The photoelectron spectra of some Tl-Sb sulphosalts     

Ivan Gržetić  Tonći Balić Žunic 《Physics and Chemistry of Minerals》1993,20(4):285-296

The results of X-ray induced photoelectron spectroscopy (XPS) experiments on several phases of the ternary system Tl-Sb-S are reported. The binding energies of the inner S, Sb and Tl electrons increase with increasing quantities of Sb and decreasing amounts of Tl in these compounds. This is explained by the influences of the proportions of the bonded metals on the effective electron affinity of S. The higher proportions of the more electronegative element bonded to S cause the increase of its effective electron affinity. The results for Tl₂S (carlinite), Tl₃SbS₃, TlSbS₂ (weissbergite), TlAsS₂ (lorandite) and Sb₂S₃ (antimonite) can be interpreted in this way. The results for Tl₄S₃ suggest a predominantly covalent character of bonding for both Tl(III) and Tl(I), which are present in this sulfide. From comparison with Tl₃SbS₄ it could be supposed that Tl(III)-S bond has a more covalent character than Sb(V)-S bond. The results for Tl₃SbS₄ are in agreement with crystal structure data and the results of Moessbauer spectroscopy. For AsS (realgar) the binding energies of the inner electrons of As and S significantly increase, showing that the electrons in molecular orbitals are less strongly bonded to individual atoms, as compared to pure elements. The results for the amorphous TlSb₅S₈ (corresponding in composition to parapierrotite) suggest that in amorphous compound the Tl-S bonding is stronger and the coordination of Tl more regular than in a crystalline one.  相似文献   

Comment on “monitoring well placement using conditional simulation of hydraulic head” by Dale H. Easley,Leon E. Borgman and Denis Weber     

Zekâi Sen 《Mathematical Geosciences》1993,25(2):241-243

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The extreme value distribution of 5-min rainfall data at Belgrade     

Unkašević Miroslava 《Theoretical and Applied Climatology》1991,44(3-4):223-228

Summary For practical applications both the parent distribution of rainfall intensities and the distribution of their annual maxima are of interest. The relationship between these two distributions cannot be obtained from classical extreme value theory because of seasonal variation and serial correlation in the data. Mathematical results for the distribution of maxima in m-dependent sequences are presented to illustrate the effect of local dependence on the extreme value distribution. The average number of exceedances in a cluster is an important parameter in the relationship between the parent and the extreme value distribution. For 5-min rainfall data from Belgrade, quantiles of the annual maxima are overestimated by about 10 mm h^–1 if the effect of serial correlation is ignored. This bias can easily be removed by taking the local clustering of large rainfall intensities in a rainy spell into account.With 4 Figures  相似文献   

Environmental capacity—Is a new scientific concept acceptable as a strategy to combat marine pollution?     

Velimir Pravdić 《Marine pollution bulletin》1985,16(7):295-296

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Some views on the geography of tourism and recreation in Yugoslavia     

Milorad Vasović 《GeoJournal》1984,9(1):83-84

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Prediction of the abiotic degradability of organic compounds in the troposphere     

Hans Güsten  Leo Klasinc  Dubravko Marić 《Journal of Atmospheric Chemistry》1984,2(1):83-93

A statistically relevant correlation between the reaction rate coefficient, k _OH, for the OH radical reaction with 161 organic compounds in the gas phase at 300 K, and the corresponding vertical ionisation energies E _i,v, reveals two classes of compounds: aromatics where –log(k _OH/cm³s^-1)3/2E _i,v(eV)–2 and aliphatics where –log(k _OH/cm³s^-1)4/5E _i,v(eV)+3. The prediction of the rate coefficient, k _OH, for the reaction of OH with organic molecules from the above equations has a probability of about 90%. Assuming a global diurnal mean of the OH radical concentration of 5×10⁵ cm³, the upper limit of the tropospheric half-life of organic compounds and their persistence can be estimated.  相似文献   

Determination of Aquifer Parameters by the Slope-Matching Method     

Zekâi Sen 《Ground water》1986,24(2):217-223

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Latitude variation of the LHR frequency in the outer ionosphere as an indicator of the degree of magnetospheric perturbance     

Jaroslava Bošková  František Jiřiček  Pavel Tříska  Reviewer S. Fischer 《Studia Geophysica et Geodaetica》1983,27(3):298-304

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Numerical Modeling of the Ston-Slano (Croatia) Aftershock Sequence     

Herak  Marijan  Herak  Davorka  Markušić  Snježana  Ivančić  Ines 《Studia Geophysica et Geodaetica》2001,45(3):251-266

The rate of aftershock occurrence after the M6 Ston-Slano (Croatia) earthquake is modeled as the Epidemic Type Aftershock Sequence (ETAS). Increase of the modeled cumulative number of aftershocks with time was fitted to observations by the least-squares criterion using the combined grid-search and Monte-Carlo approach. This enabled not only the estimation of the most probable ETAS parameters, but also the determination of their confidence limits, as well as the estimation of the bias between them. It has been found that the bias is significant for some of the parameter pairs, regardless of the threshold magnitude assumed. Residual analyses revealed that all strong aftershocks (M _L 4.5) occurred during the periods of normal to high aftershock activity. There were two periods of quiescence in the sequence, both of which were followed by a strong aftershock.  相似文献   

Possible Evidence of Long-Term Oscillations in the Solar Atmosphere     

Raju  K.P.  Singh  Jagdev  Srikanth  R.  Chou  Dean-Yi  Team  the Ton 《Solar physics》2001,199(1):1-11

We have obtained the temporal correlation function, Q(t), from time sequences of Caii K filtergrams and Dopplergrams from Antarctica, Taiwan Oscillation Network (TON) and Solar and Heliospheric Observatory (SOHO). Q(t) gives the time evolution of the pattern under examination, supergranulation in this case. It has been found that Q(t) shows oscillatory signals of both 5-min and long-term periods. The 5-min oscillations are suppressed by averaging the images over 10 min. An exponential decay curve which represents the lifetime trend of supergranules, is fitted to Q(t) and subtracted out. The Q(t) residuals thus obtained contain the oscillatory component and are then subjected to a periodogram analysis. Significant periodicities in the range of 1.4–10 hours have been noted. The causes of these oscillations are not fully known at present, but the instrumental and atmospheric factors can be ruled out, pointing to solar origin. Various possibilities are discussed. Some of the observed periodicities may be considered as probable candidates for long-term oscillations in the Sun, such as the elusive gravity modes.  相似文献