A 500 hPa synoptic wildland fire climatology for large Canadian forest fires, 1959–1996     

W. R. Skinner  M. D. Flannigan  B. J. Stocks  D. L. Martell  B. M. Wotton  J. B. Todd  J. A. Mason  K. A. Logan  E. M. Bosch 《Theoretical and Applied Climatology》2002,71(3-4):157-169

Summary In Canada, the average annual area of burned forest has increased from around 1 million ha in the 1970’s to over 2.5 million ha in the 1990’s. A previous study has identified the link between anomalous mid-tropospheric circulation at 500 hPa over northern North America and wildland fire severity activity in various large regions of Canada over the entire May to August fire season. In this study, a northern North American study region of the hemispheric gridded 5° latitude by 10° longitude 500 hPa dataset is identified and analysed from 1959 to 1996 for a sequence of six monthly periods through the fire season, beginning in April and ending in September. Synoptic types, or modes of upper air behavior, are determined objectively by the eigenvector method employing K-means cluster analysis. Monthly burned areas from the Canadian Large Fire Database (LFDB) for the same period, 1959 to 1996, are analysed in conjunction with the classified monthly 500 hPa synoptic types. Relationships between common monthly patterns of anomalous upper flow and spatial patterns of large fire occurrence are examined at the ecozone level. Average occurrence of a monthly synoptic type associated with very large area burned is approximately 18% of the years from 1959 to 1996. The largest areas burned during the main fire (May to August) season occur in the western Boreal and Taiga ecozones – the Taiga Plains, Taiga Shield, Boreal West Shield and Boreal Plains. Monthly burned areas are also analysed temporally in conjunction with a calculated monthly zonal index (Zi_m) for two separate areas defined to cover western and eastern Canada. In both western and eastern Canada, high area burned is associated with synoptic types with mid-tropospheric ridging in the proximity of the affected region and low Zi_m with weak westerlies and strong meridional flow over western Canada. Received April 3, 2001 Revised July 13, 2001  相似文献   

CO₂ solubility and speciation in intermediate (andesitic) melts: the role of H₂O and composition     

P.L. King  J.R. Holloway 《Geochimica et cosmochimica acta》2002,66(9):1627-1640

We determined total CO₂ solubilities in andesite melts with a range of compositions. Melts were equilibrated with excess C-O(-H) fluid at 1 GPa and 1300°C then quenched to glasses. Samples were analyzed using an electron microprobe for major elements, ion microprobe for C-O-H volatiles, and Fourier transform infrared spectroscopy for molecular H₂O, OH⁻, molecular CO₂, and CO₃²⁻. CO₂ solubility was determined in hydrous andesite glasses and we found that H₂O content has a strong influence on C-O speciation and total CO₂ solubility. In anhydrous andesite melts with ∼60 wt.% SiO₂, total CO₂ solubility is ∼0.3 wt.% at 1300°C and 1 GPa and total CO₂ solubility increases by about 0.06 wt.% per wt.% of total H₂O. As total H₂O increases from ∼0 to ∼3.4 wt.%, molecular CO₂ decreases (from 0.07 ± 0.01 wt.% to ∼0.01 wt.%) and CO₃²⁻ increases (from 0.24 ± 0.04 wt.% to 0.57 ± 0.09 wt.%). Molecular CO₂ increases as the calculated mole fraction of CO₂ in the fluid increases, showing Henrian behavior. In contrast, CO₃²⁻ decreases as the calculated mole fraction of CO₂ in the fluid increases, indicating that CO₃²⁻ solubility is strongly dependent on the availability of reactive oxygens in the melt. These findings have implications for CO₂ degassing. If substantial H₂O is present, total CO₂ solubility is higher and CO₂ will degas at relatively shallow levels compared to a drier melt. Total CO₂ solubility was also examined in andesitic glasses with additional Ca, K, or Mg and low H₂O contents (<1 wt.%). We found that total CO₂ solubility is negatively correlated with (Si + Al) cation mole fraction and positively correlated with cations with large Gibbs free energy of decarbonation or high charge-to-radius ratios (e.g., Ca). Combining our andesite data with data from the literature, we find that molecular CO₂ is more abundant in highly polymerized melts with high ionic porosities (>∼48.3%), and low nonbridging oxygen/tetrahedral oxygen (<∼0.3). Carbonate dominates most silicate melts and is most abundant in depolymerized melts with low ionic porosities, high nonbridging oxygen/tetrahedral oxygen (>∼0.3), and abundant cations with large Gibbs free energy of decarbonation or high charge-to-radius ratio. In natural silicate melt, the oxygens in the carbonate are likely associated with tetrahedral and network-modifying cations (including Ca, H, or H-bonds) or a combinations of those cations.  相似文献   

Turquoise   总被引：1，自引：0，他引：1  

R. J. King 《Geology Today》2002,18(3):110-114

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Gravity evidence for a larger Limpopo Belt in southern Africa and geodynamic implications   总被引：2，自引：0，他引：2  

R. T. Ranganai  A. B. Kampunzu  E. A. Atekwana  B. K. Paya  J. G. King  D. I. Koosimile  E. H. Stettler 《Geophysical Journal International》2002,149(3):F9-F14

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On the land use in Three Gorges Reservoir area     

HE Longhua  Lorenz King  JIANG Tong 《地理学报》2003,13(4):416-422

In this study the arable land changes in two counties (Zigui and Xingshan) in the Three Gorges Reservoir area in China are investigated. The statistical data from the officially published statistical books are used to study these changes in the two counties during the past 50 years since 1949. The changes of arable land, changes of arable land per capita, and changes of multiple crop index in Zigui and Xingshan counties are examined. Using an index method, we conclude that the two counties are critical in the sustainable utilization of arable land.  相似文献   

Surface oxidation of pyrite under ambient atmospheric and aqueous (pH = 2 to 10) conditions: electronic structure and mineralogy from X-ray absorption spectroscopy     

E.C Todd 《Geochimica et cosmochimica acta》2003,67(5):881-893

The nature of the surface oxidation phase on pyrite, FeS₂, reacted in aqueous electrolytes at pH = 2 to 10 and with air under ambient atmospheric conditions was studied using synchrotron-based oxygen K edge, sulfur L_III edge, and iron L_II,III edge X-ray absorption spectroscopy. We demonstrate that O K edge X-ray absorption spectra provide a sensitive probe of sulfide surface oxidation that is complementary to X-ray photoelectron spectroscopy. Using total electron yield detection, the top 20 to 50 Å of the pyrite surface is characterized. In air, pyrite oxidizes to form predominantly ferric sulfate. In aqueous air-saturated solutions, the surface oxidation products of pyrite vary with pH, with a marked transition occurring around pH 4. Below pH = 4, a ferric (hydroxy)sulfate is the main oxidation product on the pyrite surface. At higher pH, we find iron(III) oxyhydroxide in addition to ferric (hydroxy)sulfate on the surface. Under the most alkaline conditions, the O K edge spectrum closely resembles that of goethite, FeOOH, and the surface is oxidized to the extent that no FeS₂ can be detected in the X-ray absorption spectra. In a 1.667 × 10⁻³ mol/L Fe³⁺ solution with ferric iron present as FeCl₃ in NaCl, the oxidation of pyrite is autocatalyzed, and formation of the surface iron(III) oxyhydroxide phase is promoted at low pH.  相似文献   

Recent Rapid Regional Climate Warming on the Antarctic Peninsula   总被引：15，自引：1，他引：15  

David G. Vaughan  Gareth J. Marshall  William M. Connolley  Claire Parkinson  Robert Mulvaney  Dominic A. Hodgson  John C. King  Carol J. Pudsey  John Turner 《Climatic change》2003,60(3):243-274

The Intergovernmental Panel on Climate Change (IPCC) confirmed that mean global warming was 0.6 ± 0.2 °C during the 20th century and cited anthropogenic increases in greenhouse gases as the likely cause of temperature rise in the last 50 years. But this mean value conceals the substantial complexity of observed climate change, which is seasonally- and diurnally-biased, decadally-variable and geographically patchy. In particular, over the last 50 years three high-latitude areas have undergone recent rapid regional (RRR) warming, which was substantially more rapid than the global mean. However, each RRR warming occupies a different climatic regime and may have an entirely different underlying cause. We discuss the significance of RRR warming in one area, the Antarctic Peninsula. Here warming was much more rapid than in the rest of Antarctica where it was not significantly different to the global mean. We highlight climate proxies that appear to show that RRR warming on the Antarctic Peninsula is unprecedented over the last two millennia, and so unlikely to be a natural mode of variability. So while the station records do not indicate a ubiquitous polar amplification of global warming, the RRR warming on the Antarctic Peninsula might be a regional amplification of such warming. This, however, remains unproven since we cannot yet be sure what mechanism leads to such an amplification. We discuss several possible candidate mechanisms: changing oceanographic or changing atmospheric circulation, or a regional air-sea-ice feedback amplifying greenhouse warming. We can show that atmospheric warming and reduction in sea-ice duration coincide in a small area on the west of the Antarctic Peninsula, but here we cannot yet distinguish cause and effect. Thus for the present we cannot determine which process is the probable cause of RRR warming on the Antarctic Peninsula and until the mechanism initiating and sustaining the RRR warming is understood, and is convincingly reproduced in climate models, we lack a sound basis for predicting climate change in this region over the coming century.  相似文献   

A Case Study of Satellite Synthetic Aperture Radar Signatures of Spatially Evolving Atmospheric Convection over the Western Atlantic Ocean     

Steven M. Babin  Todd D. Sikora  Nathaniel S. Winstead 《Boundary-Layer Meteorology》2003,106(3):527-546

A case study of a particularly intense cold air outbreak over the northAtlantic Ocean extending from the northeast coast of the UnitedStates to the Gulf Stream is described. A RADARSAT satellite synthetic apertureradar (SAR) image of this outbreak dramatically illustrates the spatialevolution of convection. Nearly coincident images from the National Oceanic and Atmospheric Administration's Advanced Very HighResolution Radiometer are used to compare many interesting features.In addition, National Weather Service rawinsonde data, National Data Buoy Center buoy data, and Woods Hole Oceanographic Institute Coastal Mixing and Optics mooring data arepresented. We use these data to help describe the spatial evolution of the atmospheric boundary-layer processes involved in this outbreak.Rows of cellular convective clouds begin to appear some distance offshore and then slowly increase in horizontal diameter and wavelength in the downwind direction, with a subsequent jump in cloud diameter downwind of the Gulf Stream North Wall (GSNW). The SAR image shows a similar evolution of sea-surface footprints of these boundary-layer features. This change in boundary-layer structure is attributed to corresponding changes in static stability. About 300 km south of the GSNW in the SAR image, an even larger jump in cell diameter appears and the cells becomenon-uniform with bright crescents and filled semi-circles on thedownwind sides of the cells. These are believed to be surface effectsof gust fronts induced by the mesoscale cellular convection and enhanced by the overall northwesterly flow.  相似文献   

The Darwin Rise demise: the western Pacific guyot heights trace the trans-Pacific Mendocino fracture zone     

N. Christian Smoot  Robert E. King 《Geomorphology》1997,18(3-4)

The Darwin Rise has been proposed so many times and in so many forms and places that the time has come to make a more comprehensive examination of the region. Lying on the NW Pacific Plate between the Geisha Guyots, the Mid-Pacific Mountains, the equator, and the trenches, the region is roughly bounded by magnetic anomaly M20 (147 Ma). It was subjected to a massive outpouring of lava about 105 to 120 Ma, which created the guyots and seamounts in that region. Guyots are excellent tools for studying events of long ago because they eroded in the same lowstand in the Cretaceous and guyot relief, therefore, is a surrogate for paleo-sealevel. The relief is derived by subtracting the break depth of the summit plateau of a guyot from the regional depth. Guyot relief would necessarily be less in the center than to the periphery if the feature formed on a pre-existing rise, as has been postulated. The existence of a paleo-Darwin Rise would give concentric contours for the region in question. Of the sixty guyots used in this study, thirty-seven of these guyots were surveyed using SASS multibeam in the Marcus-Wake seamount group. Twenty-three guyots were surveyed using random track single-beam sonar surveys. An entirely different scenario is shown. Data revealed a major fracture passing through the area coevally or after the guyots formed. Because the depths to the summit are not the same now, vertical tectonics occurred after subaerial erosion. This means the fracture formed during and after the erosion (roughly 105 Ma) and influenced the normal sequence of events in guyot formation. Depending on how one deciphers trends through the Hess Rise morass, SASS bathymetry shows a continuation of the Surveyor/Mendocino fracture zone swarm inside the M20 region to the NE of these data. The fracture swarm continues to the western Pacific trench system. Based on this information, if the Darwin Rise ever existed, it had to have done so elsewhere.  相似文献   

Magmatic processes that generated the rhyolite of Glass Mountain, Medicine Lake volcano, N. California   总被引：13，自引：1，他引：13  

Timothy L. Grove  Julie M. Donnelly-Nolan  Todd Housh 《Contributions to Mineralogy and Petrology》1997,127(3):205-223

Glass Mountain consists of a 1 km³, compositionally zoned rhyolite to dacite glass flow containing magmatic inclusions and xenoliths of underlying shallow crust. Mixing of magmas produced by fractional crystallization of andesite and crustal melting generated the rhyolite of Glass Mountain. Melting experiments were carried out on basaltic andesite and andesite magmatic inclusions at 100, 150 and 200 MPa, H₂O-saturated with oxygen fugacity controlled at the nickel-nickel oxide buffer to provide evidence of the role of fractional crystallization in the origin of the rhyolite of Glass Mountain. Isotopic evidence indicates that the crustal component assimilated at Glass Mountain constitutes at least 55 to 60% of the mass of erupted rhyolite. A large volume of mafic andesite (2 to 2.5 km³) periodically replenished the magma reservoir(s) beneath Glass Mountain, underwent extensive fractional crystallization and provided the heat necessary to melt the crust. The crystalline residues of fractionation as well as residual liquids expelled from the cumulate residues are preserved as magmatic inclusions and indicate that this fractionation process occurred at two distinct depths. The presence and composition of amphibole in magmatic inclusions preserve evidence for crystallization of the andesite at pressures of at least 200 MPa (6 km depth) under near H₂O-saturated conditions. Mineralogical evidence preserved in olivine-plagioclase and olivine-plagioclase-high-Ca clinopyroxene-bearing magmatic inclusions indicates that crystallization under near H₂O-saturated conditions also occurred at pressures of 100 MPa (3 km depth) or less. Petrologic, isotopic and geochemical evidence indicate that the andesite underwent fractional crystallization to form the differentiated melts but had no chemical interaction with the melted crustal component. Heat released by the fractionation process was responsible for heating and melting the crust. Received: 26 March 1996 / Accepted: 14 November 1996  相似文献