Carbon Budget and Molecular Structure of Natural Organic Matter in Bank Infiltrated Groundwater     

Maija Jylhä-Ollila  Hanne Laine-Kaulio  Jos Schilder  Paula Niinikoski-Fuβwinkel  Timo Kekäläinen  Janne Jänis  Harri Koivusalo 《Ground water》2021,59(5):644-657

Managed aquifer recharge (MAR) provides means to remove natural organic matter (NOM) from surface waters. Recent studies have explored the degree of NOM removal in groundwater. In this study, we further elaborate the NOM removal at a lakeside natural bank infiltration site that functions as a surrogate for MAR. Our objective was to quantify the carbon budget in the aquifer based on concentration measurements of dissolved (in)organic carbon, and the molecular changes in NOM using Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). According to the carbon budget, only 25% of the dissolved carbon entering the aquifer was organic, and it predominantly originated from lake water. Of the inorganic majority, on average 40% was produced in the vadose zone above the groundwater table, 31% in the lake bank, 22% in the aquifer as a result of degrading organic matter of lake water, and 7% in the lake. Seasonal concentration variations suggested that the lake bank was the main carbon source in the summer, increasing the carbon concentration of infiltrating lake water, that is, 3.0 mg/L to 7.9 mg/L. FT-ICR MS results showed 4960 to 5330 individual compounds in lake and groundwater. NOM removal in the aquifer was selective: the relative abundance of oxygen-containing species decreased from 75 to 31%, while the relative abundance of sulfur-containing species increased from 15 to 57%. The average molecular weights of both species remained unchanged. The study highlighted the role of lake bank processes and sulfur-containing species in groundwater quality.  相似文献   

‘Observations and Modelling of Cold-air Advection over Arctic Sea Ice’     

Timo?VihmaEmail author  Christof?Lüpkes  J?rg?Hartmann  Hannu?Savij?rvi 《Boundary-Layer Meteorology》2005,117(2):275-300

Aircraft observations of the atmospheric boundary layer (ABL) over Arctic sea ice were made during non-stationary conditions of cold-air advection with a cloud edge retreating through the study region. The sea-ice concentration, roughness, and ABL stratification varied in space. In the ABL heat budget, 80% of the Eulerian change in time was explained by cold-air advection and 20% by diabatic heating. With the cloud cover and inflow potential temperature profile prescribed as a function of time, the air temperature and near-surface fluxes of heat and momentum were well simulated by the applied two-dimensional mesoscale model. Model sensitivity tests demonstrated that several factors can be active in generating unstable stratification in the ABL over the Arctic sea ice in March. In this case, the upward sensible heat flux resulted from the combined effect of clouds, leads, and cold-air advection. These three factors interacted non-linearly with each other. From the point of view of ABL temperatures, the lead effect was far less important than the cloud effect, which influenced the temperature profiles via cloud-top radiative cooling and radiative heating of the snow surface. The steady-state simulations demonstrated that under overcast skies the evolution towards a deep, well-mixed ABL may take place through the merging of two mixed layers one related to mostly shear-driven surface mixing and the other to buoyancy-driven top-down mixing due to cloud-top radiative cooling.  相似文献   

Environmental literacy in interpreting endangered sustainability: Case studies from Thailand and the Sudan     

Minna Hares  Anu Eskonheimo  Timo Myllyntaus 《Geoforum》2006,37(1):128-144

This paper examines how people explain reasons and impacts of environmental change in the low-rain savanna of the central Sudan and mountainous forest lands of northern Thailand. The explanations are analyzed by using the concept of environmental literacy, which refers to the people’s ability to grasp the environment and its interactions. The paper aims to study people’s conceptions of the environment, which compose one factor in directing their behavior. For the study, rural inhabitants in the State of North Kordofan, the Sudan, and the Chiang Mai Province in Thailand were interviewed.It was noted that an individual’s capability to understand the environment is alone insufficient to address environmental problems because the efficient alleviation of the problems requires collective actions at all levels, and because of factors beyond an individual’s control. However, the results supported the assumption that the local people have knowledge of their environment that may help in developing sustainable environmental management practices. The main advantages of using the environmental literacy concept are argued to be its dynamic and synthetic essence, its link to sustainable behavior, and wide applicability in various contexts within heterogeneous communities.  相似文献   

Increased Carbon Sink in Temperate and Boreal Forests   总被引：6，自引：0，他引：6  

Jari Liski  Alexander V. Korotkov  Christopher F. L. Prins  Timo Karjalainen  David G. Victor  Pekka E. Kauppi 《Climatic change》2003,61(1-2):89-99

An intense search is under way to identify the `missing sink' in the world carbon budget of perhaps 2 Pg year^–1 (petagrams, or billiontonnes) of carbon, but its location and mechanism have proved elusive. Here we use a new forest inventory data set to estimate the carbon sink and the carbon pool of woody biomass in 55 countries that account for nearly all temperate or boreal forests and approximately half the world's total forest area. In each country there was a net accumulation of biomass; together, the carbon sink of woody biomass was 0.88 Pg year^–1 during the 1990swith estimated uncertainty from 0.71 to 1.1 Pg year^–1. Thisestimate, already about half of the missing sink, would probably be even larger if carbon accumulation in soil and detritus were also accounted for, but we are unable to quantify that additional sink. The sink is twice that estimated for the woody biomass of these forests a decade ago due to higher estimates for tree growth throughout the region and decreased timber harvests in Russia. In contrast, the new data indicate a carbon pool that is smaller than earlier estimates because of improved data for Russia and Australia.  相似文献   

Footprints and Fetches for Fluxes over Forest Canopies with Varying Structure and Density   总被引：1，自引：1，他引：1  

Tiina Markkanen  Üllar Rannik  Barbara Marcolla  Alessandro Cescatti  Timo Vesala 《Boundary-Layer Meteorology》2003,106(3):437-459

A stochastic trajectory model was used to estimate scalar fluxfootprints in neutral stabilityfor canopies of varying leaf area distributions andleaf area indices. An analytical second-order closure model wasused to predict mean wind speed, second moments and the dissipationrate of turbulent kinetic energy within a forest canopy.The influence of source vertical profile on the flux footprint wasexamined. The fetch is longer for surface sourcesthan for sources at higher levels in the canopy. In order tomeasure all the flux components, and thus the total flux, with adesired accuracy, sources were located at the forest floor in thefootprint function estimation. The footprint functions werecalculated for five observation levels above the canopy top. Itwas found that at low observation heights both canopy density andcanopy structure affect the fetch. The higher abovethe canopy top the flux is measured, the more pronounced is the effectof the canopy structure. The forest fetch for flux measurements isstrongly dependent on the required accuracy: The 90% flux fetchis greater by a factor of two or more compared to the 75% fetch. Theupwind distance contributing 75% of flux is as large as 45 timesthe difference between canopy height and the observation heightabove the canopy top, being even larger for low observationlevels.  相似文献   

Magmatic versus metamorphic origin of olivine-plagioclase coronas     

Geert-Jan L. de Haas  Timo G. Nijland  Peter J. Valbracht  Cees Maijer  Rob Verschure  Tom Andersen 《Contributions to Mineralogy and Petrology》2002,143(5):537-550

An SEM, REE, and mineral Sm-Nd isotope study on olivine-plagioclase coronas in the Vestre Dale gabbro, Norway, was carried out in order to solve the temporal relationships within these coronas. It is demonstrated that in contrast to common models, corona formation is a multistage, late-magmatic process, starting with the formation of orthopyroxene by (partial) dissolution of olivine, followed by the nucleation and rapid outward growth of orthopyroxene+spinel symplectites at its outer margin, and concluded by replacement of this precursory outer shell by calcic amphibole. Isotopic equilibrium between inner shell orthopyroxene and the magmatic assemblage, and the REE contents of orthopyroxene and outer shell amphibole also provide strong arguments for a magmatic origin, with the local availability of fractionated magma acting as a limiting factor. The absence of replacement of intercumulus clinopyroxene by amphibole also favours a late stage magmatic rather than a metamorphic origin for corona amphibole.  相似文献   

Multipurpose geochemical maps produced by integration of geochemical exploration data sets in The Paraná Shield, Brazil     

Otavio Augusto Boni Licht  Timo Tarvainen 《Journal of Geochemical Exploration》1996,56(3):167-182

Old geochemical datasets from the Paraná Shield of southern Brazil have been integrated into a new geochemical database and the results are presented as a series of multipurpose geochemical maps. Although the 24 datasets retrieved were analysed by three different laboratories, the maps produced correlate surprisingly well with bedrock geological features.The retrieval of old geochemical exploration data sets for the purpose of generating maps showing element depletions and enrichments is a powerful tool with a wide range of applications: trace elements such as Zn, Cu and Mo can significantly affect crop productivity; areas with high abundances of harmful elements such as As and F can be delineated in order to identify public health hazards; heavy metals such as Cd, Pb and Hg can be measured in order to better constrain knowledge of chemical background levels for environmental monitoring. The integration and manipulation of different data sets can however be complicated by the heterogeneity in sampling and analytical procedures.  相似文献   

Big location‐based social media messages from China's Sina Weibo network: Collection,storage, visualization,and potential ways of analysis          下载免费PDF全文

Michael Jendryke  Timo Balz  Mingsheng Liao 《Transactions in GIS》2017,21(4):825-834

China's social media platform, Sina Weibo, like Twitter, hosts a considerable amount of big data: messages, comments, pictures. Collecting and analyzing information from this treasury of human behavior data is a challenge, although the message exchange on the network is readable by everyone through the web or app interface. The official Application Programming Interface (API) is the gateway to access and download public content from Sina Weibo and is used to collect messages for all mainland China. The nearby_timeline() request is used to harvest only messages with associated location information. This technical note serves as a reference for researchers who do not speak Mandarin but want to collect data from this rich source of information. Ways of data visualization are presented as a point cloud, density per areal unit, or clustered using Density‐Based Spatial Clustering of Applications with Noise (DBSCAN). The relation of messages to census information is also given.  相似文献   

Carbon balance in the forest sector in Finland during 1990–2039     

Timo Karjalainen  Seppo Kellomäki  Ari Pussinen 《Climatic change》1995,30(4):451-478

In this study we estimated the amount of carbon (C) stored in the forest growing stock and in wood-based products, and the C-sequestration capacity of the forest sector in Finland. Comparison of different management and utilization options for forest resources over the period 1990-2039 indicates that C is stored more efficiently in standing timber than in wood-based products. This implies that an appropriate increase in the length of the rotation in forestry could be optimal for balancing the needs of forest resources for C sequestration and timber production. Increased use of wood, based on sustainable use of forest resources, to substitute for fossil fuels and materials, could decrease the overall C emissions. Release of sequestered C back to the atmosphere can be delayed by prolonging product lifespans, by increasing recycling, or by disposing of discarded products in landfills. To delay C release, and affect the C balance, however, these changes should be substantial.In 1990, the net C balance of the growing stemwood stock was 5.5 Tg C/a, which increased to 16.3 Tg C/a by 2039 if in the future the use of wood would be at the level of the late 1980s. Increased use of wood resulted in a balance of 6.6 Tg C/a or -0.2 Tg C/a, depending on the extent of the use of wood. The average C balance in wood products for the whole period was 3.9, 5.6 or 6.6 Tg C/a, respectively. Changes in production capacity, and consideration of timber and product import and export decreased the average balance from 6.6 Tg C/a to 0.9–1.3 Tg C/a. By comparison, emission from the use of fossil fuels in 1990 C was 14.5 Tg C/a.  相似文献   

Spatial variability and trigger values of arsenic in the surface urban soils of the cities of Tampere and Lahti,Finland     

Gabriele Buttafuoco  Timo Tarvainen  Jaana Jarva  Ilaria Guagliardi 《Environmental Earth Sciences》2016,75(10):896

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