Electron spin resonance spectra of marine and fresh-water manganese nodules     

Stuart Wakeham  Roy Carpenter 《Chemical Geology》1974,13(1):39-47

Eighty ferromanganese nodules from a wide variety of marine and fresh-water environments have been analyzed by electron spin resonance spectroscopy. The purpose has been to gain information on the forms in which the major constituents of manganese nodules are present. Contributions to ESR spectra of the nodules come mainly from Mn²⁺ and Fe³⁺. Deep-sea samples generally showed only broad resonance lines, and those with larger peaks close to g = 2.0 are believed to contain more Mn²⁺ than others. Some Antarctic and fresh-water nodules lack a strong Mn²⁺ resonance and have a peak around g = 4.0 which is most likely tetrahedral Fe³⁺. A number of smaller peaks in several samples could not be readily interpreted in terms of contributions from individual ionic species because of fundamental problems in preparing standards having the ion of interest in the same micro-environment as it experiences in the nodules.  相似文献   

Distribution and Acoustic Characteristics of Shallow Gas in the Korea Strait Shelf Mud off SE Korea     

Dae Choul Kim  Gwang Hoon Lee  Young Kyo Seo  Gil Young Kim  Seok Yun Kim  Jeong Chang Kim  Soo Chul Park  Roy Wilkens 《Marine Georesources & Geotechnology》2004,22(1):21-31

Shallow gas in the Korea Strait shelf mud (KSSM) off SE Korea, revealed by high-resolution subbottom profiles, is associated with acoustic blanking, acoustic turbidity, seepages with plumes in the water column, and seafloor depressions. The acoustic blanking, characterized by strong, consistent top reflection and wipeout below, is most dominant. The seaward edge of the acoustic blanking zone generally coincides with the 100-m water-depth contour, suggesting that the water depth (the pressure) may control the distribution of shallow gas. The acoustic turbidity, characterized by diffuse top reflection, is a dark smear, partially blanking the data below. The seepages with plumes, characterized by vertical smearing and disturbed seafloor, are seen only along the shallowest, landward edge of the acoustic blanking zone. This may suggest that the decreased gas solubility at shallow water depths, caused by the lowered pressure, increases the volume of free gas in the sediments, facilitating the gas escape. The seafloor depressions, interpreted as pockmarks, are accompanied by cone-shaped acoustic masking, which is probably the reflection from a narrow vent of gas. The gas-related acoustic anomalies appear to occur mostly in the upper, recent mud of the KSSM. Neither permeable beds nor faults, which can act as vertical migration pathways for deep thermogenic gas, are evident in the recent mud. We interpret that the bacterial degradation of organic matter in situ is the main source for the gas in the KSSM. The upwelling off SE Korea may be an important source for the increased organic matter in the area.  相似文献   

A seismic survey to detect natural gas hydrate in the East Sea of Korea     

Jeong?Hwan?LeeEmail author  Young?Soon?Baek  Byong?Jae?Ryu  Michael?Riedel  Roy?D.?Hyndman 《Marine Geophysical Researches》2005,26(1):51-59

Recently, several countries have conducted projects to explore and develop natural gas hydrate, which is one of the new alternative energy resources for the future. In Korea, a five-year national research project was initiated in 2000. As part of this project, a seismic survey was performed in the East Sea of Korea to quantify the potential magnitude and distribution of natural gas hydrates. Multi-channel seismic data and core samples have been acquired and recovered in the survey area. Analysis of seismic data show clear bottom simulating reflectors (BSRs), seismic blank zones (or wipe-out zones) with velocity pull-up structure, and pock-marks. In this study, we present the results of seismic surveys which indicate the existence of natural gas hydrates in Korean offshore areas. These results will be applied to select areas for coring (or drilling) and detailed exploration such as 2D seismic survey with long offset or 3D seismic in the future.  相似文献   

Stratification approach for forest cover type and landuse mapping using IRS-1A LISS-II data — A case study     

S. Sudhakar  R. K. Das  D. Chakraborty  B. K. Bardhan Roy  A. K. Raha  P. Shukla 《Journal of the Indian Society of Remote Sensing》1994,22(1):21-29

Indian Remote Sensing Satellite-1A (IRS-1A) LISS-II data of 24th Nov., 1988 was analysed digitally to differentiate three density classes viz. dense/closed forest, open forest and degraded forest within each vegetation type in the district, Jalpaiguri, West Bengal. Stratification approach was used to classify separately forest cover into pure sal forests, mixed forests, riverine forests along with man-made sal/teak plantations. In this approach the forested and non-forested areas were classified separately through supervised classification techniques using maximum likelihood algorithm using VAX 11/780 based VIPS-32 Image Processing software. Later the two classified outputs were composited to provide entire area of the district. The forest cover of the district was 1420.89 sq. km, (22.82 percent). Other broad landuse/landcover dominant in the district include agricultural areas.(45.20 percent) and tea gardens (10.49 percent). The accuracy of the classified output was estimated to be 90 percent for forested areas and 85 percent in case of other landuse/landcover classes.  相似文献   

New REE and Trace Element Data on Two Kimberlitic Reference Materials by ICP-MS   总被引：1，自引：0，他引：1  

Parijat Roy  Vysetti Balaram  Anil Kumar  Manavalan Satyanarayanan  Thota Gnaneshwar Rao 《Geostandards and Geoanalytical Research》2007,31(3):261-273

Data on thirty-four minor and trace elements including all rare earth elements (REE) are reported for two kimberlitic international reference materials (SARM-39, MINTEK, RSA and MY-4, IGEM, Russia) by inductively coupled plasma-mass spectrometry (ICP-MS), some of them for the first time. Four digestion techniques (open acid, closed vessel acid, microwave and lithium metaborate fusion digestion) were used for the decomposition of samples for analysis by ICP-MS. Three other reference materials (USGS BHVO-1, CRPG BR-1 and ANRT UB-N) were analysed simultaneously using the same analytical methodology to assess the precision and accuracy of the determinations. The data obtained in this study compare well with working values wherever such values are available for comparison. Though open acid digestion was found to be very rapid, effective and convenient for the determination of several trace elements in kimberlitic samples, recoveries for heavy rare earth elements (HREE) were lower than the respective recoveries obtained by the other decomposition techniques used. The precision obtained was better than ± 6% RSD in the majority of cases with comparable accuracy. Chondrite-normalised plots of each RM for all the digestion techniques were smooth. The new data reported on the two kimberlitic reference materials make these samples useful for future geochemical studies of kimberlitic rocks.  相似文献   

Operational tropical cyclone intensity prediction—an empirical technique     

S. K. Roy Bhowmik  S. D. Kotal  S. R. Kalsi 《Natural Hazards》2007,41(3):447-455

One very specific operational requirement of the Tropical Cyclone (TC) Programme of the Regional Specialized Meteorological Centre, New Delhi is to provide 12-hourly forecasts valid up to 48 h (preferably 72 h) on the intensity of cyclones over the southern Indian Seas. In this paper, a simple empirical model for predicting the intensity of TCs occurring in the Bay of Bengal is proposed. The model parameter has been determined from a database assembled on 30 recent cyclones, and the model itself is based on the assumption that a TC intensifies exponentially. A method for correcting the forecast during subsequent observation hours (6- or 12-h intervals) is also presented. The results show that the forecast skill for forecasts of up to 48 h is reasonably good. The absolute mean errors are less than 12 knots for 48-h forecasts, with the forecast skill decreasing with time. With the incorporation of a correction procedure based on the latest observations, some improvement in the forecast skill can be obtained. The model is expected to be useful to operational forecasters.  相似文献   

Morphology and environment of cold-water coral carbonate mounds on the NW European margin   总被引：6，自引：0，他引：6  

A. J. Wheeler  A. Beyer  A. Freiwald  H. de Haas  V. A. I. Huvenne  M. Kozachenko  K. Olu-Le Roy  J. Opderbecke 《International Journal of Earth Sciences》2007,96(1):37-56

Cold-water coral carbonate mounds, owing their presence mainly to the framework building coral Lophelia pertusa and the activity of associated organisms, are common along the European margin with their spatial distribution allowing them to be divided into a number of mound provinces. Variation in mound attributes are explored via a series of case studies on mound provinces that have been the most intensely investigated: Belgica, Hovland, Pelagia, Logachev and Norwegian Mounds. Morphological variation between mound provinces is discussed under the premise that mound morphology is an expression of the environmental conditions under which mounds are initiated and grow. Cold-water coral carbonate mounds can be divided into those exhibiting “inherited” morphologies (where mound morphology reflects the morphology of the colonised features) and “developed” morphology (where the mounds assume their own gross morphology mainly reflecting dominant hydrodynamic controls). Finer-scale, surface morphological features mainly reflecting biological growth forms are also discussed.  相似文献   

Intercomparison of Secondary Inorganic Aerosol Concentrations in the UK with Predictions of the Unified Danish Eulerian Model     

Salah S. Abdalmogith  Roy M. Harrison  Zahari Zlatev 《Journal of Atmospheric Chemistry》2006,54(1):43-66

Nitrate and sulphate concentrations were measured over the period January 2002–December 2003 on daily basis at two stations in the UK: a rural site (Harwell) and an urban site (Belfast). The measurements were compared with model results obtained by using the Unified Danish Eulerian Model (UNI-DEM), which was run using both a coarse resolution grid (50 km × 50 km surface cells) and a fine resolution grid (10 km × 10 km surface cells). The results from the comparison show reasonably good agreement between concentrations measured at the two stations and calculated by the model. This is achieved despite the absence of aqueous phase sulphur oxidation chemistry in the model. The model results were also used to predict the spatial distributions of nitrate and sulphate concentrations in the UK which agree well with observations. The contribution of mainland European emission sources and that of UK sources to pollution levels in the UK was estimated. The relative proportions differ substantially across the UK with the imported contribution to UK sulphate and nitrate typically in the range 20–45% and 35–65% respectively.  相似文献   

Hydrological alteration along the Missouri River Basin: A time series approach   总被引：1，自引：0，他引：1  

Mark A. Pegg  Clay L. Pierce  Anindya Roy 《Aquatic Sciences - Research Across Boundaries》2003,65(1):63-72

Human alteration of large rivers is commonplace, often resulting in significant changes in flow characteristics. We used a time series approach to examine daily mean flow data from locations throughout the mainstem Missouri River. Data from a pre-alteration period (1925-1948) were compared with a post-alteration period (1967-1996), with separate analyses conducted using either data from the entire year or restricted to the spring fish spawning period (1 April-30 June). Daily mean flows were significantly higher during the post-alteration period at all locations. Flow variability was markedly reduced during the post-alteration period as a probable result of flow regulation and climatological shifts. Daily mean flow during the spring fish spawning period was significantly lower during the post-alteration period at the most highly altered locations in the middle portion of the river, but unchanged at the least altered locations in the upper and lower port ions of the river. Our data also corroborate other analyses, using alternate statistical approaches, that suggest similar changes to the Missouri River system. Our results suggest human alterations on the Missouri River, particularly in the middle portion most strongly affected by impoundments and channelization, have resulted in changes to the natural flow regime.  相似文献   

Remote Sensing Observations of Effects of Mountain Blocking on Travelling Gravity-Shear Waves and Associated Clouds     

Roger F. Reinking  A. Shelby Frisch  Brad W. Orr  David L. Korn  Luc R. Bissonnette  Gilles Roy 《Boundary-Layer Meteorology》2003,109(3):255-284

Trapped Kelvin–Helmholtz (K–H) waves and vortices were monitored as they were generated immediately upwind of a mountain and driven into the barrier by a low-level jet. A stratus cloud visually revealed the embedded, propagating, gravity-shear waves. Interactions of the waves with the mountain were deciphered using remote sensing measurements of the structure, motions, and microphysics within the cloud and conceptual models based on existing theories. The observations show that the mountain acted as a dam to the flow that was primed for, but did not spontaneously induce, the waves. In response to the blocking, the waves spatially developed a pattern of formation, amplification, and breakdown between the upstream flow and the barrier, and altered the associated clouds in the process. Notably, radar signatures of velocity variance depicted organized, intertwined ribbons of relatively large vorticity within the wave layer. These provided measured evidence of the vortex sheet and streamwise vortex tubes predicted by advanced K–Hinstability theory, the three-dimensional version of Scorer's `stripe', the layer of rotational fluid between opposed flows that led to the wave generation. A theory of resonant interaction of wave trains, but with blocking imposed, appears to explain the internal structure of the pile-up of the flow and wave amplification approaching the barrier. Evolution of the supporting atmospheric thermal structure and introduction of a boundary-layer flow reversal follow a current model of blocking, although some features may have developed more directly from wave-driven mixing. The remote sensors also measured the influence of the waves on the cloud liquid water, including a cumulative enlargement of droplets as they were carried through a series of waves.  相似文献