Selective Extraction Chemistry of Toxic Metal Sulfides from Sediments     

D. Craig Cooper  John W. Morse 《Aquatic Geochemistry》1999,5(1):87-97

Experimental evidence suggests that formation of metal sulfides in anoxic sediments limits the bioavailability of several toxic elements. Our ability to quantify the processes by which these metal sulfides form is dependent upon our ability to determine the speciation of solid phase metals in sediments. Our work indicates that an entire suite of Cu-Fe and Ni-Fe sulfide minerals can form upon the exposure of mackinawite to aqueous Cu and Ni. Furthermore, we have demonstrated that the solubility of pure metal sulfide minerals and their iron-metal derivatives in HCl directly correlates with the observed trends in the 'Degree of Trace Metal Pyritization' in natural sediments. Current extraction schemes cannot distinguish discrete trace metal sulfides from trace metals associated with pyrite.  相似文献   

Genesis of post-hotspot,A-type rhyolite of the Eastern Snake River Plain volcanic field by extreme fractional crystallization of olivine tholeiite   总被引：3，自引：0，他引：3  

Michael McCurry  Karl P. Hayden  Lee H. Morse  Stan Mertzman 《Bulletin of Volcanology》2008,70(3):361-383

Rhyolites occur as a subordinate component of the basalt-dominated Eastern Snake River Plain volcanic field. The basalt-dominated volcanic field spatially overlaps and post-dates voluminous late Miocene to Pliocene rhyolites of the Yellowstone–Snake River Plain hotspot track. In some areas the basalt lavas are intruded, interlayered or overlain by ~15 km³ of cryptodomes, domes and flows of high-silica rhyolite. These post-hotspot rhyolites have distinctive A-type geochemical signatures including high whole-rock FeO_tot/(FeO_tot+MgO), high Rb/Sr, low Sr (0.5–10 ppm) and are either aphyric, or contain an anhydrous phenocryst assemblage of sodic sanidine ± plagioclase + quartz > fayalite + ferroaugite > magnetite > ilmenite + accessory zircon + apatite + chevkinite. Nd- and Sr-isotopic compositions overlap with coeval olivine tholeiites (ɛ_Nd = −4 to −6; ⁸⁷Sr/⁸⁶Sr_i = 0.7080–0.7102) and contrast markedly with isotopically evolved Archean country rocks. In at least two cases, the rhyolite lavas occur as cogenetic parts of compositionally zoned (~55–75% SiO₂) shield volcanoes. Both consist dominantly of intermediate composition lavas and have cumulative volumes of several 10’s of km³ each. They exhibit two distinct, systematic and continuous types of compositional trends: (1) At Cedar Butte (0.4 Ma) the volcanic rocks are characterized by prominent curvilinear patterns of whole-rock chemical covariation. Whole-rock compositions correlate systematically with changes in phenocryst compositions and assemblages. (2) At Unnamed Butte (1.4 Ma) the lavas are dominated by linear patterns of whole-rock chemical covariation, disequilibrium phenocryst assemblages, and magmatic enclaves. Intermediate compositions in this group resulted from variable amounts of mixing and hybridization of olivine tholeiite and rhyolite parent magmas. Interestingly, models of rhyolite genesis that involve large degrees of melting of Archean crust or previously consolidated mafic or silicic Tertiary intrusions do not produce observed ranges of Nd- and Sr-isotopes, extreme depletions in Sr-concentration, and cogenetic spectra of intermediate rock compositions for both groups. Instead, least-squares mass-balance, energy-constrained assimilation and fractional crystallization modeling, and mineral thermobarometry can explain rhyolite production by 77% low-pressure fractional crystallization of a basaltic trachyandesite parent magma (~55% SiO₂), accompanied by minor (0.03–7%) assimilation of Archean upper crust. We present a physical model that links the rhyolites and parental intermediate magmas to primitive olivine tholeiite by fractional crystallization. Assimilation, recharge, mixing and fractional melting occur to limited degrees, but are not essential parts of the rhyolite formation process. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. This paper constitutes part of a special issue dedicated to Bill Bonnichsen on the petrogenesis and volcanology of anorogenic rhyolites.  相似文献   

Characterizing uncertainties for quantifying bathymetry change between time-separated multibeam echo-sounder surveys     

Thierry Schmitt  Neil C. Mitchell  A. Tony S. Ramsay 《Continental Shelf Research》2008

Changes of bathymetry derived from multibeam sonars are useful for quantifying the effects of many sedimentary, tectonic and volcanic processes, but depth changes also require an assessment of their uncertainty. Here, we outline and illustrate a simple technique that aims both to quantify uncertainties and to help reveal the spatial character of errors. An area of immobile seafloor is mapped in each survey, providing a common ‘benchmark’. Each survey dataset over the benchmark is filtered with a simple moving-averaging window and depth differences between the two surveys are collated to derive a difference histogram. The procedure is repeated using different length-scales of filtering. By plotting the variability of the differences versus the length-scale of the filter, the different effects of spatially uncorrelated and correlated noise can be deduced. The former causes variability to decrease systematically as predicted by the Central Limit Theorem, whereas the remaining variability not predicted by the Central Limit Theorem then represents the effect of spatially correlated noise. Calculations made separately for different beams can reveal whether problems are due to heave, roll, etc., which affect inner and outer beams differently. We show how the results can be applied to create a map of uncertainties, which can be used to remove insignificant data from the bathymetric change map. We illustrate the technique by characterizing changes in nearshore bed morphology over one annual cycle using data from a subtidal bay, bedrock headland and a banner sand bank in the Bristol Channel UK.  相似文献   

Roosevelt County 075: A petrologic,chemical and isotopic study of the most unequilibrated known H chondrite     

T. J. McCoy  K. Keil  R. D. Ash  A. D. Morse  C. T. Pillinger  R. Wieler  T. K. Mayeda  R. N. Clayton  P. H. Benoit  D. W. G. Sears  I. Casanova  D. W. Muenow  C. B. Moore  C. F. Lewis  I. E. Wilson 《Meteoritics & planetary science》1993,28(5):681-691

Abstract— Roosevelt County (RC) 075 was recovered in 1990 as a single 258-gram stone. Classification of this meteorite is complicated by its highly unequilibrated nature and its severe terrestrial weathering, but we favor H classification. This is supported by O isotopes and estimates of the original Fe, Ni metal content. The O isotopic composition is similar to that of a number of reduced ordinary chondrites (e.g., Cerro los Calvos, Willaroy), although RC 075 exhibits no evidence of reduced mineral compositions. Chondrule diameters are consistent with classification as an L chondrite, but large uncertainties in chondrule diameters of RC 075 and poorly constrained means of H, L and LL chondrites prevent use of this parameter for reliable classification. Other parameters are compromised by severe weathering (e.g., siderophile element abundances) or unsuitable for discrimination between unequilibrated H, L and LL chondrites (e.g., Co in kamacite, δ¹³C). Petrologic subtype 3.2± 0.1 is suggested by the degree of olivine heterogeneity, the compositions of chondrule olivines, the thermoluminescence sensitivity, the abundances and types of chondrules mapped on cathodoluminescence mosaics, and the amount of presolar SiC. The meteorite is very weakly shocked (S2), with some chondrules essentially unshocked and, thus, is classified as an H3.2(S2) chondrite. Weathering is evident by a LREE enrichment due to clay contamination, reduced levels of many siderophile elements, the almost total loss of Fe, Ni metal and troilite, and the reduced concentrations of noble gases. Some components of the meteorite (e.g., type IA chondrules, SiC) appear to preserve their nebular states, with little modification from thermal metamorphism. We conclude that RC 075 is the most unequilibrated H chondrite yet recovered and may provide additional insights into the origin of primitive materials in the solar nebula.  相似文献   

Resilience to change in two coastal communities: Using the maximum dexterity fleet     

Tony J. Pitcher  Cameron H. Ainsworth 《Marine Policy》2010

Using whole-ecosystem dynamic simulation models fitted to local data, two coastal communities are described (temperate, northern British Columbia, Canada; tropical, Raja Ampat, Indonesia) where relatively poor fishers’ livelihoods are threatened by climate change and overfishing. A novel theoretical minimum bycatch scenario, the ‘maximum dexterity fleet’, is combined with a search algorithm specifying optimal fisheries to achieve economic and biodiversity goals. Potential gains made by approaching an optimal fleet configuration prove robust against increased risks from climate variability. Although fish, gear and way of life differ greatly, in both communities it is suggested that dexterity (adroitness in adapting fishing gear) could lead to improved benefits from fishing.  相似文献   

Catchment-scale observations at the Niwot Ridge long-term ecological research site     

Nels R. Bjarke  Ben Livneh  Sarah C. Elmendorf  Noah P. Molotch  Eve-Lyn S. Hinckley  Nancy C. Emery  Pieter T. J. Johnson  Jennifer F. Morse  Katherine N. Suding 《水文研究》2021,35(9):e14320

The Niwot Ridge and Green Lakes Valley (NWT) long-term ecological research (LTER) site collects environmental observations spanning both alpine and subalpine regimes. The first observations began in 1952 and have since expanded to nearly 300 available datasets over an area of 99 km² within the north-central Colorado Rocky Mountains that include hydrological (n = 101), biological (n = 79), biogeochemical (n = 62), and geographical (n = 56) observations. The NWT LTER database is well suited to support hydrologic investigations that require long-term and interdisciplinary data sets. Experimentation and data collection at the NWT LTER are designed to characterize ecological responses of high-mountain environments to changes in climate, nutrients, and water availability. In addition to the continuation of the many legacy NWT datasets, expansion of the breadth and utility of the NWT LTER database is driven by new initiatives including (a) a catchment-scale sensor network of soil moisture, temperature, humidity, and snow-depth observations to understand hydrologic connectivity and (b) snow-albedo alteration experiments using black sand to evaluate the effects of snow-disappearance on ecosystems. Together, these observational and experimental datasets provide a substantial foundation for hydrologic studies seeking to understand and predict changes to catchment and local-scale process interactions.  相似文献   

Analysis of refracturing in horizontal wells: Insights from the poroelastic displacement discontinuity method          下载免费PDF全文

Ali Rezaei  Giorgio Bornia  Mehdi Rafiee  Mohamed Soliman  Stephen Morse 《国际地质力学数值与分析法杂志》2018,42(11):1306-1327

In this paper, a fully coupled 2‐dimensional poroelastic displacement discontinuity method is used to investigate the refracturing process in horizontal wells. One of the objectives of refracturing is to access new reserves by adding new hydraulic fractures in zones that were bypassed in the initial fracturing attempt. Pore pressure depletion in the vicinity of old fractures directly affects the state of stress and eventually the propagation of newly created hydraulic fractures. Thus, a poroelastic analysis is required to identify guidelines for the refracturing process, in particular to understand the extension of the pore pressure depletion, and eventually, the orientation of new as well as old fractures. We propose a fully coupled approach to model the whole process of child fracture propagation in a depleted area between 2 parent fractures in the same wellbore. This approach omits the need of using multistep workflow that is regularly used to model the process. The maximum tensile stress criterion (σ criterion) is used for hydraulic fracture propagation. The proposed method is verified using available analytical solutions for total stress and pore pressure loading modes on a line fracture in drained and undrained conditions. Then, test cases of multifractured horizontal wells are studied to calculate the time evolution of the stress and pore pressure fields around old fractures and to understand the effect of these fields on the propagation path of newly created fractures. Finally, the effect of the pore pressure depletion on the propagation path of the newly created fractures in the bypassed area of the same wellbore is studied. The results show that the depleted areas around old fractures are highly affected by the extent and severity of the stress redistribution and pore pressure depletion. It is observed that a successful creation of new fractures may only happen in certain time frames. The results of this study provide new insights on the behavior of newly created fractures in depleted zones. They also clarify the relationship between stress change and pore pressure depletion in horizontal wells.  相似文献   

Identifying irregularly shaped crime hot-spots using a multiobjective evolutionary algorithm     

Xiaolan Wu  Tony H. Grubesic 《Journal of Geographical Systems》2010,12(4):409-433

Spatial cluster detection techniques are widely used in criminology, geography, epidemiology, and other fields. In particular, spatial scan statistics are popular and efficient techniques for detecting areas of elevated crime or disease events. The majority of spatial scan approaches attempt to delineate geographic zones by evaluating the significance of clusters using likelihood ratio statistics tested with the Poisson distribution. While this can be effective, many scan statistics give preference to circular clusters, diminishing their ability to identify elongated and/or irregular shaped clusters. Although adjusting the shape of the scan window can mitigate some of these problems, both the significance of irregular clusters and their spatial structure must be accounted for in a meaningful way. This paper utilizes a multiobjective evolutionary algorithm to find clusters with maximum significance while quantitatively tracking their geographic structure. Crime data for the city of Cincinnati are utilized to demonstrate the advantages of the new approach and highlight its benefits versus more traditional scan statistics.  相似文献   

ON generation source sites of internal in the Luzon strait     

ZHENG Quanan  SONG Y Tony  LIN Hui  HU Xiaomin  MENG Junmin  WANG Dan 《海洋学报(英文版)》2008,27(3)

This effort aims to determine the generation source sites in the Luzon Strait for energetic, long-crest, transbasin internal waves (IW) observed in the northern South China Sea (NSCS). The roles of islands distributed on eastern side of the strait, Kuroshio, submarine ridges, shoaling thermocline, and strait configuration played in the IW generation are examined using the cruise data analysis, satellite data interpretation, and dynamical analysis. The islands and channels on eastern side of the strait are excluded from a list of possible IW source sites owing to their unmatched horizontal dimensions to the scale of IW crest line length, and the relative low Reynolds number. The Kuroshio has a potential to be a radiator for the long-crest IW disturbances, meanwhile, the Kuroshio west (east) wing absorbs the eastward (westward) propagating IW disturbance. Namely, the Kuroshio blockades the outside west-east propagating IW disturbances. The 3-D configuration of the Luzon Strait is characterized by a sudden, more than one order widening of the cross-section areas at the outlets on both sides, providing a favorable condition for IW type initial disturbance formation. In the Luzon Strait, the thermocline is featured by a westward shoaling all the year around, providing the dynamical conditions for the amplitude growth (declination) to the westward (eastward) propagating IW type disturbance. Thus,the west slope of western submarine ridge at the western outlet of the Luzon Strait is a high possibility source sites for energetic,long-crest, transbasin Iws in the NSCS. The interpretation results of satellite SAR images during a 13 a period from 1995 to 2007 provide the convincing evidence for the conclusions.  相似文献   

Dynamical analysis of mesoscale eddy-induced ocean internal waves using linear theories   总被引：3，自引：1，他引：2  

XU Qing  ZHENG Quanan  LIN Hui  LIU Yuguang  SONG Y Tony  YUAN Yeli 《海洋学报(英文版)》2008,27(3):60-69

This study aims to explore generation mechanisms of the ocean internal wave using the dynamical analysis methods based on linear theories. Historical cruise measurements and recent synthetic aperture radar （SAR） observations of mesoscale eddies with diameter of several tens of kilometers to hundreds of kilometers show that the internal wave packets with wavelength of hundreds of meters to kilometer exist inside the mesoscale eddies. This coexistence phenomenon and inherent links between the two different scale processes are revealed in the solutions of governing equations and boundary conditions for the internal wave disturbance with a horizontally slowly variable amplitude in a cylindrical coordinate system. The theoretical solutions indicate that the instability of eddy current field provides the dynamical mechanism to internal wave generation. The derived dispersion relation indicates that the internal wave propagation is modified by the eddy current field structure. The energy equation of the internal waves clearly shows the internal wave energy increment comes from the eddy. The theoretical models are used to explain the observation of the mesoscale eddy-induced internal waves off the Norwegian coast. The two-dimensional waveform solution of the anticyclonic eddy-induced internal wave packet appears as ring-shaped curves, which contains the typical features of eddy stream lines. The comparison of theoretical solutions to the structure of the internal wave packets on SAR image shows a good agreement on the major features.  相似文献