Heavily metamorphosed clasts from the CV chondrite breccias Mokoia and Yamato‐86009     

Kaori JOGO  Kazuhide NAGASHIMA  Ian D. HUTCHEON  Alexander N. KROT  Tomoki NAKAMURA 《Meteoritics & planetary science》2012,47(12):2251-2268

Abstract– Metamorphosed clasts in the CV carbonaceous chondrite breccias Mokoia and Yamato‐86009 (Y‐86009) are coarse‐grained, granular, polymineralic rocks composed of Ca‐bearing (up to 0.6 wt% CaO) ferroan olivine (Fa_34–39), ferroan Al‐diopside (Fs_9–13Wo_47–50, approximately 2–7 wt% Al₂O₃), plagioclase (An_37–84Ab_63–17), Cr‐spinel (Cr/(Cr + Al) = 0.19–0.45, Fe/(Fe + Mg) = 0.60–0.79), nepheline, pyrrhotite, pentlandite, Ca‐phosphate, and rare grains of Ni‐rich taenite; low‐Ca pyroxene is absent. Most clasts have triple junctions between silicate grains, indicative of prolonged thermal annealing. Based on the olivine‐spinel and pyroxene thermometry, the estimated metamorphic temperature recorded by the clasts is approximately 1100 K. Few clasts experienced thermal metamorphism to a lower degree and preserved chondrule‐like textures. The Mokoia and Y‐86009 clasts are mineralogically unique and different from metamorphosed chondrites of known groups (H, L, LL, R, EH, EL, CO, CK) and primitive achondrites (acapulcoites, brachinites, lodranites). On a three‐isotope oxygen diagram, compositions of olivine in the clasts plot along carbonaceous chondrite anhydrous mineral line and the Allende mass‐fractionation line, and overlap with those of the CV chondrule olivines; the Δ¹⁷O values of the clasts range from about ?4.3‰ to ?3.0‰. We suggest that the clasts represent fragments of the CV‐like material that experienced metasomatic alteration, high‐temperature metamorphism, and possibly melting in the interior of the CV parent asteroid. The lack of low‐Ca pyroxene in the clasts could be due to its replacement by ferroan olivine during iron‐alkali metasomatic alteration or by high‐Ca ferroan pyroxene during melting under oxidizing conditions.  相似文献   

Dynamical seasonal prediction of Southern African summer precipitation     

Chaoxia Yuan  Tomoki Tozuka  Willem A. Landman  Toshio Yamagata 《Climate Dynamics》2014,42(11-12):3357-3374

Prediction skill for southern African (16°–33°E, 22°–35°S) summer precipitation in the Scale Interaction Experiment-Frontier coupled model is assessed for the period of 1982–2008. Using three different observation datasets, deterministic forecasts are evaluated by anomaly correlation coefficients, whereas scores of relative operating characteristic and relative operating level are used to evaluate probabilistic forecasts. We have found that these scores for December–February precipitation forecasts initialized on October 1st are significant at 95 % confidence level. On a local scale, the level of prediction skill in the northwestern and central parts of southern Africa is higher than that in northeastern South Africa. El Niño/Southern Oscillation (ENSO) provides the major source of predictability, but the relationship with ENSO is too strong in the model. The Benguela Niño, the basin mode in the tropical Indian Ocean, the subtropical dipole modes in the South Atlantic and the southern Indian Oceans and ENSO Modoki may provide additional sources of predictability. Within the wet season from October to the following April, the precipitation anomalies in December-February are the most predictable. This study presents promising results for seasonal prediction of precipitation anomaly in the extratropics, where seasonal prediction has been considered a difficult task.  相似文献   

Formation of a solid solution in the MgSiO3–MnSiO3 perovskite system     

Lin Li  Takaya Nagai  Tomoki Ishido  Satoko Motai  Kiyoshi Fujino  Shoichi Itoh 《Physics and Chemistry of Minerals》2014,41(6):431-437

Experiments using laser-heated diamond anvil cells combined with synchrotron X-ray diffraction and SEM–EDS chemical analyses have confirmed the existence of a complete solid solution in the MgSiO₃–MnSiO₃ perovskite system at high pressure and high temperature. The (Mg, Mn)SiO₃ perovskite produced is orthorhombic, and a linear relationship between the unit cell parameters of this perovskite and the proportion of MnSiO₃ components incorporated seems to obey Vegard’s rule at about 50 GPa. The orthorhombic distortion, judged from the axial ratios of a/b and \( \sqrt{2}\,a/c, \) monotonically decreases from MgSiO₃ to MnSiO₃ perovskite at about 50 GPa. The orthorhombic distortion in (Mg_0.5, Mn_0.5)SiO₃ perovskite is almost unchanged with increasing pressure from 30 to 50 GPa. On the other hand, that distortion in (Mg_0.9, Mn_0.1)SiO₃ perovskite increases with pressure. (Mg, Mn)SiO₃ perovskite incorporating less than 10 mol% of MnSiO₃ component is quenchable. A value of the bulk modulus of 256(2) GPa with a fixed first pressure derivative of four is obtained for (Mg_0.9, Mn_0.1)SiO₃. MnSiO₃ is the first chemical component confirmed to form a complete solid solution with MgSiO₃ perovskite at the P–T conditions present in the lower mantle.  相似文献