Quartz Reference Materials for Oxygen Isotope Analysis by SIMS          下载免费PDF全文

Susanne Seitz  Lukas P. Baumgartner  Anne‐Sophie Bouvier  Benita Putlitz  Torsten Vennemann 《Geostandards and Geoanalytical Research》2017,41(1):69-75

Two quartz samples of igneous origin, UNIL‐Q1 (Torres del Paine Intrusion, Chile) and BGI‐Q1 (Shandong province, China), were calibrated for their oxygen isotope composition for SIMS measurements. UNIL‐Q1 and BGI‐Q1 were evaluated for homogeneity using SIMS. Their reference δ¹⁸O values were determined by CO₂ laser fluorination. The average δ¹⁸O value found for UNIL‐Q1 is 9.8 ± 0.06‰ and that for BGI‐Q1 is 7.7 ± 0.11‰ (1s). The intermediate measurement precision of SIMS oxygen isotope measurements was 0.32–0.41‰ (2s; UNIL‐Q1) and 0.40–0.48‰ (2s; BGI‐Q1), respectively. While less homogeneous in its oxygen isotope composition, BGI‐Q1 is also suitable for SIMS trace element measurements.  相似文献   

Exposing metal and silicate charges to electrical discharges: Did chondrules form by nebular lightning?     

Carsten Güttler  Torsten Poppe 《Icarus》2008,195(1):504-510

In order to investigate the hypothesis that dust aggregates were transformed to meteoritic chondrules by nebular lightning, we exposed silicatic and metallic dust samples to electrical discharges with energies of 120 to 500 J in air at pressures between 10 and 10⁵ Pa. The target charges consisted of powders of micrometer-sized particles and had dimensions of mm. The dust samples generally fragmented leaving the major fraction thermally unprocessed. A minor part formed sintered aggregates of 50 to 500 μm. In a few experiments melt spherules having sizes ?180 μm in diameter (and, generally, interior voids) were formed; the highest spherule fraction was obtained with metallic Ni. Our experiments indicate that chondrule formation by electric current or by particle bombardment inside a discharge channel is unlikely.  相似文献   

Mineralogy,petrology, and trace element geochemistry of the Johnstown meteorite: a brecciated orthopyroxenite with siderophile and REE-rich components     

R.J. Floran  Martin Prinz  P.F. Hlava  Klaus Keil  B. Spettel  H. Wänke 《Geochimica et cosmochimica acta》1981,45(12):2385-2391

The Johnstown meteorite is a brecciated orthopyroxenite (diogenite) containing coarsegrained centimeter-sized clasts of cumulate origin that have undergone subsolidus recrystallization. The brecciated portion is dominated by subangular fragments of orthopyroxene (Wo_2–3En_72–74Fs_23–25) in a variably comminuted matrix of the same material. Minor and accessory phases include plagioclase (An_82–90Ab_10–18Or_0–1), diopside (Wo_44–45En_46–47Fs_9–10), olivine (Fo_71–72), tridymite, troilite, metallic Ni-Fe (~3% Ni), and chromite (Cm_71–80Hc_1–8Sp_11–19Mt_2–4Uv_1–3).The clastic component is parental to the brecciated matrix which contains no foreign lithic or mineralogic components. Siderophile trace element studies, however, reveal the presence of meteoritic (chondritic) contamination in the brecciated portion using unbrecciated clasts for indigenous values. Rare earth element abundances show a wide range of values for the light REE in different samples, although all samples exhibit a strong negative Eu anomaly, indicative of earlier plagioclase fractionation. Two pairs of adjacent brecciated and unbrecciated samples from different portions of the meteorite show, respectively, the most enriched and the most depleted light REE patterns. The variability in La content is over a factor of 100. However, in each case the REE pattern for the brecciated portion is very similar to that of the unbrecciated portion. These differences are attributed to sampling of variable amounts of residual, REE-enriched, trapped liquid. The most representative REE pattern for the bulk meteorite has an intermediate composition and was obtained from the largest sample. The data presented here indicate that Johnstown is a monomict breccia, in contrast to several other diogenites which may be considered to be polymict on the basis of their mineral compositions and/or clast populations.  相似文献   

Evolved lavas from the Snake River Plain: Craters of the Moon National Monument,Idaho   总被引：4，自引：0，他引：4  

William P. Leeman  Charles J. Vitaliano  Martin Prinz 《Contributions to Mineralogy and Petrology》1976,56(1):35-60

Holocene lavas from Craters of the Moon (COM) National Monument are representative of differentiated lavas which occur around the margins of the Snake River Plains (SRP) and they range serially in composition from alkali- and phosphorous-rich ferrobasalts to ferrolatites. Petrographic study indicates that these lavas evolved primarily by cotectic crystallization of olivine, plagioclase, magnetite and apatite in the mafic members of the suite (ferrobasalts), and by cotectic crystallization of plagioclase, magnetite, clinopyroxene and minor olivine in the salic members. Quantitative phase relations in the COM lavas, calculated by means of a leastsquares mixing program, indicate that the observed range in composition among these lavas corresponds to at least 70 percent crystallization of a magma similar to the most mafic COM lavas. Anhydrous one-atmosphere experimental crystallization studies fail to reproduce exactly the inferred phase relations; the discrepancy is attributed to the presence of water in the naturally crystallized magmas. The origin of COM parental magma cannot be unequivocably resolved. Available evidence suggests that COM lavas do not represent melts derived directly from the mantle: (1) high Sr⁸⁷/Sr⁸⁶ ratios (0.708 to 0.712), (2) relatively high Fe/(Fe+Mg) and excluded-element content in even the most mafic COM lavas, (3) occurrence of megacrysts of inferred high-pressure origin in the Lava Creek flow. Megacrysts occur in the Lava Creek flow as clusters of labradorite, aluminous clinopyroxene, and olivine. Analogy with the experiments of Thompson [1] and least squares mixing calculations indicate that intermediate (ca. 8 to 10 Kbar) pressure fractionation of such megacrysts from olivine tholeiite magma may yield derivative COM-type liquids.  相似文献   

Chromian spinels in lherzolite inclusions from Itinome-gata,Japan     

Ken-ichiro Aoki  Martin Prinz 《Contributions to Mineralogy and Petrology》1974,46(4):249-256

Spinel, which constitutes from 0.7% to 3% of lherzolite inclusions, occurs as primary anhedral grains (chrome-rich variety) and as a secondary phase as breakdown products of garnet (alumina-rich variety). Although individual primary spinel grains are chemically homogeneous, spinels are characterized by a wide range of Cr/Al ratios and a relatively narrow range of Mg/Fe″ ratios, even in a single lherzolite sample. The chemical variations of spinels are considered to have the following origin: When garnet lherzolite enters the stability field of the spinel peridotite facies as a consequence of slow upward transport, both orthopyroxenes and clinopyroxenes are recrystallized with loss of jadeite and some Tschermak's component to reach equilibrium. A part of the Tschermak's component reacts with olivine to form pyroxene and spinel. This secondary spinel component is alloted to the primary chromian spinel. However, these reactions did not always reach equilibrium with the major constituent minerals in the lherzolites.  相似文献   

Sr and Nd isotope composition of Late Pleistocene sapropels and nonsapropelic sediments from the Eastern Mediterranean Sea: implications for detrital influx and climatic conditions in the source areas     

Syee Weldeab  Kay-Christian EmeisChristoph Hemleben  Torsten W VennemannHartmut Schulz 《Geochimica et cosmochimica acta》2002,66(20):3585-3598

Isotopic ratios of Sr and Nd from lithogenic components of three isochronous core sections recovered from an east-west transect in the Eastern Mediterranean Sea (EMS) have been analyzed. The data are used for a quantitative estimate of the temporal and spatial variation of detrital flux to the EMS, assuming Saharan dust and Aegean/Nile particulate matter as dominant end members. It was established that the carbonate-free Saharan dust flux during deposition of the nonsapropel layers of marine oxygen isotope stage 5.4 (MIS 5.4) was similar to the present flux. During the deposition of sapropels S5 and S6, however, the Saharan dust input was drastically reduced and was not balanced by a change in the riverine influx at this time. Denser vegetation cover during more humid conditions may have reduced physical erosion and sediment removal in the source area. During marine oxygen isotope stage 6.2 (MIS 6.2) a pronounced increase of Saharan dust and detrital influx from the Aegean region is evident and implies more arid conditions in the southern and northern catchment areas. During this period, intersite variations are interpreted in terms of their geographic location relative to the seaways connecting the Aegean Sea and EMS. The width of the straits and hence the amount of sediment entering the eastern basins may have been affected by a low sea level that impeded interbasin sediment dispersal.  相似文献   

Investigation of the pyrolytic liberation of molecular nitrogen from Palaeozoic sedimentary rocks     

Bernhard M. Krooss  Lothar Friberg  Yves Gensterblum  Jan Hollenstein  Dirk Prinz  Ralf Littke 《International Journal of Earth Sciences》2005,94(5-6):1023-1038

Open-system non-isothermal pyrolysis up to 1,200°C in combination with elemental analysis was used to study the thermal liberation of molecular nitrogen (N₂) from sedimentary rocks and kerogen concentrates of Palaeozoic age from the Central European Basin system and an Eocene shale (Liaohe Basin, China) with a high content (36%) of ammonium feldspar (buddingtonite). The N/C_org (atomic) ratios of the kerogen concentrates ranged from 0.005 to 0.014, which represents the range commonly observed for coals. Bulk N/C_org ratios of the Palaeozoic shales extended from 0.035 to 0.108, indicating the presence of significant amounts of inorganic nitrogen. Namurian A and A-B (CnA; CnA-B) samples typically exhibited the earliest onset of N₂ generation with intense, characteristic peaks around 600°C. N₂ liberation from the buddingtonite-rich sample occurred at higher temperatures, with a broad peak around 700°C. Pyrograms of the kerogen concentrates showed no or strongly reduced N₂ generation in the 500–700°C range. On-line isotope-specific analysis of the pyrolytically liberated N₂ on one sample revealed a variability of ∼10‰ in the δ¹⁵N values and a steady increase in δ¹⁵N with temperature during the main phase of N₂ generation.  相似文献   

Experience of geomagnetic field recording with a fluxgate magnetometer having a bridge sensor     

Torsten Bergmark 《Surveys in Geophysics》1984,6(3-4):381-391

A fluxgate magnetometer has been developed at the Geological Survey of Sweden. It measures the field in three orthogonal directions and has sensor elements forming bridges. The instrument can have direct readout in both digital and analogue form with a resolution of 0.1 nT.An instrument of this type has been adopted for stationary recording of geomagnetic elements in digital form. Special attention has been paid to insure good long term stability and high reliability. Experience from routine recording is described.  相似文献   

People at Risk of Flooding: Why Some Residents Take Precautionary Action While Others Do Not     

Torsten Grothmann  Fritz Reusswig 《Natural Hazards》2006,38(1-2):101-120

Self-protective behavior by residents of flood-prone urban areas can reduce monetary flood damage by 80%, and reduce the need for public risk management. But, research on the determinants of private households’ prevention of damage by natural hazards is rare, especially in Germany. To answer the question of why some people take precautionary action while others do not, a socio-psychological model based on Protection Motivation Theory (PMT) is developed, explaining private precautionary damage prevention by residents’ perceptions of previous flood experience, risk of future floods, reliability of public flood protection, the efficacy and costs of self-protective behavior, their perceived ability to perform these actions, and non-protective responses like wishful thinking. The validity of the proposed model is explored by means of representative quantitative telephone surveys and regression analyses, and compared with a socio-economic model (including residents’ age, gender, income, school degree and being owner or tenant). Participants were 157 residents of flood-prone homes in Cologne, Germany, a city that has traditionally been subject to minor and major flood events. Results of the study show the explanatory power of the socio-psychological model, with important implications for public risk communication efforts. To motivate residents in flood-prone areas to take their share in damage prevention, it is essential to communicate not only the risk of flooding and its potential consequences, but also the possibility, effectiveness and cost of private precautionary measures.  相似文献   

Geography and the study of interaction between nature and society     

Torsten Hgerstrand 《Geoforum》1976,7(5-6)

  相似文献