Optimization of dissolved urea measurements in coastal waters with the combination of a single reagent and high temperature     

Md. Shafiul Alam  Beatriz E. Casareto  Yoshimi Suzuki  Rumana Sultana  Toshiyuki Suzuki 《Journal of Oceanography》2017,73(2):249-258

Urea is an unstable and intermediate organic nitrogenous compound present in coastal environments and is derived from the excretion of some aquatic organisms and wastewater discharges. Urea plays an important role in the nitrogen cycle, where it is utilized by algae, including diatoms. However, there are very limited relevant data on the production, consumption, and degradation of urea because of the lack of appropriate measurement techniques. The conventional method is based on the formation of a colored product when urea reacts with diacetyl monoxime in a sulfuric acid solution. We examined the optimal conditions for the formation of the colored product; specifically, we evaluated different temperatures (22–80 °C), reaction times, mixing ratios of color reagents, and sample storage times. Application of the single mixed color-developing reagent (COLDER) at 70 °C resulted in the optimal formation of the colored product within a short reaction time of 60 min. This method was then used to measure dissolved urea in different coastal environments. The concentrations detected were as follows: 0.65–0.72, 0.49–0.58, and 1.09–2.28 µM urea-N at coral reef, seagrass, and mangrove sites, respectively. Our results showed high precision (SD = 0.02, CV = 1.2%), a low detection limit (0.03 µM urea-N), and a high recovery rate (94–99%). In summary, this high-temperature procedure for urea measurements should be valuable for obtaining high-precision data that can further the understanding of urea dynamics and its role in coastal ecosystems.  相似文献   

Large-amplitude internal waves observed in the Kruzenshtern Strait of the Kuril Island Chain and possible water transport and mixing     

Tomohiro Nakamura  Yasuhiro Kawasaki  Tokihiro Kono  Toshiyuki Awaji 《Continental Shelf Research》2010

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Opening and closing process of the Paleo-Tethys in Northern Thailand     

Hidetoshi HARA  Koji WAKITA  Jun-ichiro KURODA  Toshiyuki KURIHARA  Katsumi UENO  Yoshihito KAMATA  Ken-ichiro HISADA  Punya CHARUSIRI  Thasinee CHAROENTITIRAT  Pol CHAODUMRONG 《地球学报》2009,30(Z1):12-12

The Paleo-Tethys formed a large ocean basin that existed between Laurasia and Gondwana during Late Paleozoic to Early Mesozoic times. It opened in the Early Devonian by the rifting of Gondwanaland and closed at around latest Triassic time by the collision of the Cimmerian continent to Laurasia (Metcalfe, 1999). We reconstructed opening and closing process of the Paleo-Tethys in Northern Thailand.  相似文献   

Non-Fickian mass transport in fractured porous media     

Sergei A. Fomin  Vladimir A. ChugunovToshiyuki Hashida 《Advances in water resources》2011,34(2):205-214

The paper provides an introduction to fundamental concepts of mathematical modeling of mass transport in fractured porous heterogeneous rocks. Keeping aside many important factors that can affect mass transport in subsurface, our main concern is the multi-scale character of the rock formation, which is constituted by porous domains dissected by the network of fractures. Taking into account the well-documented fact that porous rocks can be considered as a fractal medium and assuming that sizes of pores vary significantly (i.e. have different characteristic scales), the fractional-order differential equations that model the anomalous diffusive mass transport in such type of domains are derived and justified analytically. Analytical solutions of some particular problems of anomalous diffusion in the fractal media of various geometries are obtained. Extending this approach to more complex situation when diffusion is accompanied by advection, solute transport in a fractured porous medium is modeled by the advection-dispersion equation with fractional time derivative. In the case of confined fractured porous aquifer, accounting for anomalous non-Fickian diffusion in the surrounding rock mass, the adopted approach leads to introduction of an additional fractional time derivative in the equation for solute transport. The closed-form solutions for concentrations in the aquifer and surrounding rocks are obtained for the arbitrary time-dependent source of contamination located in the inlet of the aquifer. Based on these solutions, different regimes of contamination of the aquifers with different physical properties can be readily modeled and analyzed.  相似文献   

Theoretical and experimental investigation of nickel isotopic fractionation in species relevant to modern and ancient oceans     

Toshiyuki Fujii  Frédéric Moynier  Minori Abe 《Geochimica et cosmochimica acta》2011,75(2):469-7643

Nickel plays a central role as an enzyme co-factor in the metabolism of methanogenic Archaea. Methanogens can fractionate Ni isotopes during assimilation, opening the possibility of using the stable isotopic composition of Ni as a biomarker. However, other sources of Ni isotopic variations need to be evaluated before one can establish Ni isotopes as an unambiguous tracer of methanogenesis in the rock record. Equilibrium exchange of Ni between the different species present in the ocean is a potential source of isotopic fractionation. Through controlled laboratory experiments and theoretical calculations, we quantify equilibrium Ni isotope fractionation between different species relevant to the modern and ancient ocean: Ni(H₂O)₆²⁺, Ni(H₂O)₁₈²⁺, NiOH(H₂O)₅⁺, Ni(OH)₂(H₂O)₄, NiCl(H₂O)₅⁺, cis-NiCl₂(H₂O)₄, trans-NiCl₂(H₂O)₄, NiHS(H₂O)₅⁺, Ni(HS)₂(H₂O)₄, NiSO₄(H₂O)₄, NiHCO₃(H₂O)₄⁺, NiCO₃(H₂O)₄, and organic ligands (crown ether and oxalic acid). The magnitude of ligand-controlled Ni isotopic fractionation, approximately 1.25‰/amu (2.5‰ for the ⁶⁰Ni/⁵⁸Ni ratio), is similar to that previously measured in cultures of methanogenic Archaea.  相似文献   

Ab initio calculations of the Fe(II) and Fe(III) isotopic effects in citrates,nicotianamine, and phytosiderophore,and new Fe isotopic measurements in higher plants     

Frédéric Moynier  Toshiyuki Fujii  Kun Wang  Julien Foriel 《Comptes Rendus Geoscience》2013,345(5-6):230-240

Iron is one of the most abundant transition metal in higher plants and variations in its isotopic compositions can be used to trace its utilization. In order to better understand the effect of plant-induced isotopic fractionation on the global Fe cycling, we have estimated by quantum chemical calculations the magnitude of the isotopic fractionation between different Fe species relevant to the transport and storage of Fe in higher plants: Fe(II)-citrate, Fe(III)-citrate, Fe(II)-nicotianamine, and Fe(III)-phytosiderophore. The ab initio calculations show firstly, that Fe(II)-nicotianamine is ～3‰ (⁵⁶Fe/⁵⁴Fe) isotopically lighter than Fe(III)-phytosiderophore; secondly, even in the absence of redox changes of Fe, change in the speciation alone can create up to ～1.5‰ isotopic fractionation. For example, Fe(III)-phytosiderophore is up to 1.5‰ heavier than Fe(III)-citrate₂ and Fe(II)-nicotianamine is up to 1‰ heavier than Fe(II)-citrate. In addition, in order to better understand the Fe isotopic fractionation between different plant components, we have analyzed the iron isotopic composition of different organs (roots, seeds, germinated seeds, leaves and stems) from six species of higher plants: the dicot lentil (Lens culinaris), and the graminaceous monocots Virginia wild rye (Elymus virginicus), Johnsongrass (Sorghum halepense), Kentucky bluegrass (Poa pratensis), river oat (Uniola latifolia), and Indian goosegrass (Eleusine indica). The calculations may explain that the roots of strategy-II plants (Fe(III)-phytosiderophore) are isotopically heavier (by about 1‰ for the δ⁵⁶Fe) than the upper parts of the plants (Fe transported as Fe(III)-citrate in the xylem or Fe(II)-nicotianamine in the phloem). In addition, we suggest that the isotopic variations observed between younger and older leaves could be explained by mixing of Fe received from the xylem and the phloem.  相似文献   

Nuclear field shift in natural environments     

Frédéric Moynier  Toshiyuki Fujii  Gregory A. Brennecka  Sune G. Nielsen 《Comptes Rendus Geoscience》2013,345(3):150-159

The nuclear field shift (NFS) is an isotope shift in atomic energy levels caused by a combination of differences in nuclear size and shape and electron densities at the nucleus. The effect of NFS in isotope fractionation was theoretically established by Bigeleisen in 1996 [Bigeleisen J. (1996) J. Am. Chem. Soc. 118:3676–3680] and has been analytically measured in laboratory chemical exchange reactions. More recently, some isotopic variations of heavy elements (Hg, Tl, U) measured in natural systems as well as isotopic anomalies measured for lower-mass elements in meteorites have been attributed to the NFS effect. These isotopic variations open up new and exciting fields of investigations in Earth sciences. In this paper, we review the different natural systems in which NFS has been proposed to be the origin of isotopic variations.  相似文献   

Radiolaria‐dated Lower Permian clastic‐rock sequence in the Fukuji area of the Hida‐gaien terrane,central Japan,and its inter‐terrane correlation across Southwest Japan     

Toshiyuki Kurihara  Masao Kametaka 《Island Arc》2008,17(4):531-545

The stratigraphy and radiolarian age of the Mizuyagadani Formation in the Fukuji area of the Hida‐gaien terrane, central Japan, represent those of Lower Permian clastic‐rock sequences of the Paleozoic non‐accretionary‐wedge terranes of Southwest Japan that formed in island arc–forearc/back‐arc basin settings. The Mizuyagadani Formation consists of calcareous clastic rocks, felsic tuff, tuffaceous sandstone, tuffaceous mudstone, sandstone, mudstone, conglomerate, and lenticular limestone. Two distinctive radiolarian faunas that are newly reported from the Lower Member correspond to the zonal faunas of the Pseudoalbaillella u‐forma morphotype I assemblage zone to the Pseudoalbaillella lomentaria range zone (Asselian to Sakmarian) and the Albaillella sinuata range zone (Kungurian). In spite of a previous interpretation that the Mizuyagadani Formation is of late Middle Permian age, it consists of Asselian to Kungurian tuffaceous clastic strata in its lower part and is conformably overlain by the Middle Permian Sorayama Formation. An inter‐terrane correlation of the Mizuyagadani Formation with Lower Permian tuffaceous clastic strata in the Kurosegawa terrane and the Nagato tectonic zone of Southwest Japan indicates the presence of an extensive Early Permian magmatic arc(s) that involved almost all of the Paleozoic non‐accretionary‐wedge terranes in Japan. These new biostratigraphic data provide the key to understanding the original relationships among highly disrupted Paleozoic terranes in Japan and northeast Asia.  相似文献   

Seasonal Variation of Stratification in the Gulf of Thailand     

Tetsuo Yanagi  Suhendar I Sachoemar  Toshiyuki Takao  Shunji Fujiwara 《Journal of Oceanography》2001,57(4):461-470

Intensive hydrographic observations were carried out in the western part of the Gulf of Thailand and the east coastal sea of Peninsular Malaysia in September 1995 and April–May 1996. The characteristics of seasonal variation of oceanic condition in that area are discussed basis of an analysis of observed water temperature, salinity and density distributions in these cruises and NAGA cruises (Yanagi and Takao, 1998a). Stratification is most developed in March–May mainly due to large sea surface heating and weak sea surface wind, which weakened until September–October, vanishing in December–January. The horizontal distribution of bottom cold, saline and heavy water masses, which are found during the stratified season, is governed by the tidal mixing and the water depth. Water exchange between the Gulf of Thailand and the South China Sea becomes large in March–May due to a coupled effect of the intensified estuarine circulation and the Ekman transport by the southwest monsoon. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

The reversible effect of temperature on the chemical composition of interstitial water of marine sediment     

Toshiyuki Masuzawa  Satoru Kanamori  Yasushi Kitano 《Journal of Oceanography》1980,36(1):68-72

The reversibility of the temperature effect on the chemical composition of interstitial waters of three deep-sea sediment samples was examined between 2 and 25°C for Cl, Na, K, Mg, Ca, Si, B, Mn and alkalinity. When the temperature of sediment samples was returned from 25°C to the initial value of 2°C, most chemical species gave nearly their initial concentrations. However, for alkalinity and in one case for magnesium, it took another three to four hours to reach their initial concentrations.  相似文献