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21.
Reduction spheroids are small-scale, biogenic, redox-controlled, metal enrichments that occur within red beds globally. This study provides the first analysis of the compositionally unique reduction spheroids of the Tumblagooda Sandstone. The work aims to account for their composition and consequently improve existing models for reduction spheroids generally, which presently fail to account for the mineralogy of the Tumblagooda Sandstone reduction spheroids. Interstitial areas between detrital grains contained in the cores of these reduction spheroids are dominated by microplaty haematite, in addition to minor amounts of svanbergite, gorceixite, anatase, uraninite, monazite and illite. The haematite-rich composition, along with an absence of base metal phases and the vanadiferous mica roscoelite, makes these reduction spheroids notable in comparison to other global reduction spheroid occurrences. Analyses of illite crystallinity provide values for samples of the Tumblagooda Sandstone host rock corresponding to heating temperatures of ca 200°C. Consequently, while Tumblagooda Sandstone reduction spheroids formed via the typical metabolic processes of dissimilatory metal-reducing bacteria, the combination of a unique mineralogy and illite crystallinity analysis provides evidence of more complex late-stage heating and reoxidation. This has not previously been recognised in other reduction spheroids and therefore expands the existing model for reduction spheroid genesis by also considering the potential for late-stage alteration. As such, future reduction spheroid studies should consider the potential impact of post-formation modification, particularly where they are to be used as evidence of ancient microbial processes; such as in the search for early evidence of life in the geological record on Earth or other planets. Additionally, because of their potential for modification, reduction spheroids serve as a record of the redox history of red beds and their study could provide insights into the evolution of redox conditions within a given red bed during its diagenesis. Finally, this paper also provides insights into the relatively understudied diagenetic history of the Tumblagooda Sandstone; supplying the first reliable and narrow constraints on its thermal history. This has important implications for the thermal history of the Carnarvon Basin and its petroleum prospectivity more broadly.  相似文献   
22.
Timms WA  Hendry MJ 《Ground water》2008,46(4):616-628
Characterizing and predicting reactive solute transport in low hydraulic conductivity ( K ) clay-rich media is challenging because the very long transport time for solutes renders conventional column tests impractical. In this study, a centrifugation technique was developed to assess the transport of a simple aqueous solution (NaCl) by accelerating flow by centrifugal force through low K (1.1 × 10−11 m/s) core samples. Duplicate cores (52-mm length × 33-mm diameter) were centrifuged at 330 × g for 90 d to model the migration of saline pore water (0.5 M NaCl) under in situ conditions through an approximately 17-m-thick clay prototype over approximately 24,000 years. A PHREEQC one-dimensional reactive solute transport code simulated effluent breakthrough of the NaCl during centrifugation, with best-fit cation exchange coefficients similar to batch tests. The calibrated code was used to predict solute profile development over the long term in the prototype or simulated field-scale conditions. Chromatographic separation of solutes due to ion exchange was evident over several meters in the simulated prototype and the field profile. The applicability of centrifugation methods to predict transport of more complex suites of reactive solutes over the long term is yet to be verified.  相似文献   
23.
Natural Resources Research - The impact that climate change may play in the future sustainability of mining projects has become increasingly important for the mining industry and its stakeholders....  相似文献   
24.
Meteoritic matrices are commonly classified by their modal mineralogy, alteration, and shock levels. Other “textural” characteristics are not generally considered in classification schemes, yet could carry important information about their genesis and evolution. Terrestrial rocks are routinely described by grain morphology, which has led to morphology‐driven classifications, and identification of controlling processes. This paper investigates three CV chondrites—Allende (CV3.2oxA), Kaba (CV3.0oxB), and Vigarano (CV3.3red)—to determine the morphologic signature of olivine matrix grains. 2D grain size and shape, and crystallographic preferred orientations (CPOs) are quantified via electron backscatter diffraction mapping. Allende contains the largest and most elongate olivine grains, while Vigarano contains the least elongate, and Kaba contains the smallest grains. Weak but notable CPOs exist in some regions proximal to chondrules and one region distal to chondrules, and CPO geometries reveal a weak flattening of the matrix grains against the edge of chondrules within Allende. Kaba contains the least plastically deformed grains, and Allende contains the most plastically deformed grains. We tentatively infer that morphology is controlled by the characteristics of the available population of accreting grains, and aqueous and thermal alteration of the parent body. The extent of overall finite deformation is likely dictated by the location of the sample with respect to compression, the localized environment of the matrix with respect to surrounding material, and the post deformation temperature to induce grain annealing. Our systematic, quantitative process for characterizing meteorite matrices has the potential to provide a framework for comparison within and across meteorite classes, to help resolve how parent body processing differed across and between chondritic asteroids.  相似文献   
25.
Lead isotopes are a powerful and versatile tool to elucidate fundamental geological problems related to the formation and evolution of continental crust. K-feldspar is a popular target for Pb isotope measurement as it is prevalent in many rock types and tends to capture the initial Pb isotope composition of its parental magma. We present data for a new Pb isotope reference material: Albany K-feldspar; as well as updated data for Shap K-feldspar. Results of Pb double-spike TIMS for Albany K-feldspar are 206Pb/204Pb = 16.7872 ± 0.0062, 207Pb/204Pb = 15.5640 ± 0.0056, and 208Pb/204Pb = 36.6600 ± 0.0168 (2s). TIMS measurement results for Shap K-feldspar indicate two isotopically distinct Pb populations. LA-MC-ICP-MS, with a spatial resolution as high as 15 μm, indicates a homogeneous Pb isotopic composition in Albany K-feldspar. In accord with previous studies, our results show that scatter in the measured Pb isotope ratios, related to the low natural isotopic abundance of 204Pb, along with the effect of isobaric 204Hg-204Pb interference, increases at lower count rates. However, the mean Pb isotope ratios measured via LA-MC-ICP-MS using a range of spot sizes are in excellent agreement with TIMS results thus highlighting the feasibility of Pb isotope determination via LA-MC-ICP-MS to access geological information preserved in small crystals, including mineral inclusions.  相似文献   
26.
Hydrogeology Journal - The hydraulic conductivity of jointed rocks is one of the main input parameters to predict water inflow to engineering structures that are located in the jointed rocks....  相似文献   
27.
The evolution of faults and paleodrainage patterns on the southwestern Australian passive margin during and after the breakup of Gondwana in the Early Cretaceous remains poorly understood. This contribution investigates the fault and paleodrainage evolution in the southern Perth Basin with the use of the ‘Bunbury Basalt’, the only lava flows known to be synchronous with continental breakup. New aeromagnetic data have been integrated with well intersections and outcrop constraints to establish the first 3D model of the Bunbury Basalt. The model reveals that flows are up to 100 m thick and are predominantly confined to two north–south-trending paleovalleys and their tributaries situated in the Bunbury Trough in the southern Perth Basin. The Donnybrook Paleovalley flow ponded in a paleovalley proximal to the Darling Fault and is truncated by the two later flows within the Bunbury Paleovalley, which is positioned centrally in the Bunbury Trough. Offsets of the Bunbury Basalt have been used to identify new northeast- and northwest-trending faults in the southern Perth Basin, and broad folding is interpreted as a consequence of drag into the Darling and Busselton faults. The model has been used to determine post-basalt net displacements for the Darling and Busselton faults of 370 and 210 m, respectively, and <175 m for the northeast and northwest-trending faults. The source vents for the Bunbury Basalt were probably located at extensional jogs at intersections between the Darling Fault and subordinate oblique faults. These results challenge the views on longstanding quiescence of the post-breakup western Australian passive margin.  相似文献   
28.
On retrieving patterns in environmental sensor data   总被引:1,自引:0,他引:1  
As many sensor networks are currently being deployed for environmental monitoring, there is a growing need to develop systems and applications for managing, processing and retrieving massive amounts of data generated from those networks. In this research, a query answering system with pattern mining techniques is investigated specifically for marine sensor data. We consider three applications of pattern mining: similar pattern search, predictive query and query by clustering. In pattern mining for query answering, we adopt the dynamic time warping (DTW) method for similarity measurement. We also propose the use of a query relaxation approach that recommends users change parameters of a given query to get an answer. Finally, we show implementation results of pattern query answering in a marine sensor network deployed in the South East of Tasmania, Australia. Pattern query answering system benefits in accessing and discovering knowledge from sensor data for decision making purposes.  相似文献   
29.
30.
Clayey-silt aquitards account for 60 % of the ~100-m-thick alluvial sediment sequence in the Gunnedah area of eastern Australia. To better understand the stress-dependent hydraulic properties of these low-permeability units, oedometer test data presented for the first time in this study have been integrated with geotechnical centrifuge permeameter tests. Estimates of vertical pre-consolidation effective stress (\(\sigma_{\text{p}}^{'}\)), vertical in situ effective stress (\(\sigma_{\text{i}}^{'}\)), and over-consolidation ratio (OCR) were used to determine whether centrifugation stresses caused compression of core samples, and the degree to which vertical hydraulic conductivity (K v) assessments were representative of the core samples tested. Results suggest that minimally disturbed drill core from semi-consolidated sediments (e.g., alluvial, colluvial, and eolian deposits) evaluated in this study should have target centrifugation stress less than \(\sigma_{\text{p}}^{'}, \) where OCR < 1 and \(\sigma_{\text{i}}^{'}\) where OCR > 1 to avoid significant changes in hydraulic properties during plastic straining. The results also imply that the stress-dependent response of aquitards is critical to understand the sensitivity of groundwater resources in areas with multiple stakeholders such as mining, coal seam gas, and agriculture developments. Groundwater in alluvial sediments that is essential for irrigation, water supply, and base flows to rivers must be sufficiently disconnected from groundwater in coal seams that are depressurized for extraction of energy resources.  相似文献   
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