Synthesis and characterisation of a multifunctional oil-based drilling fluid additive     

Wu-Juan Sun  Guo-Qing Tian  Hang-Juan Huang  Guo-Min Lu  Cong-Yu Ke  Jun-Feng Hui  Xun-Li Zhang 《Environmental Earth Sciences》2018,77(24):793

An oil-based drilling fluid additive H-DEA (or humic acid-cocamide diethanolamine) was synthesised using humic acid and cocamide diethanolamine as raw materials. The rheological behaviors of H-DEA showed that the synthesised product has the good properties in both decreasing the filtrate loss and improving rheology property of oil-based drilling fluids compared with other commercially available additives. Under the optimal additive amount of 3%, both API filtrate loss and yield point changed remarkably from 5.40 to 0.41 mL and 9.0 to 25.6 Pa, respectively. Furthermore, differential scanning calorimetry (DSC) showed that H-DEA has good thermal stability in a wide temperature range up to 170 °C. Infrared spectroscopy (IR) and rheological analysis revealed that the possible mechanism of the multifunctional effects may be attributed to the existing of high density of strong polar groups, hydrogen bonds, electrostatic forces, and intermolecular association on H-DEA molecular structure. The results of the study showed that the synthesised H-DEA can be potentially used as a multifunctional oil-based drilling fluid additive in oil-drilling excavation.  相似文献   

The Study of Stream Sediment Geochemical Data Processing by Using <Emphasis Type="Italic">k</Emphasis>-Means Algorithm and Centered Logratio Transformation—an Example of a District in Hunan,China     

Mi Tian  Libo Hao  Xinyun Zhao  Jilong Lu  Yuyan Zhao 《Geochemistry International》2018,56(12):1233-1244

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Geology of the Yap Trench: new observations from a transect near 10°N from manned submersible Jiaolong     

Yaomin Yang  Jinwei Gao  Liyan Tian  Jichao Yang  Yue Xu 《International Geology Review》2018,60(16):1941-1953

This paper describes the petrology and geochemistry of rocks from the Yap Trench acquired by three dives of the Jiaolong research submarine. Combining the geophysical data and submersible observations, this paper describes the geomorphology, shallow structures, and sedimentology of the Yap Trench and further discusses the tectonics and activities of this region. Two obvious slope breaks are found on the landward slope, and horsts and grabens with small fault offsets are observed in the ocean-ward slope of the trench. Peridotites sampled from the Yap Trench inner wall are highly depleted subduction-related mantle residues. Volcanic rocks in the northern segment of the trench have subduction-related characteristics that Yap fore-arc rocks underwent metasomatism during Cenozoic subduction. The rocks with remarkable lithologic difference from lithospheric mantle and upper crust sampled in the break slopes suggest that the slope break area may represent a lithologic boundary or transition zone. The landward slope of the Yap Trench was removed by subduction erosion as a result of collision with the Caroline Ridge. The bending of the down-going plate caused normal faults, horsts, and grabens with little or no sediments indicating that the Caroline Ridge is subducting beneath the Yap arc along the trench even though the convergence rate is very slow.  相似文献   

渝东北城口地区Y1井页岩有机地球化学特征及勘探前景   总被引：1，自引：0，他引：1  

何廷鹏  栾进华  胡科  李甜  杨柳  张跃磊 《岩矿测试》2018,37(1):87-95

基于钻井资料,以总有机碳(TOC)、干酪根显微组分、等效镜质体反射率(Ro)及碳同位素等测试数据系统分析了渝东北城口地区Y1井五峰组—龙马溪组页岩的有机地球化学特征,利用页岩流体包裹体的显微特征、均一温度及激光拉曼数据深入分析了Y1井页岩气成藏特征。结果表明:Y1井上奥陶统五峰组—下志留统龙马溪组炭质页岩发育,TOC含量2%的富含有机质页岩厚度达83 m,干酪根类型以Ⅰ型干酪根为主,处于湿气生烃阶段。页岩裂缝脉体中大量烃包裹体和富含甲烷气体的含烃盐水包裹体证实城口地区五峰组—龙马溪组页岩发生了充足页岩气供给,具有高均一温度、高盐度的伴生盐水包裹体表明城口地区页岩气成藏时期的保存条件良好。这些Y1井页岩有机地球化学特征研究成果揭示了城口地区下古生界具备良好的页岩气勘探前景。  相似文献   

川北地区寒武系筇竹寺组钙质结核裂缝充填物特征及指示意义   总被引：1，自引：0，他引：1  

冯明友  郑江  刘田  刘小洪  张家强  梅文华  孙霓源  龙涛 《地质论评》2018,64(3):711-722

川北地区寒武系筇竹寺组钙质结核泥页岩中早成岩期钙质结核较发育,结核裂缝中见多期次矿物充填。为揭示钙质结核裂缝形成机理,本次结合岩石学特征及地球化学特征等开展系统研究。川北筇竹寺组钙质结核裂缝中见三~四期矿物充填。第一期微晶方解石表面较脏,阴极发光暗淡,δ13C_(PDB)、δ18O_(PDB)平均值分别为-4.26‰及-7.69‰;第二期为细—中晶粒状方解石充填,阴极发光为橘黄色,流体包裹体均一温度为平均值为86.4℃,δ13C_(PDB)、δ18O_(PDB)平均值分别为-3.15‰及-7.41‰;第三期为粗晶方解石充填阴极发光暗淡,流体包裹体均一温度平均值为96.6℃,δ~(13)C_(_(PDB))、δ~(18)O_(_(PDB))平均值分别为-1.73‰及-10.28‰;第四期为重晶石充填。结合区域构造史—热演化史分析表明,钙质结核裂缝中四期充填物分别指示早期脱水、烃源岩早成熟期生烃、加里东构造运动抬升释压及深埋藏期硫酸盐热还原作用事件。  相似文献   

地球接受太阳辐射能量变化对板块构造影响的估算          下载免费PDF全文

田嘉铖  季建清 《地质科学》2018,(4):1499-1512

板块构造理论可以被认为是构造地质学研究的基本模型和框架。传统板块构造理论认为岩石圈板块在软流圈上方随软流圈对流发生运动,软流圈对流所需要的能量则完全由地球内部能量,如重力势能和放射性衰变产生的热能提供。但是近年来的一些研究证明了气候变化会对板块构造活动,如造山带活动产生直接影响。对传统的板块构造所需能量全部由地球内部提供这一观点做出了补充和更新。本文主要从两个方面对外动力作用可能影响板块构造做出分析,一是利用傅里叶分析证明了太阳辐射变化在构造活动,如洋中脊两侧地貌和火山沉积物中均能够留下记录;二是建立了一个简单的平面力学模型,探究洋流同大陆的力学作用会如何影响大陆运动特征。虽然这一模型忽略了很多因素,定量计算的结果本身并不具有很严格的数据绝对意义。但是这一模型的结果可以证明地球所有板块构造活动中释放的能量低于地球系统每年从太阳辐射中接收的能量,而且模型得到的大陆运动特征同现今实际观测下的运动特征存在一致性,洋流向大陆岩石圈传递的能量同地震活动释放的能量处于同一量级,从侧面可以证明洋流可能对板块构造产生了较大的影响。  相似文献   

青藏高原东部暴雨的中尺度有效位能收支分析          下载免费PDF全文

Kuo Zhou  Lingkun Ran  Yi Liu  Xiuxia Tian 《大气和海洋科学快报》2021,14(2):53-59

针对2018年7月10-11日青藏高原东部一次暴雨过程,利用模式模拟资料分析了有效位能分布特征,成因及其对降水发展演变的影响.结果表明,有效位能主要分布在对流层低层4km以下和高层8-14km,高层有效位能和降水有更好的对应性西北冷平流和降水粒子下落的蒸发作用是低层有效位能高值中心的主要成因,而降水过程释放潜热带来的热力扰动叠加高原大地形造成的位温扰动是导致高层有效位能高值的主要原因.有效位能收支分析表明,有效位能的通量输送项以及与动能间的转换项是主要源汇项.低层有效位能的经向通量输送和动能向有效位能的转化补给了有效位能的耗散;高层有效位能向垂直动能转化增强垂直运动是促进降水发展演变的主要因素.高层有效位能与垂直运动之间的正反馈过程使得两者相关性较强;低层较长时间内均存在垂直动能向有效位能的转化,削弱了垂直运动,而西北冷平流使得低层有效位能有增强的趋势,因此二者相关性较弱.  相似文献   

青藏高原地区气溶胶直接辐射强迫的数值模拟研究     

田甜  马建中 《气候与环境研究》2021,26(4):449-460

通过比较EMAC模式模拟结果和卫星观测结果证实了模式的可信性,进而利用模拟结果分析研究了2010～2012年青藏高原上空气溶胶光学厚度及其直接辐射强迫的时空分布规律。结果表明:所有气溶胶组分中,沙尘、水溶性气溶胶和气溶胶中液态水是高原的主要消光物质,三者年平均消光占比分别为0.27、0.20和0.49。2011年夏季纳布罗火山爆发,高空气溶胶消光在海拔14 km以上显著增强。青藏高原气溶胶在大气顶和地表的直接辐射强迫分布总体上由北向南递减,沙尘气溶胶在高原北部边缘大气顶产生正辐射强迫,气溶胶大气层直接辐射强迫对大气有增温效应,主要出现在沙尘含量高的地区。此外,受纳布罗火山爆发的影响,平流层气溶胶在2011年秋、冬季产生了明显较强的负辐射强迫,相比于无火山爆发的2010年和 2012年,青藏高原上空平流层气溶胶负辐射强迫在2011年秋季和冬季分别增加了55.50%和52.38%。  相似文献   

Estimating satellite phase fractional cycle biases based on Kalman filter     

Guorui Xiao  Lifen Sui  Bernhard Heck  Tian Zeng  Yuan Tian 《GPS Solutions》2018,22(3):82

Phase fractional cycle biases (FCBs) originating from satellites and receivers destroy the integer nature of PPP carrier phase ambiguities. To achieve integer ambiguity resolution of PPP, FCBs of satellites are required. In former work, least squares methods are commonly adopted to isolate FCBs from a network of reference stations. However, it can be extremely time consuming concerning the large number of observations from hundreds of stations and thousands of epochs. In addition, iterations are required to deal with the one-cycle inconsistency among FCB measurements. We propose to estimate the FCB based on a Kalman filter. The large number of observations are handled epoch by epoch, which significantly reduces the dimension of the involved matrix and accelerates the computation. In addition, it is also suitable for real-time applications. As for the one-cycle inconsistency, a pre-elimination method is developed to avoid iterations and posterior adjustments. A globally distributed network consisting of about 200 IGS stations is selected to determine the GPS satellite FCBs. Observations recorded from DoY 52 to 61 in 2016 are processed to verify the proposed approach. The RMS of wide lane (WL) posterior residuals is 0.09 cycles while that of the narrow lane (NL) is about 0.05 cycles, which indicates a good internal accuracy. The estimated WL FCBs also have a good consistency with existing WL FCB products (e.g., CNES-GRG, WHU-SGG). The RMS of differences with respect to GRG and SGG products are 0.03 and 0.05 cycles. For satellite NL FCB estimates, 97.9% of the differences with respect to SGG products are within ±?0.1 cycles. The RMS of the difference is 0.05 cycles. These results prove the efficiency of the proposed approach.  相似文献   

华北克拉通东缘金岭杂岩体岩浆源区及构造背景:来自岩相学、岩石地球化学及年代学的证据          下载免费PDF全文

高继雷周永刚  张振飞高明波赵体群  田振环朱振宏 《地质科学》2021,56(1):253-271

金岭杂岩体由细粒黑云角闪闪长岩、中细粒黑云角闪闪长岩、中细粒黑云角闪二长闪长岩和细粒角闪二长闪长岩组成,是鲁西地区典型矽卡岩型富铁矿(金岭铁矿)控矿岩体。本次研究对细粒黑云角闪闪长岩和细粒角闪二长闪长岩进行了锆石LA‐ICP‐MS U‐Pb定年,其结果分别为129.2±3.2 Ma和132.8±1.2 Ma,表明该杂岩体的侵位时代为早白垩世。样品SiO2、K2O和Na2O含量分别介于54.17%~63.73%、1.92%~4.76%和3.10%~5.41%之间,K2O/Na2O为0.58~0.94,A/CNK为0.60~0.93,具有轻稀土富集,重稀土亏损的右倾型稀土配分模式,轻、重稀土分馏程度中等((La/Yb)N=9.94~23.49),Eu异常不明显(δEu=0.84~1.10),具中—弱负Ce异常(δCe=0.56~0.92)。样品以富集大离子亲石元素(Ba、K、U、Pb等)、亏损高场强元素(Nb、Ta、Ti)以及高Sr/Y为特征。金岭杂岩体为燕山晚期岩浆活动产物,属准铝质高钾钙碱性系列,岩浆主要来源于富集岩石圈地幔的部分熔融,并在岩浆上升侵位的过程中有地壳物质的同化混染。燕山晚期华北克拉通在古太平洋板块俯冲后后撤引起的板内伸展环境下,增厚陆壳减薄阶段,岩浆上侵就位形成金岭杂岩体。  相似文献