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111.
A method that links acoustic mapping data to underwater video observations of seafloor substrate is described for use in defining fish habitat. Three study areas in the Aleutian Islands were acoustically mapped using sidescan and multibeam sonar. The sidescan sonar data were used to compute average reflectivity (hardness) and seafloor complexity. The multibeam depth data were used to determine local slope, rugosity (seafloor roughness) and relative height. Underwater video was collected from three to four transects in each of the three study areas. The underwater video was used to classify the seafloor into nine observed primary and secondary substrate classes. A statistical relationship between the observed (video) and the remotely sensed (acoustic) seafloor characteristics was estimated using a classification tree. The best classification tree utilized rugosity, reflectivity and complexity data and produced misclassification rates of less than 25% overall. Mean grain size of sediment samples was not strongly related to the acoustic data. Error rates were highest for those substrate classes with the smallest number of data points. The results highlight the need for adequate sample sizes and coverage of all potential substrate types when groundtruthing acoustic maps.  相似文献   
112.
Mass media frequently makes use of more than the visual image. With the exception of music, movie scores, and radio news however, media geographers have largely ignored the impact sound in media has on shaping and characterizing our experience of the world. We address this lack by showcasing two types of audio media: audio drama and audio-guided tours. The former will be explored with the help of the world’s most successful audio drama series The Three Investigators to give a historical and theoretical introduction to the realm of sound within mass media. The latter will be illustrated using the example of the Austin Walking Tour as a representative production for city tourism.  相似文献   
113.
In the last decade the zircon (U-Th)/He (ZHe) thermochronometer has been applied to a variety of geologic problems. Although bulk diffusion coefficients for He in zircon are available from laboratory step-heating experiments, little is known about the diffusion mechanism(s) and their dependence on the crystallographic structure of zircon. Here, we investigate the diffusion of He in perfectly crystalline zircon using atomistic simulation methods that provide insights into the structural pathways of He migration in zircon. Empirical force fields and quantum-mechanical calculations reveal that the energy barriers for He diffusion are strongly dependent on structure. The most favorable pathway for He diffusion is the [0 0 1] direction through the open channels parallel to the c-axis (, activation energy for tracer diffusion of a He atom along [0 0 1]). In contrast, energy barriers are higher in other directions where narrower channels for He diffusion are identified, such as [1 0 0], [1 0 1], and [1 1 0] (ΔE of 44.8, 101.7, and 421.3 kJ mol−1, respectively). Molecular dynamics simulations are in agreement with these results and provide additional insight in the diffusion mechanisms along different crystallographic directions, as well as the temperature dependence. Below the closure temperature of He in zircon [Tc ∼ 180 °C, Reiners P. W., Spell T. L., Nicolescu S., and Zanetti K. A. (2004) Zircon (U-Th)/He thermochronometry: He diffusion and comparisons with Ar-40/Ar-39 dating. Geochim. Cosmochim. Acta68, 1857-1887], diffusion is anisotropic as He moves preferentially along the [0 0 1] direction, and calculated tracer diffusivities along the two most favorable directions differ by approximately five orders of magnitude (D[001]/D[100] ∼ 105, at T = 25 °C). Above this temperature, He atoms start to hop between adjacent [0 0 1] channels, along [1 0 0] and [0 1 0] directions (perpendicular to the c-axis). The diffusion along [1 0 0] and [0 1 0] is thermally activated, such that at higher temperatures, He diffusion in zircon becomes nearly isotropic (D[001]/D[100] ∼ 10, at T = 580 °C). These results suggest that the anisotropic nature of He diffusion at temperatures near the closure temperature should be considered in future diffusivity experiments. Furthermore, care should be taken when making geologic interpretations (e.g., exhumation rates, timing of cooling, etc.) from this thermochronometer until the effects of anisotropic diffusion on bulk ages and closure temperature estimates are better quantified.  相似文献   
114.
Rifted margins are created as a result of stretching and breakup of continental lithosphere that eventually leads to oceanic spreading and formation of a new oceanic basin. A cornerstone for understanding what processes control the final transition to seafloor spreading is the nature of the continent‐ocean transition (COT). We reprocessed multichannel seismic profiles and use available gravity data to study the structure and variability of the COT along the Northwest subbasin (NWSB) of the South China Sea. We have interpreted the seismic images to discern continental from oceanic domains. The continental‐crust domain is characterized by tilted fault blocks generally overlain by thick syn‐rift sedimentary units, and underlain by fairly continuous Moho reflections typically at 8–10 s twtt. The thickness of the continental crust changes greatly across the basin, from ~20 to 25 km under the shelf and uppermost slope, to ~9–6 km under the lower slope. The oceanic‐crust domain is characterized by a highly reflective top of basement, little faulting, no syntectonic strata and fairly constant thickness (over tens to hundreds of km) of typically 6 km, but ranging from 4 to 8 km. The COT is imaged as a ~5–10 km wide zone where oceanic‐type features directly abut or lap on continental‐type structures. The South China margin continental crust is cut by abundant normal faults. Seismic profiles show an along‐strike variation in the tectonic structure of the continental margin. The NE‐most lines display ~20–40 km wide segments of intense faulting under the slope and associated continental‐crust thinning, giving way to a narrow COT and oceanic crust. Towards the SW, faulting and thinning of the continental crust occurs across a ~100–110 km wide segment with a narrow COT and abutting oceanic crust. We interpret this 3D structural variability and the narrow COT as a consequence of the abrupt termination of continental rifting tectonics by the NE to SW propagation of a spreading centre. We suggest that breakup occurred abruptly by spreading centre propagation rather than by thinning during continental rifting. We propose a kinematic evolution for the oceanic domain of the NWSB consisting of a southward spreading centre propagation followed by a first narrow ridge jump to the north, and then a younger larger jump to the SE, to abandon the NWSB and create the East subbasin of the South China Sea.  相似文献   
115.
Semi qualitative index based methods using rankings and ratings are commonly used in susceptibility estimations over a wide area. However, generalized ranking and ratings are not applicable for one single landslide. This paper gives an easy and transferable approach to a susceptibility assessment of Huangtupo landslide (P.R. China), using raster addition without taking account for ranking and ratings. Slope, aspect, curvature, location and drainage buffer distance raster data sets have been obtained out of open source digital elevation models using ESRI’s ArcGIS. These conditioning factor raster data sets have been translated into raster data sets including simple yes or no criteria, referring to triggering or not. Subsequently they have been added by raster math to acquire a simple raster overlay map. After that this map is compared to initial displacement measurements, obtained by using a ground based synthetic aperture radar device. Acquired data is recalculated to a raster data set using the same spatial extent, to provide the possibility of comparison of the two raster data sets. The results reveal, that 76.35% of all measured movements occur in areas where raster cells include three or more conditioning factors, indicating that easy raster math operations can lead to satisfying results in local scale.  相似文献   
116.
Structures, stabilities and vibrational spectra have been calculated using molecular quantum mechanical methods for As(OH)3, AsO(OH)3, As(SH)3, AsS(SH)3 and their conjugate bases and for several species with partial substitution of S for O. Properties for the neutral gas-phase molecules are calculated with state-of-the-art methods which yield AsL distances within 0. 01 Å and AsL stretching frequencies within 10 cm−1 of experiment. Similar accuracy is obtained for neutral molecules in solution using a polarizable continuum model (PCM). For monoanions such as and frequencies can be calculated to within 20 cm−1 of experiment using the polarizable continuum model. Multiply charged anions remain a challenge for accurate frequency calculations, but we have obtained results within the PCM model which at least semiquantitatively reproduce the available data. This allows us to assign the controversial features D, E and F in the Raman data of (Wood S. A., Tait C. D. and Janecky D. R. (2002) A Raman spectroscopic study of arsenite and thioarsenite species in aqueous solution at 25 °C. Geochem. Trans. 3, 31-39).To help in the assignment of the arsenic sulfide spectra we have also calculated energetics for the oxidation of As(III) to As(V) compounds by polysulfides, disproportionation of As(III) compounds and for the dissociation of the oxo- and thio-acids. We have determined that As(III) oxyacids can be transformed to thioacids which can in turn be oxidized to As(V) sulfides by polysulfides and that the pKa1s of the acids involved can be ordered as follows: AsS(SH)3 < As(SH)3 < AsO(OH)3 < As(OH)3 in order of increasing pKa1. We have also established from the calculated energies that the most stable form of the As(III) oxyacid in acidic aqueous solution is indeed As(OH)3, consistent with previous assignments.  相似文献   
117.
The Seine estuary possesses a heavily industrialised catchment area that contrasts significantly with that possessed by the smaller Authie estuary. For both of these northern French estuaries, Pb isotopic compositions and concentrations have been determined on specimens of Hediste diversicolor (ragworms) and on HCl leachates performed on related mudflat sediment. Three sampling campaigns were completed in 2003. As expected, the reactive Pb obtained by 1 M HCl leaching, shows higher concentrations and a more anthropogenic signature in samples from the Seine estuary than in samples from the Authie. However, neither of the two sites is free from the influence of anthropogenic Pb. Possible contaminant sources are discussed through comparisons with previously published data. For the more highly contaminated Seine estuary, most of the ragworm Pb signatures are similar to those of the sediments. In contrast, ragworms from the Authie site exhibit a higher proportion of anthropogenic Pb than the corresponding sediments. Various hypotheses are discussed to explain this significant discrepancy: (1) analytical artifacts, (2) migration of ragworm populations, (3) diet and feeding behaviour, and as the most likely explanation (4) an unsuitable leaching method for the extraction of bioavailable Pb.  相似文献   
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120.
An improved mathematical hydrodynamic quasi-two-dimensional model of cells, CELSUB3, is presented for simulating drainage systems that consist of pumping well fields or subsurface drains. The CELSUB3 model is composed of an assemblage of algorithms that have been developed and tested previously and that simulate saturated flow in porous media, closed conduit flow, and flow through pumping stations. A new type of link between aquifer cells and drainage conduits is proposed. This link is verified in simple problems with well known analytical solutions. The correlation between results from analytical and mathematical solutions was considered satisfactory in all cases. To simulate more complex situations, the new proposed version, CELSUB3, was applied in a project designed to control the water-table level within a sewer system in Cha?ar Ladeado Town, Santa Fe Province, Argentina. Alternative drainage designs, which were evaluated under conditions of dynamic recharge caused by rainfall in a critical year (wettest year for the period of record) and a typical year, are briefly described. After analyzing ten alternative designs, the best technical–economic solution is a subsurface drainage system of closed conduits with pumping stations and evacuation channels. Electronic Publication  相似文献   
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