Factors Controlling In Situ Biogeochemical Transformation of Trichloroethene: Column Study     

Patrick J. Evans  Dung Nguyen  Rick W. Chappell  Kent Whiting  John Gillette  Adria Bodour  John T. Wilson 《Ground Water Monitoring & Remediation》2014,34(3):65-78

In situ biogeochemical transformation involves biological formation of reactive minerals in an aquifer that can destroy chlorinated solvents such as trichloroethene (TCE) without accumulation of intermediates such as vinyl chloride. There is uncertainty regarding the materials and geochemical conditions that are required to promote biogeochemical transformation. The objective of this study was to identify amendments and biogeochemical conditions that promote in situ biogeochemical transformation. Laboratory columns constructed with plant mulch were supplemented with different amendments and were operated under varying conditions of water chemistry and hydraulic residence time. Four patterns of TCE removal were observed: (1) no removal, (2) biotic transformation of TCE to cis‐1,2‐dichloroethene (cis‐1,2‐DCE), (3) biogeochemical transformation of TCE without accumulation of reductive dechlorination products, and (4) mixed behavior where a combination of patterns was observed either simultaneously or over time. Principal coordinates analysis and analysis of variance (ANOVA) identified factors that promoted biogeochemical transformation: (1) high influent sulfate concentration, (2) relatively high hydraulic retention time, (3) supplementation of mulch with vegetable oil, and (4) addition of hematite or magnetite. The combination of the first three factors promoted complete sulfate reduction and a high volumetric sulfate consumption rate. The fourth factor provided a source of ferrous iron and/or a surface to which sulfide could react to form reactive iron sulfides. Many columns demonstrated either no TCE removal or a biotic TCE transformation pattern. Modification of column operation to include all four factors identified above promoted biogeochemical transformation in these columns. These results support the importance of the factors in biogeochemical transformation.  相似文献   

Experimental evidence of the double-porosity effects in geomaterials     

Tien Dung Tran Ngoc  Jolanta Lewandowska  Henri Bertin 《Acta Geophysica》2014,62(3):642-655

Double-porosity is an important characteristic of microstructure in a large range of geomaterials. It designs porous media with connected fissures/fractures or aggregated soils. The origin of double-porosity can be natural or/and it can result from mechanical, chemical or biological damage. The presence of double-porosity can significantly affect the behaviour of geomaterials. In this paper we provide an experimental evidence of the double-porosity effects by performing laboratory experiments. Series of tracer dispersion experiments (in saturated and unsaturated steady-state water flow conditions) in a physical model of double-porosity geomaterial were carried out. For the comparative purposes, experiments of the same type were also performed in a singleporosity model medium. The results clearly showed that the double-porosity microstructure leads to the non-Fickian behaviour of the tracer (early breakthrough and long tail) in both saturated and unsaturated cases.  相似文献   

Field strength prediction of mobile communication network based on GIS     

CHEN Xiaoyong  WU Hualing  Tran Minh TRI 《地球空间信息科学学报》2012,15(3)

  相似文献   

东南亚断裂构造的演化     

高庭朝  阮友宣  黎文勇  范南雄  Mai Xuan Bach  Thai Anh Tuan 《大地测量与地球动力学》2005,25(1):51-60

本研究项目是采用诸如地质学解释、影像判读和地球物理探测等多种方法相结合进行的。在所得结果的基础上参考了越南国内外同行的一些资料编制了东南亚、越南及邻区的断裂构造图．其比例尺分别为1：4百万和1：1百万。分析所得结果显示出东南亚断裂构造演化的下列情况：1)在现今地质结构方面东南亚是欧亚岩石圈板块的东南部分．由一条消减带围绕．这条消减带的伸展从Myanmer开始,通过Nicobar,Java Timor直到东菲律宾。东南亚被Song Hong(即红河)断裂,Three Pagodas断裂和Hainam-Natuna断裂等2级断裂系统分成3个微板块。2)在早新生代．东南亚是分为5个微板块的。它们的分界断裂中有2个一级断裂(中央东海扩张带和Lupar-Kuching消减带)和3个二级断裂(即上述3个)。3)上述绝大多数二和三级断裂从晚新生代起活化且继承了从早新生代即已发生和发展了的二、三级断裂,但在某些条件下．运动方向却完全变成了相反,尤其是走滑运动的方向。我们的研究结果表明：在这一地区内,盆地、隆起、岩浆侵入、褶皱和局部断裂等构造的形成都取决于这些沿着一、二级走滑断裂的微板块运动。  相似文献   

Measurements of Rare Earth Element and Other Element Mass Fractions in Environmental Reference Materials (NIST SRM 1646a,NIST SRM 1400, IAEA‐395 and IAEA‐450) by INAA,ICP‐AES and ICP‐MS          下载免费PDF全文

Vu Dong Cao  Raymond Sucgang  Thien Quang Tran  Doanh Van Ho  Naoki Shirai  Mitsuru Ebihara 《Geostandards and Geoanalytical Research》2017,41(2):303-315

INAA, ICP‐AES and ICP‐MS were used to elementally characterise four environmental reference materials – NIST SRM 1646a (Estuarine Sediment), NIST SRM 1400 (Bone Ash), IAEA‐395 (Urban Dust) and IAEA‐450 (Algae). An analytical scheme consisting of the three methods was first applied to NIST SRM 1646a to validate the methodology because it has been extensively analysed and has certified values for many elements. With repeated analyses of NIST SRM 1646a, the accuracy and measurement repeatability of the data obtained were evaluated based on two statistical calculations (zeta‐score and Horwitz ratio) and were observed to be good enough for the analytical scheme to be applied to similar sorts of environmental/geochemical samples. Applying the same approach to NIST SRM 1400, IAEA‐395 and IAEA‐450, enabled mass fractions of 29, 38 and 28 elements to be determined, respectively. Among these results, the data for rare earth elements are of particular interest, not only for IAEA‐450 but also for the other three reference samples. The data for Pr, Gd, Dy, Ho, Er and Tm in NIST SRM 1646a are newly reported in this study. By using small test portions (< 100 mg) for NIST SRM 1646a and IAEA‐395, and recommended minimum amounts for NIST SRM 1400 and IAEA‐450, sample homogeneity was evaluated.  相似文献   

Comparing the performance of TRIGRS and TiVaSS in spatial and temporal prediction of rainfall-induced shallow landslides   总被引：1，自引：0，他引：1  

The Viet Tran  Giha Lee  Hyunuk An  Minseok Kim 《Environmental Earth Sciences》2017,76(8):315

This study compares the performance of transient rainfall infiltration and grid-based regional slope stability (TRIGRS) model and time-variant slope stability (TiVaSS) model in the prediction of rainfall-induced shallow landslides. TRIGRS employs one-dimensional (1-D) subsurface flow to simulate the infiltration rate, whereas a three-dimensional (3-D) model is utilized in TiVaSS. The former has been widely used in landslide modeling, while the latter was developed only recently. Both programs are used for the spatiotemporal prediction of shallow landslides caused by rainfall. This study uses the July 2011 landslide event that occurred in Mt. Umyeon, Seoul, Korea, for validation. The performance of the two programs is evaluated by comparison with data of the actual landslides in both location and timing by using a landslide ratio for each factor of safety class (\({\text{LR}}_{\text{class}}\) index), which was developed for addressing point-like landslide locations. Moreover, the influence of surface flow on landslide initiation is assessed. The results show that the shallow landslides predicted by the two models are highly consistent with those of the observed sliding sites, although the performance of TiVaSS is slightly better. Overland flow affects the buildup of the pressure head and reduces the slope stability, although this influence was not significant in this case. A slight increase in the predicted unstable area from 19.30 to 19.93% was recorded when the overland flow was considered. It is concluded that both models are suitable for application in the study area. However, although it is a well-established model requiring less input data and shorter run times, TRIGRS produces less accurate results.  相似文献   

Sandwaves on the Southeast Vietnam Shelf recorded by high resolution seismic profiles: formation and mechanism   总被引：1，自引：0，他引：1  

Viet Dung Bui  Alex Schimanski  Karl Stattegger  Phach Van Phung  The Tiep Nguyen  Tien Hai Nguyen  Trung Thanh Nguyen  Truong Thanh Phi 《Frontiers of Earth Science》2009,3(1):9-20

The application of high resolution seismic data using boomer sound source has revealed a wide distribution of large-scale bedforms (sandwaves) on the Southeast Vietnam continental shelf. Bedforms that are a few meters high in wave height and hundreds of meters long in wavelength are primarily developed in the inner shelf (20–40 m) and considered to be formed under the present-day marine hydrodynamic conditions. Those bedforms developed in the deeper water (120 m) of the northernmost part of the continent can be interpreted as the relict morphological features formed during the latest sea-level lowstand of the late Pleistocene period. Two sediment transport paths have been identified on the basis of the bedform’s leeward orientation: northeast-southwest (along-shore) and north-south (cross-shore). A quantitative bottom current map is constructed from sandwave dimensions, surface sediments and measurement data. The strongest current velocities that gradually decrease toward the southwest are indicated by large sandwaves in the north (field B). Water depth, surficial sediment composition and bottom current are three factors that control the development of bedforms.  相似文献   

The Nui Chua layered peridotite-gabbro complex as manifestation of Permo-Triassic mantle plume in northern Vietnam     

G.V. Polyakov  R.A. Shelepaev  Tran Trong Hoa  A.E. Izokh  P.A. Balykin  Ngo Thi Phuong  Tran Quoc Hung  Bui An Nien 《Russian Geology and Geophysics》2009,50(6):501-516

New data on the age, composition, formation conditions, and ore-geochemical specialization of the Nui Chua layered peridotite-gabbro complex are reported. They evidence that the complex resulted from the Permo-Triassic mantle plume activity in northern Vietnam (southern framing of the Yangtze Platform). Two series of mafic and ultramafic rocks differing in ore productivity—layered (PGE-Cu-Ni) and pegmatoid (Fe-Ti-V)—have been recognized within the complex. The first estimates of the composition of their parental melts have been obtained.  相似文献   

Trace metals in Japanese eel Anguilla japonica in relation to ecological migratory types and growth stages     

Dung Quang Le  Naoko Chino  Kotaro Shirai  Takaomi Arai 《Estuarine, Coastal and Shelf Science》2010

In order to understand the metal concentrations in Japanese eel Anguilla japonica, nine elements were analyzed in the livers of different migratory types of eels collected from Tokushima region (south Japan). Migratory types were defined by examining the Sr:Ca ratio in otoliths. The results showed that there were significant differences in V, Cr, Cd, and Pb concentrations among the migratory types. Mature-sea-eels show a higher risk of metal accumulation than other migratory types of eels, and the concentrations of Mn, Cu, and Zn in mature eels were significantly higher than those in immature eels. The study suggests that the eel liver is a valuable bioindicator for trace metals; however, when using the eel as a bioindicator to reveal the pollutants in aquatic systems, life history analysis should be carried out for accurate interpretation of the results.  相似文献   

Origin of the Permian-Triassic komatiites,northwestern Vietnam   总被引：7，自引：0，他引：7  

Eero?HanskiEmail author  Richard?J.?Walker  Hannu?Huhma  Gleb?V.?Polyakov  Pavel?A.?Balykin  Tran Trong Hoa  Ngo Thi Phuong 《Contributions to Mineralogy and Petrology》2004,147(4):453-469

Abstract Rare examples of Phanerozoic komatiites are found in the Song Da zone, NW Vietnam. These komatiites were erupted through continental crust and may belong to the SE extension of the Permo-Triassic Emeishan volcanic province located in SW China. They provide a good opportunity to study the source characteristics of starting plume magmas in a continental flood basalt province. Erupted on late-Permian carbonate rocks, the komatiitic rocks are interbedded with low-Ti olivine basalts. Basaltic komatiites display pyroxene spinifex textures, while more magnesian rocks (MgO up to 32 wt.%) are porphyritic, containing a single, cognate population of euhedral to elongated olivine phenocrysts with Fo up to 93.0%. This suggests a highly magnesian parental magma with 22–23 wt.% MgO. In terms of major and minor elements, the komatiites are similar to the ca. 89 Ma old Gorgona Island komatiites of Colombia. The Song Da komatiites are also strongly light-rare-earth-element- (LREE) depleted (Ce_N/Yb_N 0.30–0.62) and have unfractionated heavy rare earth element (HREE) patterns. The komatiites have high Os concentrations (up to 7.0 ppb), low but variable Re/Os ratios, and define an isochron with an age of 270±21 Ma, and an initial ¹⁸⁸Os/¹⁸⁷Os ratio of 0.12506± 0.00041 (_Os=+0.02±0.40). The Os isotopic systematics of the komatiites show no effects of crustal contamination. In contrast, their initial _Nd values range from +3 to +8, reflecting varying but generally small degrees of contamination with Proterozoic sialic basement material. Associated low-Ti basalts have low initial _Nd values (–0.8 to –7.5), high initial _Os values (15), flat or LREE-enriched REE patterns, and Nb-Ta depletion. These characteristics are also attributed to variable extents of crustal contamination.Editorial responsibility: T.L. Grove  相似文献