The role of water in the deep upper mantle and transition zone: dehydration of stagnant slabs and its effects on the big mantle wedge     

E. Ohtani  D. Zhao 《Russian Geology and Geophysics》2009,50(12):1073-1078

Mineral physics data related to the deep dehydration of stagnant slabs are summarized. The hydrogen diffusion in minerals of the mantle transition zone is not fast enough to homogenize the transition zone on the geological time scale, and hydrogen is expected to be unevenly distributed there. The hydrous fluid formed in the transition zone tends to percolate into shallower depths to form gravitationally stable hydrous magmas at the base of the upper mantle. We need further studies on the relation of intraplate volcanism above the stagnant slab and deep dehydration, because we expect the geochemical fingerprints of deep dehydration to be quite different from those of shallow dehydration from the subducting slabs.  相似文献   

Three-dimensional analysis of groundwater flow in neogene rocks at the Rokkasho low-level radioactive waste disposal center, Japan     

Tai Sasaki  Naro Hashimoto  Takayuki Nakato  Tomonari Shiraishi  Kazuaki Yajima  Tomoyuki Hishiya 《Engineering Geology》1998,49(3-4):337-343

As a preliminary step for predicting groundwater flow in a plateau 30–50 m above sea level, a model for three-dimensional analysis of groundwater flow was formulated and its validity was verified. The plateau consists of Neogene sedimentary rocks and a Quaternary deposit. Most of the groundwater originates in precipitation, with the groundwater table lying in the Quaternary deposit. Steady-state analysis was conducted by using the finite element method. The results of pore-water pressure measurement and water examination were useful in verifying the validity of the model. In constructing the model, reducing the hydraulic conductivity according to the depth on the basis of the results of the actual measurement was important.  相似文献   

Experimental investigation of the α-β transformation of San Carlos olivine single crystal     

T. Kubo  E. Ohtani  T. Kato  T. Shinmei  K. Fujino 《Physics and Chemistry of Minerals》1998,26(1):1-6

Single crystalline San Carlos olivine (1 mm cube) was transformed to (Mg,Fe)₂SiO₄β-phase at 13.5–15 GPa, 1030–1330 °C for 0–600 min using a multi-anvil high pressure apparatus. The α-β transformation occurred by incoherent surface nucleation and interface-controlled growth and recovered partially transformed samples showed sharply defined reaction rim. The growth rate of the β-phase rim significantly decreased with time and the growth eventually ceased. TEM observations revealed that many dislocations were created in both the relict olivine just near the α-β interface and the β-phase in the rim, which show evidence for deformation caused by interfacial stresses associated with the misfit elastic strain of the transformation. The observed tangled dislocation texture in β-phase suggested that the β-phase rim was hardened and relaxation of the interfacial stress was retarded. This probably caused a localized pressure drop in the relict olivine and decreased the growth rate. Time-dependent growth rates of β-phase is possibly controlled by the rheology of β-phase, which must be considered for the prediction of the olivine metastability in the subducting slabs. Received: 24 January 1997 / Revised, accepted: 24 July 1998  相似文献   

Mg–Fe interdiffusion rates in wadsleyite and the diffusivity jump at the 410-km discontinuity     

T.?KuboEmail author  A.?Shimojuku  E.?Ohtani 《Physics and Chemistry of Minerals》2004,31(7):456-464

Mg–Fe interdiffusion rates have been measured in wadsleyite aggregates at 16.0–17.0 GPa and 1230–1530 °C by the diffusion couple method. Oxygen fugacity was controlled using the NNO buffer, and water contents of wadsleyite were measured by infrared spectroscopy. Measured asymmetric diffusion profiles, analyzed using the Boltzmann–Matano equation, indicate that the diffusion rate increases with increasing iron concentration and decreasing grain size. In the case of wadsleyite containing 50–90 weight ppm H₂O, the Mg–Fe interdiffusion coefficients at compositions of Mg/(Mg + Fe)=0.95 in the coarse-grained region (about 60 m) and 0.90 in the fine-grained region (about 6 m) were determined to be a D_Xmg = 0.95 (m² s^–1)=1.24 × 10^–9 exp[–172 (kJ mol^–1)/RT] and D_Xmg = 0.90 (m² s^–1)=1.77 × 10^–9 exp[–143 (kJ mol^–1)/RT], respectively. Grain-boundary diffusion rates were estimated to be about 4 orders of magnitude faster than the volume diffusion rate. Grain-boundary diffusion dominates when the grain size is less than a few tens of microns. Results for the nominally dry diffusion couple in the present study are roughly consistent with previous studies, taking into account differences in pressure and grain size, although water contents of samples were not clear in previous studies. We observed that the diffusivity is enhanced by about 1 order of magnitude in wadsleyite containing 300–2100 wt. ppm H₂O at 1230 °C, which is almost identical to the enhancement associated with a 300 °C increase in temperature. It is still not conclusive that a jump in diffusivity exists between olivine and wadsleyite because water contents of olivine in previous diffusion studies and effects of water on the olivine diffusivity are uncertain.  相似文献   

Detailed Observation of Spatial Abundance of Clam Larva Ruditapes philippinarum in Tokyo Bay, Central Japan     

Tomoyuki Kasuya  Masami Hamaguchi  Keita Furukawa 《Journal of Oceanography》2004,60(3):631-636

The spatial distribution of the larval abundance of the clam Ruditapes philippinarum has been investigated at 65 stations throughout Tokyo Bay on August 2, 2001. The large number of small D-shaped larvae that were found shortly after hatching in the waters around the Banzu, Futtu, and Sanmaizu-Haneda areas indicates that spawning populations in these areas probably contribute greatly to the larval supply in the bay. Small larvae also occurred abundantly around the Yokohama and Ichihara port areas, suggesting that these port regions play a role in the transport of larvae into Tokyo Bay. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Experimental degradation of crude oil by marine bacteria     

Shinichi Nagata  Goro Kondo  Tomoyuki Asano 《Journal of Oceanography》1978,34(3):105-107

The ability of biodegradation for crude oil was examined for ten strains of marine bacteria. With regard to their degradation ability forn-alkanes the microorganisms tested could be divided into four groups, although the same result was not observed for microbial degradation of aromatic hydrocarbons obtained by the UV measurements.  相似文献   

Thermoelastic properties of chromium oxide Cr<Subscript>2</Subscript>O<Subscript>3</Subscript> (eskolaite) at high pressures and temperatures     

Anna M. Dymshits  Peter I. Dorogokupets  Igor S. Sharygin  Konstantin D. Litasov  Anton Shatskiy  Sergey V. Rashchenko  Eiji Ohtani  Akio Suzuki  Yuji Higo 《Physics and Chemistry of Minerals》2016,43(6):447-458

A new synchrotron X-ray diffraction study of chromium oxide Cr₂O₃ (eskolaite) with the corundum-type structure has been carried out in a Kawai-type multi-anvil apparatus to pressure of 15 GPa and temperatures of 1873 K. Fitting the Birch–Murnaghan equation of state (EoS) with the present data up to 15 GPa yielded: bulk modulus (K _0,T0), 206 ± 4 GPa; its pressure derivative K′_0,T , 4.4 ± 0.8; (?K _0,T /?T) = ?0.037 ± 0.006 GPa K^?1; a = 2.98 ± 0.14 × 10^?5 K^?1 and b = 0.47 ± 0.28 × 10^?8 K^?2, where α _0,T  = a + bT is the volumetric thermal expansion coefficient. The thermal expansion of Cr₂O₃ was additionally measured at the high-temperature powder diffraction experiment at ambient pressure and α _0,T0 was determined to be 2.95 × 10^?5 K^?1. The results indicate that coefficient of the thermal expansion calculated from the EoS appeared to be high-precision because it is consistent with the data obtained at 1 atm. However, our results contradict α ₀ value suggested by Rigby et al. (Brit Ceram Trans J 45:137–148, 1946) widely used in many physical and geological databases. Fitting the Mie–Grüneisen–Debye EoS with the present ambient and high-pressure data yielded the following parameters: K _0,T0 = 205 ± 3 GPa, K′_0,T  = 4.0, Grüneisen parameter (γ ₀) = 1.42 ± 0.80, q = 1.82 ± 0.56. The thermoelastic parameters indicate that Cr₂O₃ undergoes near isotropic compression at room and high temperatures up to 15 GPa. Cr₂O₃ is shown to be stable in this pressure range and adopts the corundum-type structure. Using obtained thermoelastic parameters, we calculated the reaction boundary of knorringite formation from enstatite and eskolaite. The Clapeyron slope (with \({\text{d}}P/{\text{d}}T = - 0.014\) GPa/K) was found to be consistent with experimental data.  相似文献   

The high-pressure phase relation of the MgSO₄-H₂O system and its implication for the internal structure of Ganymede     

Ryo Nakamura  Eiji Ohtani 《Icarus》2011,211(1):648-654

We have determined the phase relation of the MgSO₄-H₂O binary system using an externally heated diamond anvil cell in the compositional range of 0-30 wt.% MgSO₄, and under temperature and pressure conditions from 298 to 500 K and up to 4.5 GPa. Using our experimental results, we were able to estimate the composition of the ice mantle of the large icy satellites of Jupiter, such as Ganymede.In our experiments, we identified the following phases in the MgSO₄-H₂O system up to 4 GPa at 298 K: Ices VI and VII, magnesium heptahydrate, MgSO₄·7H₂O, and a liquid phase. The present phase relations suggest that there may be a deep internal ocean down to a depth about 800 km in the interior of Ganymede.  相似文献   

Large-scale landslides in Toyama Prefecture,central Japan,and their probable relationship with earthquakes     

Satoru Kojima  Tamotsu Nozaki  Hidehisa Nagata  Ryota Tanahashi  Ryoich Kondo  Noriaki Okamura  Kazuhiro Suzuki  Akiko Ikeda  Toshio Nakamura  Tomoyuki Ohtani 《Environmental Earth Sciences》2014,71(6):2753-2763

Large-scale landslides along the Kubusu and Besso rivers in Toyama Prefecture are developed in the Miocene Iwaine Formation, which is composed of andesitic lava, tuff, and tuff breccia. In the middle member of this formation, the tuff is easily altered to montmorillonite-bearing rock, and subsequently plays an important role in the development of landslides events, which tend to be large-scale events, as the massive lava of the upper member forms a cap rock over the tuff. The Kiritani and Koinami basins, which are flat intermontane basins located along the Kubusu and Besso rivers, respectively, are interpreted as landslide-dammed lakes, later filled with sediment. Accelerator mass spectrometry ¹⁴C ages show that the landslides forming each dam occurred simultaneously, at approximately 2500 BP. These ages were measured from wood fragments embedded in the landslide material of Kiritani, and from an in situ stump drowned during the impoundment of Koinami. If the trigger of these landslides was an earthquake, it is most likely to have been the penultimate event along the Atotsugawa fault zone.  相似文献   

Experimental study of the pyroxene-garnet phase transition in the Na2MgSi5O12 system at pressures of 13–20 GPa: First synthesis of sodium majorite     

Dymshits  A. M.  Bobrov  A. V.  Litasov  K. D.  Shatskiy  A. F.  Ohtani  E.  Litvin  Yu. A. 《Doklady Earth Sciences》2010,434(1):1263-1266

Doklady Earth Sciences -  相似文献