The Application of Petroleum Hydrocarbon Fingerprint Characterization in Site Investigation and Remediation     

Dawn A. Zemo  James E. Bruya  Tom E. Graf 《Ground Water Monitoring & Remediation》1995,15(2):147-156

Tremendous resources have been and continue to be spent investigating and remediating petroleum hydrocarbon compounds (PHCs) in soil and ground water. Investigating and planning a remedial strategy for sites affected by PHCs is often a challenging task because of the complex chemical nature of the PHCs. the complex regulatory environment related to PHC cleanup, and the use of analytical methods that provide quantitation but not identification of PHCs. From a technical standpoint, the PHC impacting soil and/or ground water is frequently inadequately characterised, both in identification as well as in is general properties (solubility, toxicity). From a regulatory standpoint, promulgated or recommended total petroleum hydrocarbon (TPH) cleanup levels generally relate to assumed properties of specific unweathered products and are inconsistent among different agencies and regions. This produces a prime situation for unwillingly spending more resources on investigation or remediation than may be necessary, especially when the PHC in the subsurface has different properties from unweathered products such as gasoline or diesel.
Accurately identifying the PHC and its nature, a process known as fingerprint characterization, is critical to the determination of appropriate regulatory goals and design of cost-effective remedial approaches. This paper presents several case studies in which fingerprint characterization made a significant difference in the project outcome. In each instance the nature of the organic material was better understood, the regulatory cleanup levels were negotiated based on the nature of the material, and a remedial approach was implemented that differed significantly from and was generally less costly than what would have been required without fingerprint characterization data.  相似文献   

Dissolution of secondary copper sulphides using complex-forming agents (EDTA,EDA). Part I: Covellite dissolution in EDTA and EDA     

J. Tomásek  L. Neumann 《International Journal of Mineral Processing》1982,9(1):23-40

Problems of dissolution of the so-called secondary copper sulphides are very important for dynamic as well as percolation leaching of ores. This paper deals with dissolution kinetics of sulphides in an alkaline medium, using complex-forming agents in connection with possibility to leach basic, partially oxidized ores. Natural minerals and their polydispersions were investigated and the so-called geometrical model was used for evaluation. Basic dependences of the dissolution rate on the reagent concentration and pH value of the leaching solution were found and an attempt at their mathematical expression and physical interpretation was made. The first part of this work refers to the systems of covellite-ethylene diamine tetra-acetic acid (EDTA) and covellite-ethylene diamine (EDA). The established dependences are not only of theoretical but also of practical importance.  相似文献   

Dissolution of secondary copper sulphides using complex-forming agents (EDTA,EDA). Part II: Chalcocite dissolution in EDTA and EDA     

J. Tomášek  L. Neumann 《International Journal of Mineral Processing》1982,9(1):41-57

This work is immediate continuation of Part I, using an identical method and evaluation for kinetic studies. The systems chalcocite-ethylene diamine tetra-acetic acid and chalcocite-ethylene diamine were studied. It was necessary to refine the geometrical model method for chalcocite in order to establish dissolution kinetics of polydispersions. This work confirms that chalcocite leaching proceeds through covellite even in the medium of complex-forming agents and kinetic equations for both leaching stages were evaluated with an attempt at physical interpretation.  相似文献   

Modelling nearshore oil slick trajectories     

Tom Beer  R.B. Humphries  Ron Bouwhuis 《Marine pollution bulletin》1983,14(4):141-144

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Inference of mantle viscosity from GRACE and relative sea level data   总被引：12，自引：0，他引：12  

Archie Paulson  Shijie Zhong  John Wahr 《Geophysical Journal International》2007,171(2):497-508

Gravity Recovery And Climate Experiment (GRACE) satellite observations of secular changes in gravity near Hudson Bay, and geological measurements of relative sea level (RSL) changes over the last 10 000 yr in the same region, are used in a Monte Carlo inversion to infer-mantle viscosity structure. The GRACE secular change in gravity shows a significant positive anomaly over a broad region (>3000 km) near Hudson Bay with a maximum of ∼2.5 μGal yr⁻¹ slightly west of Hudson Bay. The pattern of this anomaly is remarkably consistent with that predicted for postglacial rebound using the ICE-5G deglaciation history, strongly suggesting a postglacial rebound origin for the gravity change. We find that the GRACE and RSL data are insensitive to mantle viscosity below 1800 km depth, a conclusion similar to that from previous studies that used only RSL data. For a mantle with homogeneous viscosity, the GRACE and RSL data require a viscosity between  1.4 × 10²¹  and  2.3 × 10²¹  Pa s. An inversion for two mantle viscosity layers separated at a depth of 670 km, shows an ensemble of viscosity structures compatible with the data. While the lowest misfit occurs for upper- and lower-mantle viscosities of  5.3 × 10²⁰  and  2.3 × 10²¹  Pa s, respectively, a weaker upper mantle may be compensated by a stronger lower mantle, such that there exist other models that also provide a reasonable fit to the data. We find that the GRACE and RSL data used in this study cannot resolve more than two layers in the upper 1800 km of the mantle.  相似文献   

Early diagenetic greigite as a recorder of the palaeomagnetic signal in Miocene–Pliocene sedimentary rocks of the Carpathian foredeep (Romania)     

Iuliana Vasiliev  Mark J. Dekkers  Wout Krijgsman  Christine Franke  Cor G. Langereis  Tom A. T. Mullender 《Geophysical Journal International》2007,171(2):613-629

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Embedding reach-scale fluvial dynamics within the CAESAR cellular automaton landscape evolution model   总被引：2，自引：2，他引：2  

Marco J. Van De Wiel  Tom J. Coulthard  Mark G. Macklin  John Lewin 《Geomorphology》2007,90(3-4):283

We introduce a new computational model designed to simulate and investigate reach-scale alluvial dynamics within a landscape evolution model. The model is based on the cellular automaton concept, whereby the continued iteration of a series of local process ‘rules’ governs the behaviour of the entire system. The model is a modified version of the CAESAR landscape evolution model, which applies a suite of physically based rules to simulate the entrainment, transport and deposition of sediments. The CAESAR model has been altered to improve the representation of hydraulic and geomorphic processes in an alluvial environment. In-channel and overbank flow, sediment entrainment and deposition, suspended load and bed load transport, lateral erosion and bank failure have all been represented as local cellular automaton rules. Although these rules are relatively simple and straightforward, their combined and repeatedly iterated effect is such that complex, non-linear geomorphological response can be simulated within the model. Examples of such larger-scale, emergent responses include channel incision and aggradation, terrace formation, channel migration and river meandering, formation of meander cutoffs, and transitions between braided and single-thread channel patterns. In the current study, the model is illustrated on a reach of the River Teifi, near Lampeter, Wales, UK.  相似文献   

Conditioning Geologic Models to Local Continuity Azimuth in Spectral Simulation     

Tingting Yao  Craig Calvert  Tom Jones  Lincoln Foreman  Glen Bishop 《Mathematical Geology》2007,39(3):349-354

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Certainty, uncertainty, and the spatiality of disease: a West Nile Virus example     

Tom Koch  Kenneth Denike 《Stochastic Environmental Research and Risk Assessment (SERRA)》2007,21(5):523-531

The problem is not uncertainty—proposed here as an inevitable condition—but the chimera of certainty asserted by most contemporary researchers. Problems of data definition, collection, and their use are reviewed in terms of spatial epidemiology and health data with examples drawn from several areas of contemporary health research. The argument is that preconceptions limit data modeled in a manner assuming its completeness. The result, as the West Nile Virus example seeks to demonstrate, may obscure other patterns and limit avenues of research.  相似文献   

GPS/GNSS Current Bibliography     

Tomás Soler 《GPS Solutions》2002,6(3):206-208

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