Nd and Sr isotopic variations in acidic rocks formed under a peculiar tectonic environment in Miocene Southwest Japan     

Yasutaka Terakado  Hiroshi Shimizu  Akimasa Masuda 《Contributions to Mineralogy and Petrology》1988,99(1):1-10

Initial Nd and Sr isotopic ratios were obtained for middle Miocene igneous rocks as well as for related rocks from the Outer Zone of Southwest Japan to investigate the petrogenesis of acidic magmas and their relation to a peculiar tectonic environment bearing on the back-arc spreading of the Japan Sea. On the _Nd- _Sr diagram, data points for the acidic rocks fall in the – _Nd, + _Sr quadrant occupying different positions from those for sedimentary and old crustal rocks, and seem to define several subparallel lines which extend towards the lower-righthand sedimentary field. The S-type acidic rocks occupy an intermediate position between I-type rocks and sedimentary ones, a fact suggesting mixing of an igneous component and a sedimentary one. The linear mixing trend observed on the _Nd- _Sr diagram can be attained in the restricted case that the igneous component has similar Sr/Nd concentration ratios to that of the sedimentary one, which implies an intermediate to acidic composition for the igneous component. Inconsistency between the elemental and isotopic variations observed may be reconciled by considering that mixing, probably in the relatively deep part of the crust, might have occured prior to chemical differentiation processes. The episodic igneous activity and the high heat energy required to melt such materials involving sedimentary rocks may be explained by a model in which a hot mantle region probably corresponding to the rising part of the mantle convection supplied the heating energy to the Outer Zone of Southwest Japan when passing beneath Southwest Japan in the course of movement of the hot rising part from the Shikoku basin areas to the Japan Sea area.  相似文献   

Iron and zinc partitioning between coexisting stannite and sphalerite: a possible indicator of temperature and sulfur fugacity     

M. Shimizu  N. Shikazono 《Mineralium Deposita》1985,20(4):314-320

Stannite and sphalerite coexisting with iron sulfides (pyrite and/or pyrrhotite) from Japanese ore deposits associated with tin mineralization were analyzed. Based on the iron and zinc partitioning between stannite and sphalerite, the formation temperature and sulfur fugacity for this mineral assemblage were estimated. A good correlation between stannite-sphalerite temperatures and filling temperatures of fluid inclusions and sulfur isotope temperatures was obtained. This good correlation suggests that the stannite-sphalerite pair is a useful indicator of temperature and sulfur fugacity. It is deduced that the formation temperatures are not different for skarn-type, polymetallic vein-type and Sn-W vein-type deposits, whereas the sulfur fugacities are different; sulfur fugacities increase from the skarn-type through the Sn-W vein-type to the polymetallic vein-type deposits.  相似文献   

The Ag/Au ratio of native gold and electrum and the geochemical environment of gold vein deposits in Japan     

N. Shikazono  M. Shimizu 《Mineralium Deposita》1987,22(4):309-314

The chemical composition of native gold and electrum from auriferous vein and gold-silver vein deposits in Japan has been analyzed and summarized. The Ag/Au ratios of native gold and electrum from these two types of deposits are distinct, i.e., 10–20 Ag at % (auriferous vein) and 30–70 Ag at % (gold-silver vein). Thermochemical calculations suggest that the Ag/Au ratio of native gold and electrum should decrease with increasing chloride concentration and temperature. This is consistent with analytical results of native gold and electrum and fluid inclusion studies. Based on the Ag content of native gold and electrum, the Fe content of sphalerite, and the estimated temperatures, it is deduced that the sulfur activity for auriferous vein-type systems was lower than that of gold-silver vein-type systems.  相似文献   

Ferric iron partitioning between plagioclase and silicate liquid: thermodynamics and petrological applications     

Toru Sugawara 《Contributions to Mineralogy and Petrology》2001,141(6):659-686

A series of Fe and Mg partition experiments between plagioclase and silicate liquid were performed in the system SiO₂-Al₂O₃-Fe₂O₃-FeO-MgO-CaO-Na₂O under oxygen fugacities from below the IW buffer up to that of air. A thermodynamic model of plagioclase solid solution for the (CaAl,NaSi,KSi)(Fe³⁺,Al³⁺)Si₂O₈-Ca(Fe²⁺,Mg)Si₃O₈ system is proposed and is calibrated by regression analysis based on new and previously reported experimental data of Fe and Mg partitioning between plagioclase and silicate liquid, and reported thermodynamic properties of end members, ternary feldspar and silicate liquid. Using the derived thermodynamic model, FeO^t, MgO content and Mg/(Fe^t+Mg) in plagioclase can be predicted from liquid composition with standard deviations of ǂ.34 wt% (relative error =9%) and ǂ.08 wt% (14%) and ǂ.7 (8%) respectively. Calculated Fe³⁺-Al exchange chemical potentials of plagioclase, m_{Fe^{3 +} ( Al )- 1} ^Pl{\rm \mu }_{{\rm Fe}^{{\rm 3 + }} \left( {{\rm Al}} \right)_{{\rm - 1}} }^{{\rm Pl}} agree with those calculated using reported thermodynamic models for multicomponent spinel, m_{Fe^{3 +} ( Al )- 1} ^Sp{\rm \mu }_{{\rm Fe}^{{\rm 3 + }} \left( {{\rm Al}} \right)_{{\rm - 1}} }^{{\rm Sp}} and clinopyroxene, m_{Fe^{3 +} ( Al )- 1} ^Cpx{\rm \mu }_{{\rm Fe}^{{\rm 3 + }} \left( {{\rm Al}} \right)_{{\rm - 1}} }^{{\rm Cpx}} . The FeO^t content of plagioclase coexisting with spinel or clinopyroxene is affected by Fe³⁺/(Fe³⁺+Al) and Mg/(Fe+Mg) of spinel or clinopyroxene and temperature, while it is independent of the anorthite content of plagioclase. Three oxygen barometers based on the proposed model are investigated. Although the oxygen fugacities predicted by the plagioclase-liquid oxygen barometer are scattered, this study found that plagioclase-spinel-clinopyroxene-oxygen and plagioclase-olivine-oxygen equilibria can be used as practical oxygen barometers. As a petrological application, prediction of plagioclase composition and f_O2 are carried out for the Upper Zone of the Skaergaard intrusion. The estimated oxygen fugacities are well below QFM buffer and consistent with the estimation of oxidization states in previous studies.  相似文献   

Dislocation microstructures in naturally deformed silicate garnets   总被引：1，自引：0，他引：1  

Jun-ichi Ando  Kiyoshi Fujino  Toru Takeshita 《Physics of the Earth and Planetary Interiors》1993,80(3-4):105-116

Dislocation microstructures of naturally deformed silicate garnets and olivines in garnet-peridotites and silicate garnets in eclogites from four localities have been observed with a transmission electron microscope (TEM) to clarify the dislocation characteristics of silicate garnets. We have obtained the following results: (1) dislocation densities of garnets in all the garnet-peridotites (ρ = 10⁵−10⁷ cm⁻²) are always nearly an order of magnitude lower than those of co-existing olivines; (2) dislocation densities of garnets in eclogites (ρ = 10⁵−10⁸ cm⁻²) which are embedded in garnet-peridotites are almost an order of magnitude higher than those of garnets in the surrounding garnet-peridotites; (3) the dominant Burgers vector, b, of mainly edge dislocations in garnet is 100 for specimens with dislocation density ρ = 10⁵−10⁶ cm⁻², while b=1/2111 for specimens with ρ = 10⁷−10⁸ cm⁻². Result (1) indicates that the observed dislocations in garnets were formed by plastic deformation under the same stresses as for co-existing olivines, and that there is a similar relationship between applied stress and dislocation density for garnets as for olivines. Result (2) suggests that the stress concentration occurred around eclogites embedded in garnet-peridotites, and the resulting differential stress in garnets in eclogites was further elevated by the interlocking of neighboring hard garnet grains. Finally, result (3) indicates that the dominant Burgers vector of mainly edge dislocations in garnet changes from 100 to 1/2111 with increasing applied differential stress.  相似文献   

Strong interaction between the ring system and the ionosphere of saturn     

Mikio Shimizu 《Earth, Moon, and Planets》1980,22(4):521-522

An abnormally low electron density in the Saturnian ionosphere observed by the radio occultation experiment of the Pioneer 11 may be explained in terms of the contamination of water in the Saturnian upper atmosphere from its ring system.  相似文献   

The structure of cometary atmospheres     

Mikio Shimizu 《Astrophysics and Space Science》1976,40(1):149-155

The temperature distributions in cometary atmospheres at various heliocentric distances for comets of Bennett and Encke types have been calculated by taking into account heating due to the absorption of solar ultraviolet radiation, cooling by H₂O far infrared emission, and various dynamical processes (expansion, advection, and thermal conduction). The agreement of the results with the observations is in general satisfactory. The conversion of CH₄ and NH₃ to CO and N₂ through thermochemical reaction with H₂O is concluded to be impossible, since the temperature is too low at a heliocentric distance 1.5 AU where CO⁺ ions begin to be observable.  相似文献   

Spatial distribution of deuterium in atmospheric water vapor: Diagnosing sources and the mixing of atmospheric moisture   总被引：1，自引：0，他引：1  

Tsutomu Yamanaka  Ryosuke Shimizu 《Geochimica et cosmochimica acta》2007,71(13):3162-3169

We measured the stable isotopic composition of hydrogen (δD) within atmospheric water vapor collected simultaneously at six sites in the vicinity of a lake (Lake Kasumigaura, Eastern Japan) to determine its spatial distribution characteristics and thereby diagnose sources and mixing of atmospheric moisture. The measured spatial distribution of δD showed no relation to distance from the lake, although it showed a correlation with the distribution of the water-vapor mixing ratio Q. For two of the three sampling days, we found a simple two-component (i.e., water vapor transpiring from local land surfaces and pre-existing vapor in the background atmosphere) mixing line in a Keeling plot (i.e., δ − 1/Q diagram). On a third day, however, contributions from lake evaporation were detected in addition to the above components. On this day, lake-derived vapor accounted for approximately 10-20% of atmospheric water vapor at the sites located leeward of the lake. The observed differences in mixing patterns among sampling days can be explained by a simple atmospheric moisture budget. Thus, it is likely that simultaneous isotopic measurements of atmospheric water vapor at multiple locations with aid of Keeling plot are capable of giving us useful information in diagnosing the sources and mixing pattern of the vapor.  相似文献   

Relationship between faults and generation of inland shallow earthquakes: enlightenment of the M=7.2 southern Hyogo prefecture earthquake     

Toru Ouchi  Qing-Hua Huang 《地震学报(英文版)》1998,11(4):413-420

The M=7.2 southern Hyogo prefecture earthquake, which occurred on January 17, 1995, destroyed the region severely. Further researches are necessary to explain the problems obtained from this earthquake. We have discussed some characteristics correlating with this earthquake, such as distribution of aftershocks and disaster, relationship between fault and generation of inland shallow earthquakes, strong motion and so on. The tectonic movements of surface faults may be different from those of deep faults. Earthquakes may not be restricted directly by the tectonic movements of surface faults. The strong motion zone is often appeared in the region a little away from the both ends or from the single side of a fault instead of the region of a focal fault. Some mechanisms of strong motion have also been discussed.  相似文献   

Tectono–Magmatic Evolution and Metallogenesis along the Northeast Jiangxi Deep Fault, China     

Ying Ye  Hidehiko Shimazaki  Masaaki Shimizu  Shouxi Hu 《Resource Geology》1998,48(1):43-50

Abstract: From the southernmost part of Jiangsu province to the northeastern part of Jiangxi province, China, the Northeast Jiangxi Deep Fault runs for about 400 km length with a width of 30 to 40 km. This fault marks the suture zone of two ter-ranes of Proterozoic age. At the both sides of the fault, Yanshanian granitic activity is recognized. That is, the Dexing-Wuyuan porphyry belt on the NW side of the fault, and the Damaoshan-Lingshan granite belt on the SE side. The former activity is characterized by the occurrence of small stocks of granodioritic composition, rich in siderophile elements but poor in LIL elements. No distinct Eu anomaly is recognized in the REE pattern, and a low initial ⁸⁷Sr/⁸⁶Sr ratio is reported. Magnetite, sphene and apatite are observed as accessory minerals. On the contrary, granitic activity on the SE side of the fault is characterized by the occurrence of composite batholiths, in general of granitic to monzogranitic composition, rich in LIL and alkali elements but poor in siderophile and alkali earth elements. A strong Eu anamaly is recognized in the REE pattern, and initial ⁸⁷Sr/⁸⁶Sr ratios are as high as 0. 716. Fluorite, zircon and REE minerals are observed as accessory minerals. These two contrasting granitic activities are refered to as syntexis– and transformation–types, respectively, following the classification commonly used in China, and have similar petrochemical characteristics to those defined for the magnetite– and ilmenite–series, and I– and S-type granitoids. Considering that the above igneous activity occurred far from the supposed subduction zone along the East Coast of China, intracontinental A-type (continent to continent) subduction is proposed to have occurred northwestwards along the NE Jiangxi Deep Fault during Yanshanian time due to a strong compressional stress from SE to NW. A-type subduction introduced the continental slab to some depth, and resulted in the production of the paired granitic activity observed on both sides of the fault. Many mineral deposits are associated with both granitic belts. In the Dexing-Wuyuan porphyry belt, the Dexing porphyry Cu and Yinshan polymetallic deposits are representative, whereas in the Damaoshan-Lingshan granite belt, several tens of rare metal deposits are known such as the Geyuan Nb–Ta–W–Sn deposits. Metal assemblages of those deposits reflect the source materials of magmas in both granitic belts.  相似文献