  Francis Claret  Frieder Enzmann 《Applied Geochemistry》2012

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Complexation of aqueous elements by DOC in a clay aquitard   总被引：1，自引：0，他引：1  

Reszat TN  Hendry MJ 《Ground water》2007,45(5):542-553

The extent of partitioning of several elements (Cu, Mn, Mo, Ni, Sr, U, and Zn) on dissolved organic carbon (DOC) was investigated in pore water samples collected from a clay-rich aquitard. High DOC concentrations in the aquitard, ranging from 21 to 143 mg C/L, and natural aqueous metal concentrations higher than in most ground water environments facilitated complexation studies at this site. Analyses were conducted using on-line coupling of asymmetrical flow field-flow fractionation with ultraviolet, total organic carbon, and inductively coupled plasma-mass spectrometry detectors. Of the elements investigated, only U and Zn were complexed with all DOC samples, ranging from 2.2 to 60 microg U/g DOC (0.4% to 3% of the total U in the pore water) and 0.04 to 0.5 microg Zn/g DOC (0.1% to 0.9% of the total Zn in the pore water), respectively. Laboratory experiments conducted over a range in pH (1.3 to 9.7) and geochemical modeling supported the measured complexation of U and Zn on the DOC. The in situ association constant, K(d), for U decreased with depth from 76 mL/g C for pore water samples at 2.2 m below ground (BG) to 24 mL/g C at 9.7 m BG. The decrease was attributed to a decrease in aromaticity of the DOC with depth. Zn K(d)constants ranged from 2 to 12 mL/g C and exhibited no trend with depth. Results of the current study suggest minor masses of U and Zn (less than or equal to 4% of total) complex with this DOC under in situ pH conditions. Our data suggest that competitive complexation by other ligands may limit the importance of DOC-facilitated transport of the elements studied in water of similar chemical composition.  相似文献   

Double-barred galaxies at intermediate redshifts: a feasibility study     

Thorsten Lisker  Victor P. Debattista †  Ignacio Ferreras  Peter Erwin 《Monthly notices of the Royal Astronomical Society》2006,370(1):477-487

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A transitioning Arctic surface energy budget: the impacts of solar zenith angle, surface albedo and cloud radiative forcing     

Joseph Sedlar  Michael Tjernström  Thorsten Mauritsen  Matthew D. Shupe  Ian M. Brooks  P. Ola G. Persson  Cathryn E. Birch  Caroline Leck  Anders Sirevaag  Marcel Nicolaus 《Climate Dynamics》2011,37(7-8):1643-1660

Snow surface and sea-ice energy budgets were measured near 87.5°N during the Arctic Summer Cloud Ocean Study (ASCOS), from August to early September 2008. Surface temperature indicated four distinct temperature regimes, characterized by varying cloud, thermodynamic and solar properties. An initial warm, melt-season regime was interrupted by a 3-day cold regime where temperatures dropped from near zero to ?7°C. Subsequently mean energy budget residuals remained small and near zero for 1 week until once again temperatures dropped rapidly and the energy budget residuals became negative. Energy budget transitions were dominated by the net radiative fluxes, largely controlled by the cloudiness. Variable heat, moisture and cloud distributions were associated with changing air-masses. Surface cloud radiative forcing, the net radiative effect of clouds on the surface relative to clear skies, is estimated. Shortwave cloud forcing ranged between ?50 W m^?2 and zero and varied significantly with surface albedo, solar zenith angle and cloud liquid water. Longwave cloud forcing was larger and generally ranged between 65 and 85 W m^?2, except when the cloud fraction was tenuous or contained little liquid water; thus the net effect of the clouds was to warm the surface. Both cold periods occurred under tenuous, or altogether absent, low-level clouds containing little liquid water, effectively reducing the cloud greenhouse effect. Freeze-up progression was enhanced by a combination of increasing solar zenith angles and surface albedo, while inhibited by a large, positive surface cloud forcing until a new air-mass with considerably less cloudiness advected over the experiment area.  相似文献   

Polycrystalline apatite synthesized by hydrothermal replacement of calcium carbonates     

Argyrios Kasioptas  Thorsten Geisler  Christina Perdikouri  Nikolaus Gussone 《Geochimica et cosmochimica acta》2011,75(12):3486-202

Aragonite and calcite single crystals can be readily transformed into polycrystalline hydroxyapatite pseudomorphs by hydrothermal treatment in a (NH₄)₂HPO₄ solution. Scanning electron microscopy of the reaction products showed that the transformation of aragonite to apatite is characterised by the formation of a sharp interface between the two phases and by the development of intracrystalline porosity in the hydroxyapatite phase. In addition, electron backscattered diffraction (EBSD) imaging showed that the c-axis of apatite is predominantly oriented perpendicular to the reaction front with no crystallographic relationship to the aragonite lattice. However, the Ca isotopic composition of the parent aragonite, measured by thermal ionization mass spectrometry was inherited by the apatite product.Hydrothermal experiments conducted with use of phosphate solutions prepared with water enriched in ¹⁸O (97%) further revealed that the ¹⁸O from the solution is incorporated in the product apatite, as measured by micro-Raman spectroscopy. Monitoring the distribution of ¹⁸O with Raman spectroscopy was possible because the incorporation of ¹⁸O in the PO₄ group of apatite generates four new Raman bands at 945.8, 932, 919.7 and 908.8 cm⁻¹, in addition to the ν₁(PO₄) symmetric stretching band of apatite located at 962 cm⁻¹, which can be assigned to four ¹⁸O-bearing PO₄ species. The relative intensities of these bands reflect the ¹⁸O content in the PO₄ group of the apatite product. By using equilibrated and non-equilibrated solutions, with respect to the ¹⁸O distribution between aqueous phosphate and water, we could show that the concentration of ¹⁸O in the apatite product is linked to the degree of ¹⁸O equilibration in the solution. The textural and chemical observations are indicative of a coupled mechanism of aragonite dissolution and apatite precipitation taking place at a moving reaction interface.  相似文献   

Geomorphic knowledge for mangrove restoration: a pan‐tropical categorization          下载免费PDF全文

Thorsten Balke  Daniel A. Friess 《地球表面变化过程与地形》2016,41(2):231-239

Extreme events such as storm surges and tsunamis in combination with subsidence of densely populated coastal areas pose an increasing threat to millions of people in the tropics. Intertidal mangrove forests may form a natural protection against some extreme events, but have also widely been destroyed by coastal development. The establishment of mangroves and the maintenance of their stability over the short‐ to long‐term requires an understanding of sedimentary processes and landforms in the coastal zone, making geomorphology a crucial, but sometimes neglected discipline when attempting restoration for disaster risk reduction. Mangrove geomorphic setting varies markedly across the tropics, depending on abiotic parameters such as suspended sediment supply and tidal range, with different restoration strategies suitable for each. In this study we provide a global categorization of mangrove geomorphic settings, based on the literature and global remote sensing data. The world's mangroves can be broadly defined as: (1) minerogenic and high tidal range; (2) minerogenic and low tidal range; and (3) organogenic and low tidal range. We further discuss restoration and management approaches most suitable for each geomorphic setting. Overall, this study can be used to inform managers about the relevance of geomorphic knowledge for successful mangrove restoration, how an understanding of geomorphology can influence site selection and restoration success, and how to match specific restoration methods to the prevailing geomorphic context. The stronger incorporation of geomorphic knowledge into site planning and design will improve the success rates of restoration for this important and globally threatened ecosystem. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献