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401.
402.
403.
Robert C. Borden Russell Todd Goin Chih-Ming Kao 《Ground Water Monitoring & Remediation》1997,17(1):70-80
A permeable barrier system. consisting of a line of closely spaced wclls. was installed perpendicular to ground water flow to control the migration of a dissolved hydrocarhon plume. The wells were charged wiih concrete briquets that release oxygen and nitrate at a controlled rate. enhancing aerobic bio-degradation in the downgradient aquifer.
Laboratory batch reactor experiments were conducted to identify concrete mixtures that slowly released oxygcn over an extended time period. Concretes prepared with urea hydrogen peroxide were unsatisfactory, while concretes prepared with calcium peroxide and a proprietary formalation of magnesium peroxide (ORC®) gradually released oxygen at a steadily declining rate. The 21 percent MgO2 conerete cylinders and briquets released oxygen at measurable rates for up to 300 days, while the 14 percent CaO2 briquets were exhausted by 100 days.
A full-scale permeable barrier system using ORC was constructed at a gasoline-spill site. During the first 242 days of operation. total BTFX decreased from 17 to 3.4 mg/L. and dissolved oxygen increased from 0.4 to 1.8 mg/L. during transport through the barrier. Over time, BTEX treatment efficiencies declined. indicating the barrier system had becomc less effective in releasing oxygen and nutrients to the highly contaminated portion of the aquifer. Point dilution tests and sediment analyses performed at the conclusion of the project indicated that ihc aquifer in the vicinity of the remediation wells had been clogged by precipitation with iron minerals. This clogging is believed to result from high pH from the concrete and oxygen released by ihc ORC. Oxygen-releasing permeable barriers and other aerobic bioremediation processes should be used with caution in aquifers with high levels of dissolved iron. 相似文献
Laboratory batch reactor experiments were conducted to identify concrete mixtures that slowly released oxygcn over an extended time period. Concretes prepared with urea hydrogen peroxide were unsatisfactory, while concretes prepared with calcium peroxide and a proprietary formalation of magnesium peroxide (ORC®) gradually released oxygen at a steadily declining rate. The 21 percent MgO
A full-scale permeable barrier system using ORC was constructed at a gasoline-spill site. During the first 242 days of operation. total BTFX decreased from 17 to 3.4 mg/L. and dissolved oxygen increased from 0.4 to 1.8 mg/L. during transport through the barrier. Over time, BTEX treatment efficiencies declined. indicating the barrier system had becomc less effective in releasing oxygen and nutrients to the highly contaminated portion of the aquifer. Point dilution tests and sediment analyses performed at the conclusion of the project indicated that ihc aquifer in the vicinity of the remediation wells had been clogged by precipitation with iron minerals. This clogging is believed to result from high pH from the concrete and oxygen released by ihc ORC. Oxygen-releasing permeable barriers and other aerobic bioremediation processes should be used with caution in aquifers with high levels of dissolved iron. 相似文献
404.
Harmful algal blooms in the Chesapeake and Coastal Bays of Maryland, USA: Comparison of 1997, 1998, and 1999 events 总被引:2,自引:0,他引:2
Patricia M. Glibert Robert Magnien Michael W. Lomas Jeffrey Alexander Chunlei Tan Erin Haramoto Mark Trice Todd M. Kana 《Estuaries and Coasts》2001,24(6):875-883
Harmful algal blooms in the Chesapeake Bay and coastal bays of Maryland, USA, are not a new phenomenon, but may be increasing in frequency and diversity. Outbreaks ofPfiesteria piscicida (Dinophyceae) were observed during 1997 in several Chesapeake Bay tributaries, while in 1998,Pfiesteria-related events were not found but massive blooms ofProrocentrum minimum (Dinophyceae) occurred. In 1999,Aureococcus anophagefferens (Pelagophyceae) developed in the coastal bays in early summer in sufficient densities to cause a brown tide. In 1997, toxicPfiesteria was responsible for fish kills at relatively low cell densities. In 1998 and 1999, the blooms ofP. minimum andA. anophagefferens were not toxic, but reached sufficiently high densities to have ecological consequences. These years differed in the amount and timing of rainfall events and resulting nutrient loading from the largely agricultural watershed. Nutrient loading to the eastern tributaries of Chesapeake Bay has been increasing over the past decade. Much of this nutrient delivery is in organic form. The sites of thePfiesteria outbreaks ranked among those with the highest organic loading of all sites monitored bay-wide. The availability of dissolved organic carbon and phosphorus were also higher at sites experiencingA. anophagefferens blooms than at those without blooms. The ability to supplement photosynthesis with grazing or organic substrates and to use a diversity of organic nutrients may play a role in the development and maintenance of these species. ForP. minimum andA. anophagefferens, urea is used preferentially over nitrate.Pfiesteria is a grazer, but also has the ability to take up nutrients directly. The timing of nutrient delivery may also be of critical importance in determining the success of certain species. 相似文献
405.
Implementation of a Locally Conservative Numerical Subgrid Upscaling Scheme for Two-Phase Darcy Flow 总被引:1,自引:0,他引:1
Todd Arbogast 《Computational Geosciences》2002,6(3-4):453-481
We present a locally mass conservative scheme for the approximation of two-phase flow in a porous medium that allows us to obtain detailed fine scale solutions on relatively coarse meshes. The permeability is assumed to be resolvable on a fine numerical grid, but limits on computational power require that computations be performed on a coarse grid. We define a two-scale mixed finite element space and resulting method, and describe in detail the solution algorithm. It involves a coarse scale operator coupled to a subgrid scale operator localized in space to each coarse grid element. An influence function (numerical Greens function) technique allows us to solve these subgrid scale problems independently of the coarse grid approximation. The coarse grid problem is modified to take into account the subgrid scale solution and solved as a large linear system of equations posed over a coarse grid. Finally, the coarse scale solution is corrected on the subgrid scale, providing a fine grid representation of the solution. Numerical examples are presented, which show that near-well behavior and even extremely heterogeneous permeability barriers and streaks are upscaled well by the technique. 相似文献
406.
407.
408.
Introduced to astronomy less than a decade ago, infrared detector arrays have radically and forever changed astronomer's observational techniques, instruments, and telescope designs. This paper first examines the array technology development that caused this change, with emphasis on the 1- to 5-m band. Technology trends and projections for further development within the infrared industry are analyzed to assist astronomers in planning future instruments. This technology development is predicted to result in arrays with lower noise, greater well depth, response to a wider band of wavelengths, and, above all, much larger formats than arrays currently in use. 相似文献
409.
Postshield volcanism and catastrophic mass wasting of the Waianae Volcano, Oahu, Hawaii 总被引:2,自引:2,他引:0
The 3.9- to 2.9-Ma Waianae Volcano is the older of two volcanoes making up the island of Oahu, Hawaii. Exposed on the volcanic
edifice are tholeiitic shield lavas overlain by transitional and alkalic postshield lavas. The postshield "alkalic cap" consists
of aphyric hawaiite of the Palehua Member of the Waianae Volcanics, overlain unconformably by a small volume of alkalic basalt
of the Kolekole Volcanics. Kolekole Volcanics mantle erosional topography, including the uppermost slopes of the great Lualualei
Valley on the lee side of the Waianae Range. Twenty new K–Ar dates, combined with magnetic polarity data and geologic relationships,
constrain the ages of lavas of the Palehua member to 3.06–2.98 Ma and lavas of the Kolekole Volcanics to 2.97–2.90 Ma. The
geochemical data and the nearly contemporaneous ages suggest that the Kolekole Volcanics do not represent a completely independent
or separate volcanic event from earlier postshield activity; thus, the Kolekole Volcanics are reduced in rank, becoming the
Kolekole Member of the Waianae Volcanics. Magmas of the Palehua and Kolekole Members have similar incompatible element ratios,
and both suites show evidence for early crystallization of clinopyroxene consistent with evolution at high pressures below
the edifice. However, lavas of the Kolekole Member are less fractionated and appear to have evolved at greater depths than
the earlier Palehua hawaiites. Postshield primary magma compositions of the Palehua and Kolekole Members are consistent with
formation by partial melting of mantle material of less than 5–10% relative to Waianae shield lavas. Within the section of
Palehua Member lavas, an increase with respect to time of highly incompatible to moderately incompatible element ratios is
consistent with a further decrease in partial melting by approximately 1–2%. This trend is reversed with the onset of eruption
of Kolekole Member lavas, where an increase in extent of partial melting is indicated. The relatively short time interval
between the eruption of Palehua and Kolekole Member lavas appears to date the initial formation of Lualualei Valley, which
was accompanied by a marked change in magmatic conditions. We speculate that the mass-wasting event separating lavas of the
Palehua and Kolekole Members may be related to the formation of a large submarine landslide west and southwest of Waianae
Volcano. Enhanced decompression melting associated with removal of the equivalent volume of this landslide deposit from the
edifice is more than sufficient to produce the modeled increase of 1–2% in extent of melting between the youngest Palehua
magmas and the posterosional magmas of the Kolekole Member. The association between magmatic change and a giant landsliding
event suggests that there may be a general relationship between large mass-wasting events and subsequent magmatism in Hawaiian
volcano evolution.
Received: 1 September 1996 / Accepted: 26 November 1996 相似文献
410.
Steve W. Lyon Arthur J. Lembo Jr. M. Todd Walter Tammo S. Steenhuis 《Advances in water resources》2006
In humid, well-vegetated areas, such as in the northeastern US, runoff is most commonly generated from relatively small portions of the landscape becoming completely saturated, however, little is known about the spatial and temporal behavior of these saturated regions. Indicator kriging provides a way to use traditional water table data to quantify probability of saturation to evaluate predicted spatial distributions of runoff generation risk, especially for the new generation of water quality models incorporating saturation excess runoff theory. When spatial measurements of a variable are transformed to binary indicators (i.e., 1 if above a given threshold value and 0 if below) and the resulting indicator semivariogram is modeled, indicator kriging produces the probability of the measured variable to exceed the threshold value. Indicator kriging gives quantified probability of saturation or, consistent with saturation excess runoff theory, runoff generation risk with depth to water table as the variable and the threshold set near the soil surface. The probability of saturation for a 120 m × 180 m hillslope based upon 43 measurements of depth to water table is investigated with indicator semivariograms for six storm events. The indicator semivariograms show high spatial structure in saturated regions with large antecedent rainfall conditions. The temporal structure of the data is used to generate interpolated (soft) data to supplement measured (hard) data. This improved the spatial structure of the indicator semivariograms for lower antecedent rainfall conditions. Probability of saturation was evaluated through indicator kriging incorporating soft data showing, based on this preliminary study, highly connected regions of saturation as expected for the wet season (April through May) in the Catskill Mountain region of New York State. Supplementation of hard data with soft data incorporates physical hydrology of the hillslope to capture significant patterns not available when using hard data alone for indicator kriging. With the need for water quality models incorporating appropriate runoff generation risk estimates on the rise, this manner of data will lay the groundwork for future model evaluation and development. 相似文献