Geochemical modelling of a Zn–Pb skarn: Constraints from LA–ICP–MS analysis of fluid inclusions     

Martina Bertelli  Timothy Baker  James S. Cleverley  Thomas Ulrich 《Journal of Geochemical Exploration》2009

The Bismark deposit (northern Chihuahua, Mexico) is one of several base metal-rich high-temperature, carbonate-replacement deposits hosted in northern Mexico. Previous fluid inclusion studies based on microthermometry and PIXE have shown that the Zn-rich, Pb-poor Bismark deposit formed from a moderate salinity magmatic fluid [Baker, T. and Lang, J.R., 2003. Reconciling fluid inclusion types, fluid processes, and fluid sources in skarns: an example from the Bismark Deposit, Mexico. Mineralium Deposita 38(4), 474–495; Baker, T., van Achterberg, E., Ryan, C.G. and Lang, J.R., 2004. Composition and evolution of ore fluids in a magmatic-hydrothermal skarn deposit. Geology 32(2), 117–120]. The exact precipitation mechanisms are unclear and may have due to cooling, salinity decrease and wall rock reaction. Furthermore, PIXE data suggested that Pb and Zn concentrations were comparable and inconsistent with the Zn-rich nature of the ore. However, Pb was commonly below the limit of detection for PIXE and the data presented by Baker et al. [Baker, T., van Achterberg, E., Ryan, C.G. and Lang, J.R., 2004. Composition and evolution of ore fluids in a magmatic-hydrothermal skarn deposit. Geology 32(2), 117–120] are regarded as the maximum concentrations of Pb in the fluid. In this study new LA ICP MS analysis was carried out on the same fluid inclusion population to compare with the PIXE data in order to constrain the uncertainty related to the Pb data and the new results are used to model possible ore deposition mechanisms. The new laser ablation data reveal overall lower concentrations of Pb in the ore fluid (average value ~ 285 ppm) than previously indicated by PIXE analysis (average value ~ 713 ppm). Chemical modelling using the new laser ablation data tested the following ore deposition processes: 1) cooling; 2) fluid–rock reaction at constant temperature; 3) cooling and simultaneous fluid–rock interaction. Modelling results show that the gangue and ore minerals observed at Bismark are best reproduced by fluid–rock interaction and simultaneous cooling. Results from the simulations strongly indicate that ore deposition was mainly driven by a pH increase due to the neutralization of the acidic ore fluid (pH = 3.9) as the result of the reaction with the limestone. Modelling results also suggest that the deposit likely formed under cooling conditions, but do not support the hypothesis of a temperature decrease as the principal ore-forming process.  相似文献   

Change of collision efficiency with distance in bacterial transport experiments     

Dong H  Scheibe TD  Johnson WP  Monkman CM  Fuller ME 《Ground water》2006,44(3):415-429

Understanding the mechanisms of bacterial transport in aquifers is important in developing bioremediation strategies. Collision efficiency (alpha) is one important parameter used in modeling bacterial transport. This study was undertaken to measure change in alpha with distance by performing a bacterial transport experiment in Oyster, Virginia. Following injection of a bacterium, Comamonas sp., into a well, water samples were collected at various distances along the flowpath and injected into columns packed with homogenized South Oyster focus area sediment. Zeta potentials of the bacteria in the samples were measured. Values of alpha were determined at various locations in the field in two ways: based on field breakthrough concentrations at the sampling points and based on column breakthrough concentrations. The alpha values estimated from field breakthrough decreased with distance, whereas those estimated from column breakthrough increased with distance. Bacterial cell surface charge became progressively more negative with distance in the field. We hypothesize that the apparent contradiction between field and column alpha values was caused by differences in the flow of the two systems. Flow in the columns was forced to occur through fine-grained zones of iron and aluminum hydroxide coatings that selectively removed the most negatively charged bacteria. In contrast, in the field, the injected cells did not come into contact with the positively charged coatings because the bulk solution bypassed them due to heterogeneous hydraulic properties. These results suggest that laboratory-based models may underestimate bacterial transport distance in the field. A more realistic approach may be necessary to capture the degree of heterogeneity.  相似文献   

Downscaling large-scale NCEP CFS to resolve fine-scale seasonal precipitation and extremes for the crop growing seasons over the southeastern United States     

Young-Kwon Lim  Steven Cocke  D. W. Shin  Justin T. Schoof  Timothy E. LaRow  James J. O’Brien 《Climate Dynamics》2010,35(2-3):449-471

Seasonally predicted precipitation at a resolution of 2.5° was statistically downscaled to a fine spatial scale of ~20 km over the southeastern United States. The downscaling was conducted for spring and summer, when the fine-scale prediction of precipitation is typically very challenging in this region. We obtained the global model precipitation for downscaling from the National Center for Environmental Prediction/Climate Forecast System (NCEP/CFS) retrospective forecasts. Ten member integration data with time-lagged initial conditions centered on mid- or late February each year were used for downscaling, covering the period from 1987 to 2005. The primary techniques involved in downscaling are Cyclostationary Empirical Orthogonal Function (CSEOF) analysis, multiple regression, and stochastic time series generation. Trained with observations and CFS data, CSEOF and multiple regression facilitated the identification of the statistical relationship between coarse-scale and fine-scale climate variability, leading to improved prediction of climate at a fine resolution. Downscaled precipitation produced seasonal and annual patterns that closely resemble the fine resolution observations. Prediction of long-term variation within two decades was improved by the downscaling in terms of variance, root mean square error, and correlation. Relative to the coarsely resolved unskillful CFS forecasts, the proposed downscaling drove a significant reduction in wet biases, and correlation increased by 0.1–0.5. Categorical predictability of seasonal precipitation and extremes (frequency of heavy rainfall days), measured with the Heidke skill score (HSS), was also improved by the downscaling. For instance, domain averaged HSS for two category predictability by the downscaling are at least 0.20, while the scores by the CFS are near zero and never exceed 0.1. On the other hand, prediction of the frequency of subseasonal dry spells showed limited improvement over half of the Georgia and Alabama region.  相似文献   

Climate change mitigation: trade-offs between delay and strength of action required     

Naomi E. Vaughan  Timothy M. Lenton  John G. Shepherd 《Climatic change》2009,96(1-2):29-43

Climate change mitigation via a reduction in the anthropogenic emissions of carbon dioxide (CO₂) is the principle requirement for reducing global warming, its impacts, and the degree of adaptation required. We present a simple conceptual model of anthropogenic CO₂ emissions to highlight the trade off between delay in commencing mitigation, and the strength of mitigation then required to meet specific atmospheric CO₂ stabilization targets. We calculate the effects of alternative emission profiles on atmospheric CO₂ and global temperature change over a millennial timescale using a simple coupled carbon cycle-climate model. For example, if it takes 50 years to transform the energy sector and the maximum rate at which emissions can be reduced is ?2.5% $\text{year}^{-1}$ , delaying action until 2020 would lead to stabilization at 540 ppm. A further 20 year delay would result in a stabilization level of 730 ppm, and a delay until 2060 would mean stabilising at over 1,000 ppm. If stabilization targets are met through delayed action, combined with strong rates of mitigation, the emissions profiles result in transient peaks of atmospheric CO₂ (and potentially temperature) that exceed the stabilization targets. Stabilization at 450 ppm requires maximum mitigation rates of ?3% to ?5% $\text{year}^{-1}$ , and when delay exceeds 2020, transient peaks in excess of 550 ppm occur. Consequently tipping points for certain Earth system components may be transgressed. Avoiding dangerous climate change is more easily achievable if global mitigation action commences as soon as possible. Starting mitigation earlier is also more effective than acting more aggressively once mitigation has begun.  相似文献   

Changes in frost, snow and Baltic sea ice by the end of the twenty-first century based on climate model projections for Europe     

Kirsti Jylhä  Stefan Fronzek  Heikki Tuomenvirta  Timothy R. Carter  Kimmo Ruosteenoja 《Climatic change》2008,86(3-4):441-462

Changes in indices related to frost and snow in Europe by the end of the twenty-first century were analyzed based on experiments performed with seven regional climate models (RCMs). All the RCMs regionalized information from the same general circulation model (GCM), applying the IPCC-SRES A2 radiative forcing scenario. In addition, some simulations used SRES B2 radiative forcing and/or boundary conditions provided by an alternative GCM. Ice cover over the Baltic Sea was examined using a statistical model that related the annual maximum extent of ice to wintertime coastal temperatures. Fewer days with frost and snow, shorter frost seasons, a smaller liquid water equivalent of snow, and milder sea ice conditions were produced by all model simulations, irrespective of the forcing scenario and the driving GCM. The projected changes have implications across a diverse range of human activities. Details of the projections were subject to differences in RCM design, deviations between the boundary conditions of the driving GCMs, uncertainties in future emissions and random effects due to internal climate variability. A larger number of GCMs as drivers of the RCMs would most likely have resulted in somewhat wider ranges in the frost, snow and sea ice estimates than those presented in this paper.  相似文献   

Enhanced visualization of the flat landscape of the Cambridgeshire Fenlands          下载免费PDF全文

Oliver Pritchard  Timothy Farewell  Stephen Hallett 《Geology Today》2015,31(5):187-192

The Fenlands of East Anglia, England, represent a subtle landscape, where topographic highs rarely exceed 30 m above sea level. However, the fens represent an almost full sequence of Quaternary deposits which, together with islands of Cretaceous and Jurassic outcrops, make the area of geological importance. This feature discusses the advantages of using 3D visualization coupled with high‐resolution topographical data, over traditional 2D techniques, when undertaking an analysis of the landscape. Conclusions suggest that the use of 3D visualization will result in a higher level of engagement, particularly when communicating geological information to a wider public.  相似文献   

The importance of student-led initiatives in rethinking the Ph.D.     

Timothy L. Hawthorne  David Fyfe 《GeoJournal》2015,80(2):175-179

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Strength Envelopes from Single and Multi Geosynthetic Interface Tests     

Timothy D. Stark  Fawad S. Niazi  Timothy C. Keuscher 《Geotechnical and Geological Engineering》2015,33(5):1351-1367

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Reconstructing a millennial‐scale record of flooding in a single valley setting: the 2011 flood‐affected Lockyer Valley,south‐east Queensland,Australia          下载免费PDF全文

Jacky Croke  Christopher Thompson  Robert Denham  Heather Haines  Ashneel Sharma  Timothy Pietsch 《第四纪科学杂志》2016,31(8):936-952

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Long-term ecosystem and biogeochemical research in Loch Vale watershed,Rocky Mountain National Park,Colorado     

Jill S. Baron  David W. Clow  Isabella A. Oleksy  Timothy Weinmann  Caitlin Charlton  Amanda Jayo 《水文研究》2021,35(3):e14107

Loch Vale watershed was instrumented in 1983 with initial support from the National Acid Precipitation Assessment Program to ask whether ecosystems of Rocky Mountain National Park (RMNP) were affected by acidic atmospheric deposition. Research and monitoring activities were expanded in 1991 by the U.S. Geological Survey Water, Energy, and Biogeochemical Budgets program to understand the processes, and their interactions, controlling water, energy, and biogeochemical fluxes. With help from many collaborators we have characterized trends and patterns in atmospheric deposition, climate, and hydrology, including glaciers and other ice features. Instead of acidic deposition, we documented high atmospheric inputs of reactive nitrogen (Nr), and have studied the ecological consequences in soils, surface water, and vegetation. Using paleolimnology, we documented the onset of human-caused change to lake primary producers ca. 1950 in response to increased Nr deposition and warming. Our results provided the basis for the Colorado Nitrogen Deposition Reduction Plan, a state policy that aims to reduce Nr emissions to protect resources in RMNP by 2032. Carbon cycle research revealed mountain wetlands now release more carbon than they store, and respiration and methane flux occurs even during winter through deep snow packs. Trend analyses found export of Nr to be closely tied to atmospheric inputs, but can lag in response to drought. Current research explores consequences of the combination of warming, changes in precipitation dynamics, and atmospheric deposition of Nr and dust on stream and lake CO₂ dynamics, lake biology and trophic state, and soil carbon composition. Dramatic increases in park visitors have prompted studies on the effects of recreational use on water quality. New tools such as remote sensing and high frequency instream water quality sensors are being applied to lake and stream studies. Monitoring, combined with experiments, models, and spatial comparisons is an essential foundation for science-based resource management.  相似文献