Carbon isotopic study on coexisting calcite and graphite in the Ryoke metamorphic rocks,northern Kiso district,central Japan     

Toshiro Morikiyo 《Contributions to Mineralogy and Petrology》1984,87(3):251-259

Carbon isotope fractionation between coexisting calcite and grpahite ( ¹³C_cc-gr) has been determined in metamorphosed limestones and calc-silicate rocks from the Ryoke metamorphic belt in the northern Kiso district. In this district, the Ryoke metamorphic rocks, ranging from the lower greenschist facies to the upper amphibolite facies, are widely distributed. The fractionation of ¹³C/¹²C between calcite and graphite decreases regularly with increasing metamorphic grade and is independent of absolute ¹³C values of calcite. This evidence suggests that carbon isotopic exchange equilibrium has been attained during metamorphism even in the greenschist facies and isotopic modification, possibly caused by retrogressive metamorphism, is not distinguished. For T=270–650° C, the fractionation is expressed by the following equation: ¹³C_cc-gr=8.9×10⁶T^–2–7.1 (T in °K).This equation has a slope steeper than the current results on the ¹³C_cc-gr versus 10⁶T^–2 diagram. It can be used as a potential geothermometer for almost the entire temperature range of metamorphism. ¹³C values of carbonaceous matter in unmetamorphosed limestones in this district are approximately –22, due to its biogenic origin. Graphite from metamorphosed limestones is also considered to be of biogenic origin but shows enrichment of ¹³C due to isotopic exchange with calcite. ¹³C values of graphite as well as ¹³C_cc-gr confirm that zone II represents the lowest grade zone of Ryoke metamorphism. The maximum equilibrium fractionation of ¹³C between calcite and graphite is considered to be approximately 23%, which corresponds to 270° C. Below this temperature, it seems that carbon isotopic exchange between the minerals does not occur.Calcite in marble from the higher grade zones has relatively lower ¹³C and ¹⁸O values. The depletion of heavy isotopes is considered to be caused by the loss of ¹³C and ¹⁸O enriched carbon dioxide during decarbonation reactions. For oxygen, it is considered that isotopic exchange with metamorphic fluids plays an important role in lowering the ¹⁸O value of calcite in some higher grade marbles.  相似文献   

Hydrogen and carbon isotope studies on the graphite-bearing metapelites in the northern Kiso district of central Japan     

Toshiro Morikiyo 《Contributions to Mineralogy and Petrology》1986,94(2):165-177

Measurements were made of the hydrogen isotope ratios of hydrous silicates (mica and amphibole) and whole rocks, and the carbon isotope ratios of graphite and carbonaceous matter in the metamorphic rocks from the northern Kiso district in central Japan.D values of hydrous silicates in the graphite-bearing metapelites are always higher than those in graphite-free schists, even though the sample localities of the two rock-types are very close. Hydrogen isotopic equilibrium has been attained between the coexisting minerals.D/H ratios of water in the metamorphic fluids seem to depend strongly on the presence or absence of graphite and seem to be not constant throughout the district. The district is divided into three areas of low (metamorphic zones I, II), medium (zones IIIa–V) and high ¹³C_gr value (zones VIa–VII) areas. In the high ¹³C_gr values area, the carbon contents of the graphite-bearing rocks decrease slightly from zones VIa to VII, whereas the ¹³C_gr values increase sharply from the upper part of zone VIa to VIb. TheD values of biotite in these graphite-bearing rocks are higher than those in the medium ¹³C_gr area. This suggests that methane enriched inH and¹²C is produced and liberated by the devolatilization reactions between muscovite, graphite and water. The fluid produced is composed of water, methane and a subordinate amount of carbon dioxide, and its logfO₂ value is deduced to be about 1.2 lower than that defined by the FMQ buffer. In the medium ¹³C_gr area, the ¹³C values of graphite are nearly constant (–20.8), while the Fe₂O₃/(Fe₂O₃ + FeO) ratio of the graphite-bearing rocks apparently decreases with increasing metamorphic grade.D differences in hydrous silicates between graphite-bearing and graphite-free rocks are observed. These facts are interpreted to mean that methane was produced in addition to water and carbon dioxide, and that its generation ( ratio of the fluid was about 2) had practically no isotope effect on the graphite. In the low ¹³C_gr area, the carbon contents of the rocks decrease clearly from zones I to IIIa. TheD and ¹³C_gr values of the non-metamorphosed shales are much lower than those of the low grade graphite-bearing metapelites. This suggests that methane is produced and liberated from the rocks even at the incipient stage of metamorphism.  相似文献   

In-situ dissolution experiment of radiolaria in the central North Pacific ocean     

Jonathan Erez  Kozo Takahashi  Susumu Honjo 《Earth and Planetary Science Letters》1982,59(2):245-254

Monospecific phaeodarian radiolarian assemblages of Castanidium longispinum were suspended in plastic cages built with 225 μm nylon mesh at different water depths from 378 to 5582 m in the central North Pacific. Weight losses of these samples after a suspension period of 61 days were used to determine dissolution rates. The highest weight losses were observed at 378 m where samples lost ～90% of their initial weight. Through the main thermocline weight losses decreased from 90 to 60% and reached a constant value of 40% below it. These weight losses are roughly an order of magnitude higher than those reported by earlier workers. The higher weight losses can be attributed in part to the more soluble nature of the phaeodarian radiolarian skeletons and in part to the improved experimental technique. Kinetic considerations show that temperature is the major factor that controls silica dissolution rates in the ocean. Using an Arrehnius plot for the apparent rate constants, it can be shown that in surface water dissolution rats should be two orders of magnitude higher than in deep water below the main thermocline.  相似文献   

Stoichiometric control of crystal/liquid single-component partition coefficients     

E. Takahashi  T.N. Irvine 《Geochimica et cosmochimica acta》1981,45(7):1181-1185

Single-component (e.g., single-element) partition coefficients for silicate melts and the minerals that crystallize from them typically show large variations with temperature and melt composition. It is shown that, in particular cases, these variations can be calculated from two-component distribution coefficients that are practically constants, given the structural formula of the mineral and the melt composition.  相似文献   

Partitioning Eddy-Covariance Methane Fluxes from a Shallow Lake into Diffusive and Ebullitive Fluxes   总被引：1，自引：0，他引：1  

Hiroki Iwata  Ryuichi Hirata  Yoshiyuki Takahashi  Yuichi Miyabara  Masayuki Itoh  Kotaro Iizuka 《Boundary-Layer Meteorology》2018,169(3):413-428

Methane (\(\mathrm {CH}_{4}\)) is known to be emitted from lakes to the atmosphere via processes such as diffusion and ebullition (i.e., bubble emission). We developed a practical method for partitioning eddy-covariance \(\mathrm {CH}_{4}\) fluxes from a shallow lake into diffusive and ebullitive fluxes using a wavelet analysis based on local scalar similarity between the \(\mathrm {CH}_{4}\) concentration and other reference scalars, such as the air temperature or water vapour concentration, in the wavelet time-scale domain, with the hypothesis that similar and dissimilar fluctuation components are related to diffusive and ebullitive \(\mathrm {CH}_{4}\) fluxes, respectively. Our method is applied to approximately two weeks of data obtained at a shallow mid-latitude lake. The partitioned diffusive flux has a physically sound relationship with wind speed, supporting the validity of the method. The ratio of the diffusive flux to the total flux is typically 0.11 with flow from an area of steady bubble emission, but otherwise 0.36. Further validation is required using a larger dataset and data from other lakes. The proposed method can be easily applied to historical data because it requires only 10-Hz data of \(\mathrm {CH}_{4}\) concentration and other reference scalars, along with an empirical parameter.  相似文献   

What dynamics drive future wind scenarios for coastal upwelling off Peru and Chile?     

Ali Belmadani  Vincent Echevin  Francis Codron  Ken Takahashi  Clémentine Junquas 《Climate Dynamics》2014,43(7-8):1893-1914

The dynamics of the Peru–Chile upwelling system (PCUS) are primarily driven by alongshore wind stress and curl, like in other eastern boundary upwelling systems. Previous studies have suggested that upwelling-favorable winds would increase under climate change, due to an enhancement of the thermally-driven cross-shore pressure gradient. Using an atmospheric model on a stretched grid with increased horizontal resolution in the PCUS, a dynamical downscaling of climate scenarios from a global coupled general circulation model (CGCM) is performed to investigate the processes leading to sea-surface wind changes. Downscaled winds associated with present climate show reasonably good agreement with climatological observations. Downscaled winds under climate change show a strengthening off central Chile south of 35°S (at 30°S–35°S) in austral summer (winter) and a weakening elsewhere. An alongshore momentum balance shows that the wind slowdown (strengthening) off Peru and northern Chile (off central Chile) is associated with a decrease (an increase) in the alongshore pressure gradient. Whereas the strengthening off Chile is likely due to the poleward displacement and intensification of the South Pacific Anticyclone, the slowdown off Peru may be associated with increased precipitation over the tropics and associated convective anomalies, as suggested by a vorticity budget analysis. On the other hand, an increase in the land–sea temperature difference is not found to drive similar changes in the cross-shore pressure gradient. Results from another atmospheric model with distinct CGCM forcing and climate scenarios suggest that projected wind changes off Peru are sensitive to concurrent changes in sea surface temperature and rainfall.  相似文献   

Anomalously large seismic amplifications in the seafloor area off the Kii peninsula     

Takeshi Nakamura  Masaru Nakano  Naoki Hayashimoto  Narumi Takahashi  Hiroshi Takenaka  Taro Okamoto  Eiichiro Araki  Yoshiyuki Kaneda 《Marine Geophysical Researches》2014,35(3):255-270

Seismic wave amplifications were investigated using strong-motion data obtained from the ground’s surface (K-net) on the Kii peninsula (southwestern Japan) and from the network of twenty seismic stations on the seafloor (DONET) located off the peninsula near the Nankai trough. Observed seismograms show that seismic signals at DONET stations are significantly larger than those at K-net stations, independent of epicentral distances. In order to investigate the cause of such amplifications, seismic wavefields for local events were simulated using the finite-difference method, in which a realistic 3D velocity structure in and around the peninsula was incorporated. Our simulation results demonstrate that seismic waves are significantly amplified at DONET stations in relation to the presence of underlying low-velocity sediment layers with a total thickness of up to 10 km. Our simulations also show considerable variations in the degree of amplification among DONET stations, which is attributed to differences in the thickness of the sediment layers. The degree of amplification is relatively low at stations above thin sediment layers near the trough axis, but seismic signals are much more amplified at stations closer to the Kii peninsula, where sediment layers are thicker than those at the trough axis. Simulation results are consistent with observations. This study, based on seafloor observations and simulations, indicates that because seismic signals are amplified due to the ocean-specific structures, the magnitude of earthquakes would be overestimated if procedures applied to data observed at land stations are used without corrections.  相似文献   

An index for tropical temperate troughs over southern Africa     

Satyaban B. Ratna  Swadhin Behera  J. Venkata Ratnam  Keiko Takahashi  Toshio Yamagata 《Climate Dynamics》2013,41(2):421-441

Strong cases of the tropical temperate troughs (TTT) that are responsible for the most of the summer rainfall over subtropical southern Africa are analyzed. An index for identifying the TTT is introduced for the first time using anomalies of outgoing longwave radiation (OLR) and the wind. The TTT is associated with a ridge-trough-ridge wave-like structure in the lower troposphere over southern Africa and the adjoining Indian Ocean. Therefore, the index considers physical processes that occur over southern Africa, adjoining the Atlantic and Indian Oceans to depict the variability of the TTT events. Unusually strong TTT events are identified when the standard deviations of the TTT indices defined by the OLR and wind anomalies in the selected regions are above 1.5 and 0.5 respectively. After applying this criterion and filtering out consecutive events, 55 TTT events are identified during the study period of December–January–February seasons from 1980–1981 to 2009–2010. From the composite analyses of those 55 events, it is found that the TTTs evolve with suppressed (enhanced) convection over the southwest Indian Ocean adjacent to Madagascar (southern Africa). The suppressed convection is, in turn, found to be associated with the enhanced convection around Sumatra in the southeast tropical Indian Ocean. This may explain why more TTT events occur in La Niña years as compared to El Niño years. Time evolution of the canonical TTT event shows that it starts 3 days prior to the mature phase of the event, suggesting possible predictability. After reaching a matured state, the system moves east toward the Indian Ocean and decays within the subsequent couple of days. In addition, the intertropical convergence zone (ITCZ) structure changes over Southern Africa/Madagascar during the TTT event and remains similar to climatology over other regions. The results indicate that the continental part of the ITCZ intensifies prior to the TTT event and then spreads southward following the mid-latitude influence during and after the event.  相似文献   

Comparison of carbon cycle between the western Pacific subarctic and subtropical time-series stations: highlights of the K2S1 project     

Makio C. Honda  Masahide Wakita  Kazuhiko Matsumoto  Tetsuichi Fujiki  Eko Siswanto  Kosei Sasaoka  Hajime Kawakami  Yoshihisa Mino  Chiho Sukigara  Minoru Kitamura  Yoshikazu Sasai  Sherwood L. Smith  Taketo Hashioka  Chisato Yoshikawa  Katsunori Kimoto  Shuichi Watanabe  Toru Kobari  Toshi Nagata  Koji Hamasaki  Ryo Kaneko  Mario Uchimiya  Hideki Fukuda  Osamu Abe  Toshiro Saino 《Journal of Oceanography》2017,73(5):647-667

A comparative study of ecosystems and biogeochemistry at time-series stations in the subarctic gyre (K2) and subtropical region (S1) of the western North Pacific Ocean (K2S1 project) was conducted between 2010 and 2013 to collect essential data about the ecosystem and biological pump in each area and to provide a baseline of information for predicting changes in biologically mediated material cycles in the future. From seasonal chemical and biological observations, general oceanographic settings were verified and annual carbon budgets at both stations were determined. Annual mean of phytoplankton biomass and primary productivity at the oligotrophic station S1 were comparable to that at the eutrophic station K2. Based on chemical/physical observations and numerical simulations, the likely “missing nutrient source” was suggested to include regeneration, meso-scale eddy driven upwelling, meteorological events, and eolian inputs in addition to winter vertical mixing. Time-series observation of carbonate chemistry revealed that ocean acidification (OA) was ongoing at both stations, and that the rate of OA was faster at S1 than at K2 although OA at K2 is more critical for calcifying organisms.  相似文献