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11.
Iain D. Leighton John F. Hiemstra Christoph T. Weidemann 《Boreas: An International Journal of Quaternary Research》2013,42(2):463-469
It is a scientist's mission to try to remain unbiased. However, certain factors play a role in scientific analyses that are not controlled by conscious thought. These factors are potentially very important in areas of science where interpretations are based on a scientist's ability to identify patterns or structures. One such area is the micromorphology of glacial sediments. In this paper we investigate the role of an analyst's experience in relation to pattern perception with specific reference to turbate microstructures in glacial diamictons. An experiment was conducted on 52 participants, which demonstrated that, as may be expected, more experienced (glacial) micromorphologists tend to exhibit a higher sensitivity‐to‐signal, but that complete novices, if given clear instructions, can reach levels of sensitivity similar to those of experts. It also showed, perhaps more surprisingly, that response bias does not decrease with experience. We discuss psychological factors, such as the drive for success and consistency, that may have contributed to these results and investigate their possible implications in the micromorphological analysis and interpretation of glacial sediments. 相似文献
12.
Beike Hiemstra Paolo Soleri Mariano Méndez Tomaso Belloni Reham Mostafa Rudy Wijnands 《Monthly notices of the Royal Astronomical Society》2009,394(4):2080-2088
We analysed simultaneous archival XMM–Newton and Rossi X-ray Timing Explorer observations of the X-ray binary and black hole candidate Swift J 1753.5−0127 . In a previous analysis of the same data, a soft thermal component was found in the X-ray spectrum, and the presence of an accretion disc extending close to the innermost stable circular orbit was proposed. This is in contrast with the standard picture in which the accretion disc is truncated at large radii in the low/hard state. We tested a number of spectral models and found that several of them fit the observed spectra without the need of a soft disc-like component. This result implies that the classical paradigm of a truncated accretion disc in the low/hard state cannot be ruled out by these data. We further discovered a broad iron emission line between 6 and 7 keV in these data. From fits to the line profile we found an inner disc radius that ranges between ∼6 and 16 gravitational radii, which can be in fact much larger, up to ∼250 gravitational radii, depending on the model used to fit the continuum and the line. We discuss the implications of these results in the context of a fully or partially truncated accretion disc. 相似文献
13.
Tjisse Hiemstra Willem H. Van Riemsdijk André Rossberg Kai-Uwe Ulrich 《Geochimica et cosmochimica acta》2009,73(15):4437-19695
The adsorption of uranyl (UO22+) on ferrihydrite has been evaluated with the charge distribution (CD) model for systems covering a very large range of conditions, i.e. pH, ionic strength, CO2 pressure, U(VI) concentration, and loading. Modeling suggests that uranyl forms bidentate inner sphere complexes at sites that do not react chemically with carbonate ions. Uranyl is bound by singly-coordinated surface groups present at particular edges of Fe-octahedra of ferrihydrite while another set of singly-coordinated surface groups may form double-corner bidentate complexes with carbonate ions. The uranyl surface speciation strongly changes in the presence of carbonate due to the specific adsorption of carbonate ions as well as the formation of ternary uranyl-carbonate surface complexes. Data analysis with the CD model suggests that a uranyl tris-carbonato surface complex, i.e. (UO2)(CO3)34−, is formed. This species is most abundant in systems with a high pH and carbonate concentration. This finding differs significantly from previous interpretations made in the literature. At high pH and low carbonate concentrations, as can be prepared in CO2-closed systems, the model suggests the additional presence of a ternary uranyl-monocarbonato complex. The binding mode (type A or type B complex) is uncertain. At high uranyl concentrations, uranyl polymerizes at the surface of ferrihydrite giving, for instance, tris-uranyl surface complexes with and without carbonate. The similarities and differences between U(VI) adsorption by goethite and ferrihydrite are discussed from a surface structural point of view. 相似文献
14.
Till deposition by glacier submarginal,incremental thickening 总被引：1，自引：0，他引：1
Macro‐ and micro‐scale sedimentological analyses of recently deposited tills and complex push/squeeze moraines on the forelands of Icelandic glaciers and in a stacked till sequence at the former Younger Dryas margin of the Loch Lomond glacier lobe in Scotland are used to assess the depositional processes involved in glacier submarginal emplacement of sediment. Where subglacial meltwater is unable to flush out subglacial sediment or construct thick debris‐rich basal ice by cumulative freeze‐on processes, glacier submarginal processes are dictated by seasonal cycles of refreezing and melt‐out of tills advected from up‐ice by a combination of lodgement, deformation and ice keel and clast ploughing. Although individual till layers may display typical A and B horizon deformation characteristics, the spatially and temporally variable mosaic of subglacial processes will overprint sedimentary and structural signatures on till sequences to the extent that they would be almost impossible to classify genetically in the ancient sediment record. At the macro‐scale, Icelandic tills display moderately strong clast fabrics that conform to the ice flow directions documented by surface flutings; very strong fabrics typify unequivocally lodged clasts. Despite previous interpretations of these tills as subglacial deforming layers, micro‐morphological analysis reveals that shearing played only a partial role in the emplacement of till matrixes, and water escape and sediment flowage features are widespread. A model of submarginal incremental thickening is presented as an explanation of these data, involving till slab emplacement over several seasonal cycles. Each cycle involves: (1) late summer subglacial lodgement, bedrock and sediment plucking, subglacial deformation and ice keel ploughing; (2) early winter freeze‐on of subglacial sediment to the thin outer snout; (3) late winter readvance and failure along a decollement plane within the till, resulting in the carriage of till onto the proximal side of the previous year's push moraine; (4) early summer melt‐out of the till slab, initiating porewater migration, water escape and sediment flow and extrusion. Repeated reworking of the thin end of submarginal till wedges produces overprinted strain signatures and clast pavements. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
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The Fe(II) adsorption by non-ferric and ferric (hydr)oxides has been analyzed with surface complexation modeling. The CD model has been used to derive the interfacial distribution of charge. The fitted CD coefficients have been linked to the mechanism of adsorption. The Fe(II) adsorption is discussed for TiO2, γ-AlOOH (boehmite), γ-FeOOH (lepidocrocite), α-FeOOH (goethite) and HFO (ferrihydrite) in relation to the surface structure and surface sites. One type of surface complex is formed at TiO2 and γ-AlOOH, i.e. a surface-coordinated Fe2+ ion. At the TiO2 (Degussa) surface, the Fe2+ ion is probably bound as a quattro-dentate surface complex. The CD value of Fe2+ adsorbed to γ-AlOOH points to the formation of a tridentate complex, which might be a double edge surface complex. The adsorption of Fe(II) to ferric (hydr)oxides differs. The charge distribution points to the transfer of electron charge from the adsorbed Fe(II) to the solid and the subsequent hydrolysis of the ligands that coordinate to the adsorbed ion, formerly present as Fe(II). Analysis shows that the hydrolysis corresponds to the hydrolysis of adsorbed Al(III) for γ-FeOOH and α-FeOOH. In both cases, an adsorbed M(III) is found in agreement with structural considerations. For lepidocrocite, the experimental data point to a process with a complete surface oxidation while for goethite and also HFO, data can be explained assuming a combination of Fe(II) adsorption with and without electron transfer. Surface oxidation (electron transfer), leading to adsorbed Fe(III)(OH)2, is favored at high pH (pH > ∼7.5) promoting the deprotonation of two FeIII-OH2 ligands. For goethite, the interaction of Fe(II) with As(III) and vice versa has been modeled too. To explain Fe(II)-As(III) dual-sorbate systems, formation of a ternary type of surface complex is included, which is supposed to be a monodentate As(III) surface complex that interacts with an Fe(II) ion, resulting in a binuclear bidentate As(III) surface complex. 相似文献
16.
John F. Hiemstra Bernd Kulessa Edward C. King Dimitris Ntarlagiannis 《地球表面变化过程与地形》2011,36(14):1860-1871
Despite significant advances over the past decades, our understanding of drumlin formation and associated ice‐bed processes is still incomplete. In this paper, we present the integrated use of geomorphological, sedimentological and geophysical techniques as a powerful means to force a breakthrough towards solving the drumlin enigma. We report on investigations of the anatomy of the Pigeon Point drumlin, Clew Bay, Ireland. We found that the bulk of the landform, which displays a classical drumlin shape, consists of silty‐clayey diamicton showing evidence of deformation, hydrofracturing and comminution. The unit is interpreted as a sub‐glacial traction till/comminution till. The thin unit overlying this basal till consists of silty‐sandy diamicton, and is interpreted as a para‐glacially modified melt‐out till. The partly cemented third unit consists of stratified, massive to graded sands and gravels. Its contact with the sub‐glacial traction till consists of a series of concave shapes, which suggests that it was deposited in meltwater channels that flowed in sub‐glacial cavities and that cut laterally into the drumlin. We propose that highs in the undulating rockhead relief, as shown in the seismic profile, have provided nuclei which initiated drumlin formation. This idea is supported by the observation of local detached bedrock slabs that grade upwards into a comminution till. In the long profile, very high normalized induced polarization (IP) values form a wedge‐shape, which is interpreted as a set of conjugate thrusts, or a ‘pop‐up’ structure. The structure is positioned directly above one of the undulations in the bedrock, suggesting a direct relationship. The high values are thought to reflect the presence of pre‐existing clays, which were sheared into the till, thus forming linings in the thrust features. It is concluded that glacitectonic processes, notably differential bedrock weathering and thrusting, have played a key role in the formation of this drumlin. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
17.
John F. Hiemstra David J. A. Evans Colm Ó Cofaigh 《Boreas: An International Journal of Quaternary Research》2007,36(4):386-399
Sedimentological and structural geological data from two sites in southwest Ireland and Antarctica provide evidence for the formation of subglacial till by the brecciation and crushing of bedrock rafts. Up-sequence transitions, from undisturbed bedrock, to deformed bedrock, to crushed and brecciated bedrock, to massive matrix-supported till with far-travelled erratics, represent a process-form continuum of till production. Initially, bedrock fragments and rafts up to several metres in length are liberated from the substrate by glacitectonic thrusting and plucking. These rafts are then crushed to produce the matrix of a till. Such products are commonly referred to as comminution tills, although the original definition focused primarily on the second phase of the process (crushing of bedrock rafts and fragments) as well as abrasion of bedrock. Data from Ireland and Antarctica indicate that rafting of bedrock is an essential part of the process of till formation. This process is facilitated by weak sedimentary bedrock, which can be displaced along joints and bedding planes to form rafts that are then incorporated into the 'proto-till' prior to being crushed subglacially. Our field data suggest that bedrock failure and displacement of such rafts can occur to depths of 3 m. The occurrence of erratics in the uppermost part of the till demonstrates that the glacier effectively mixes far-travelled and local materials. 相似文献
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19.
Nanoparticles in natural systems I: The effective reactive surface area of the natural oxide fraction in field samples 总被引：1，自引：0，他引：1
Information on the particle size and reactive surface area of natural samples is essential for the application of surface complexation models (SCM) to predict bioavailability, toxicity, and transport of elements in the natural environment. In addition, this information will be of great help to enlighten views on the formation, stability, and structure of nanoparticle associations of natural organic matter (NOM) and natural oxide particles.Phosphate is proposed as a natively present probe ion to derive the effective reactive surface area of natural samples. In the suggested method, natural samples are equilibrated (?10 days) with 0.5 M NaHCO3 (pH = 8.5) at various solid-solution ratios. This matrix fixes the pH and ionic strength, suppresses the influence of Ca2+ and Mg2+ ions by precipitation these in solid carbonates, and removes NOM due to the addition of activated carbon in excess, collectively leading to the dominance of the PO4-CO3 interaction in the system. The data have been interpreted with the charge distribution (CD) model, calibrated for goethite, and the analysis results in an effective reactive surface area (SA) and a reversibly bound phosphate loading Γ for a series of top soils.The oxidic SA varies between about 3-30 m2/g sample for a large series of representative agricultural top soils. Scaling of our data to the total iron and aluminum oxide content (dithionite-citrate-bicarbonate extractable), results in the specific surface area between about 200-1200 m2/g oxide for most soils, i.e. the oxide particles are nano-sized with an equivalent diameter in the order of ∼1-10 nm if considered as non-porous spheres. For the top soils, the effective surface area and the soil organic carbon fraction are strongly correlated. The oxide particles are embedded in a matrix of organic carbon (OC), equivalent to ∼1.4 ± 0.2 mg OC/m2 oxide for many soils of the collection, forming a NOM-mineral nanoparticle association with an average NOM volume fraction of ∼80%. The average mass density of such a NOM-mineral association is ∼1700 ± 100 kg/m3 (i.e. high-density NOM). The amount of reversibly bound phosphate is rather close to the amount of phosphate that is extractable with oxalate. The phosphate loading varies remarkably (Γ ≈ 1-3 μmol/m2 oxide) in the samples. As discussed in part II of this paper series (Hiemstra et al., 2010), the phosphate loading (Γ) of field samples is suppressed by surface complexation of NOM, where hydrophilic, fulvic, and humic acids act as a competitor for (an)ions via site competition and electrostatic interaction. 相似文献
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