Mineralogy and Petrology - In this paper, we describe the metamorphic conditions of Fe-rich granulite and variations in rare earth elements (REE) between peak garnet porphyroblasts and secondary... 相似文献
A simple geochemical technique using the ratio of total sulfur (TS) to total organic carbon (TOC) was successfully used to reconstruct paleoenvironments in the Jurassic–Cretaceous Tetori Group, central Japan. The TS to TOC ratio is often employed as an effective parameter to separate modern marine or brackish sediments from freshwater deposits. To test the TS/TOC method for paleoenvironmental interpretation of the Tetori Group, we first analyzed TS/TOC for samples for which depositional conditions (i.e. marine, brackish or freshwater) had been recognized paleontologically. The results indicate that the method can effectively separate sedimentary rocks deposited under freshwater from marine and brackish settings. Once we had established the effectiveness of this method, we applied it to three sections of the Tetori Group, central Japan. Stratigraphic fluctuations in TS/TOC values revealed episodic incursions of marine or brackish conditions in the dominantly freshwater depositional sequence in the middle of the Jobu Formation of the Itoshiro Subgroup at the Izumi section, Fukui Prefecture. The same paleoenvironment is also suggested to occur at the top of the Tetori Group in the Tateyama section, Toyama Prefecture. This research provides important information to paleogeographers who currently lack evidence from facies fossils to indicate if the uppermost part of the Tetori Group represents marine or brackish settings. A chemostratigraphy of TS/TOC parameters potentially could provide a correlation among Jurassic–Cretaceous sequences along continental margins over East Asia. 相似文献
Dietary intake is one of the important routes of human exposure to brominated flame retardants (BFRs) such as polybrominated diphenyl ethers (PBDEs). The use of PBDEs may also result in exposure to polybrominated dibenzo-p-dioxins and dibenzofurans (PBDDs/DFs), as these compounds are impurities in technical mixtures of BFRs and can also be formed unintentionally by the same processes that generate chlorinated dioxins. This study determined the concentrations of polybrominated compounds in common seafood in Guangzhou and Zhoushan, and assessed the health risks of these chemicals via consumption of contaminated seafood. Seafood samples (fish, bivalves, shrimp, crab, and cephalopods) purchased from local markets in 2003 and 2004 were analyzed for PBDEs and PBDDs/DFs. The highest concentration of total PBDEs (46.3 ng g−1 lipid wt.) was detected in fish from Guangzhou, in which BDEs 47 and 209 were the two predominant congeners. The total daily intakes of PBDEs, PBDDs, and PBDFs were, 946, 6.39, and 6.54 pg kg−1 body weight (bw) in Guangzhou, and 489, 4.99, and 7.65 pg kg−1 bw in Zhoushan, respectively. The hazard ratios for PBDDs and PBDFs were both greater than unity, indicating that these compounds may pose some health risks to the local population. 相似文献
The Ediacaran Yangtze platform in South China, which represents depositional settings ranging from coastal to basinal, provides valuable information for understanding climate changes and animal evolution during the Ediacaran Period. Although the shallower settings have been investigated, research on the basinal sections has been limited. This has hampered efforts to establish stratigraphic correlations and understand the oceanographic setting of the Yangtze platform. In this paper, the chemostratigraphy of a basinal section at Fengtan, Hunan Province, is reported based on analyses of stable carbon isotope profiles in carbonates (δ13Ccarb), organic matter (δ13Corg), total organic carbon, 87Sr/86Sr ratios, and Mn, Rb, and Sr concentrations. The basinal section of the Doushantuo Formation, which is represented at Fengtan, provides data supporting regional correlations and oceanography. Three intervals in the Doushantuo Formation are correlated with the Three Gorges: (i) a negative δ13Ccarb anomaly with stable δ13Corg values and altered 87Sr/86Sr ratios in the lower section can be correlated to the boundary between Doushantuo Members 2 and 3 (Interval A); (ii) a relatively high δ13Ccarb anomaly with unaltered 87Sr/86Sr ratios (up to 0.7086) in the middle section corresponding to the lower part of Doushantuo Member 3 (Interval B); and (iii) a negative δ13Ccarb anomaly with lowered δ values in the upper section can be correlated to the long interval of negative δ13Ccarb (Interval C). The Gaskiers glaciation is likely represented in Interval A, and Interval C corresponds to the Shuram excursion reported for other Ediacaran localities. Our correlations confirm the depth gradient of δ13Ccarb in the Yangtze platform and imply that reductive conditions prevailed in the basinal section from the Early to Middle Ediacaran. Under such conditions, anaerobic degradation of organic carbon or methane perturbed the inorganic carbon isotopic compositions and was at least partly responsible for the depth gradient of δ13Ccarb. 相似文献
To help the decision making regarding where to locate new observation instruments on the seafloor, we examined the detectability of interplate earthquakes and slow slips in the Nankai subduction thrust in Japan using seafloor observation instruments. Here, the detectability is defined as the smallest magnitude of the interplate fault slip detected by the assumed observation points based on crustal deformation simulation. In the detectability analyses, we considered the effect of sensor drifts that are particularly associated with seafloor observations. In addition, we introduced high-resolution three-dimensional (3D) finite element modeling of crustal deformation to consider the effect of the topography and 3D heterogeneous crustal structure around the Nankai Trough. The results of the detectability analyses show that introducing new seafloor stations for tilt observation in the Nankai region should increase the detectability of small- or medium-sized interplate earthquakes and slow slips significantly. Based on the obtained results, we also discuss the advantage of both the existing and the new observation instruments in detecting interplate fault slips.
Primary data on the organic geochemistry of the Tetori Group provide basic information about depositional environments and thermal maturation of organic matter through two geological sections in the Hokuriku region, central Japan. The thermal maturity of organic matter was evaluated by the methylphenanthrene index‐1. The maturity progressively increases stratigraphically down through the Izumi section in Fukui Prefecture. The estimated vitrinite reflectance equivalent is <1.35% near the top of the section, gradually increasing to >2.0% near the base. The thermal maturation process can account for stratigraphic changes in abundance of PAHs through this section. However, the occasional occurrence of coronene in the middle of the Izumi section is attributed to possible paleo‐wildfires that supplied more coronene to the depositional site. The stratigraphic distribution of PAHs through the Tateyama section, Toyama Prefecture, also can be explained by the same scenario as envisaged for the Izumi section, but weathering and/or other secondary factors may have partly modified primary signals for this section. Polycyclic aromatic sulfur compounds were observed in nearly all samples from both sections, even in samples for which a freshwater paleoenvironment is surmised. Most plausibly, some reduced sulfur was re‐oxidized to elemental sulfur, which persisted in the sediments and may have contributed to the formation of aromatic sulfur compounds. Hence, polycyclic aromatic sulfur compounds do not provide an index to separate marine environments from the freshwater settings for the Tetori Group. 相似文献
An evaluation method for the mechanical behavior of unsaturated soils is studied in this paper. Although the mechanical behavior
of unsaturated soils is complicated, a simple modeling is preferable in practice. This is because the soil properties are
not homogeneous and ground data is limited when structures are being designed. In addition, in order to evaluate the reliability
of the design, the physical meanings of the parameters applied in the prediction model should be clear. Firstly, the authors
study the relationship between compaction curves and compression indexes in the unsaturated state that is used in the proposed
constitutive model. Based on the constitutive model, the stress paths for constant volume shear tests are formulated under
a constant void ratio condition and the stress paths for undrained shear tests are calculated under a constant water content
condition. In the case of unsaturated specimens, the volume of these specimens changes with the shear deformation and the
stress paths depend on the initial degree of saturation. The results of the calculation qualitatively describe the test results
by considering the changes in effective confining pressure in the undrained condition and the water retention curves. 相似文献
Water table dynamics, dissolved oxygen (DO) content, electrical resistivity (ER) in monitoring wells and air pressure in the vadose zone are monitored in air sparging (AS) accompanied by soil vapor extraction (SVE) at a hydrocarbon-contaminated groundwater site in Oman, where a diesel spillover affected a heterogeneous unconfined aquifer. The formation of a groundwater mound at the early stage of air injection and potential lateral migration of contaminants from the mound apex called for an additional hydrodynamic barrier constructed as a pair of pump-and-treat (P&T) wells whose recirculation zone encompassed the AS and SVE wells. In all monitored piezometers the phreatic surface showed a rapid and distinct peak, which is attributed to the time of air breakthrough from the injection point to the vadose zone and a relatively mild recession limb interpreted as a decay of the mound. Tracer tests showed a layer of a relatively low hydraulic conductivity at an intermediate depth of the screened interval of the wells. Increased levels of DO and borehole air pressure that have been observed (as far as 50 m away) are likely mitigated by SVE and P&T. Radius of influence can be indirectly inferred from ER and DO changes in the AS operation zone. Salt tracer tests have shown that groundwater velocity within the AS zone decreases with the increase of air injection rate. 相似文献
This paper reports the first evidence of ultrahigh-temperature (UHT) metamorphism from the Sør Rondane Mountains, eastern Dronning Maud Land, East Antarctica, which is evident as orthopyroxene + spinel symplectite in an amphibolitized mafic granulite. The granulite consists of olivine, orthopyroxene, clinopyroxene, pargasitic amphibole, plagioclase, and ilmenite, and it possesses a within-plate alkali basalt signature. The local bulk chemical composition of symplectite, major and trace element compositions, and thermodynamic calculations for the symplectite, suggest the presence of garnet at the high-pressure stage and that the symplectite formed from garnet, olivine, and primary orthopyroxene by decompression from more than 12 kbar at 1000 °C. The granulite records a subsequent amphibolite-facies overprint (<700 °C at <6 kbar) that involved the chemical re-equilibration of several phases. The obtained pressure–temperature (P–T) conditions and P–T path are different from the UHT metamorphism from the Schirmacher Hills, central Dronning Maud Land, which is considered to have occurred in a back-arc tectonic setting. The relatively high-P conditions and the decompression path reconstructed in the present study are similar to those reported for southern India, Sri Lanka, and part of northeastern Mozambique, possibly reflecting continental thickening and exhumation during the main collision event between East and West Gondwana. 相似文献